Synthesis and photoinduced birefringence of polymethacrylates with azo-substituted pyrazoline in the side chain

Two azo-containing polymers with pyrazoline group (polymers II and III) have been synthesized and their reversible optical storage properties tested in comparison with electron donor and acceptor substituted azobenzene-containing polymer I. The growth and relaxation process of birefringence signals...

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Published inMaterials chemistry and physics Vol. 82; no. 1; pp. 246 - 252
Main Authors Jin, Ming, Yang, Qing Xin, Lu, Ran, Pan, Ling Yun, Qi, Wen Yan, Zhao, Ying Ying
Format Journal Article
LanguageEnglish
Published Lausanne Elsevier B.V 28.09.2003
Elsevier
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Abstract Two azo-containing polymers with pyrazoline group (polymers II and III) have been synthesized and their reversible optical storage properties tested in comparison with electron donor and acceptor substituted azobenzene-containing polymer I. The growth and relaxation process of birefringence signals were fit with biexponential functions. It was found that polymer II, in which azo chromophores are connected with the main chain through pyrazoline groups, has fast storage rate and good storage stability. The storage efficiency indicated that the introduction of pyrazoline groups in the polymers II and III has a positive effect. The birefringence per mole of azo chromophore showed that polymers II and III have four times the value of polymer I. The relative stability of the photoinduced birefringence decreased with the increase of temperature.
AbstractList Two azo-containing polymers with pyrazoline group (polymers II and III) have been synthesized and their reversible optical storage properties tested in comparison with electron donor and acceptor substituted azobenzene-containing polymer I. The growth and relaxation process of birefringence signals were fit with biexponential functions. It was found that polymer II, in which azo chromophores are connected with the main chain through pyrazoline groups, has fast storage rate and good storage stability. The storage efficiency indicated that the introduction of pyrazoline groups in the polymers II and III has a positive effect. The birefringence per mole of azo chromophore showed that polymers II and III have four times the value of polymer I. The relative stability of the photoinduced birefringence decreased with the increase of temperature.
Author Qi, Wen Yan
Zhao, Ying Ying
Pan, Ling Yun
Jin, Ming
Lu, Ran
Yang, Qing Xin
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Issue 1
Keywords Photoinduced birefringence
Azo polymers
Pyrazoline
Polymethacrylates
Optical storage
Methacrylate polymer
Ultraviolet spectra
Visible spectra
Chemical structure
Photoinduced effect
Organic polymers
Experimental study
Pyrazolines
Synthesis
Azo polymer
Birefringence
Optical materials
Language English
License CC BY 4.0
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Snippet Two azo-containing polymers with pyrazoline group (polymers II and III) have been synthesized and their reversible optical storage properties tested in...
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StartPage 246
SubjectTerms Azo polymers
Exact sciences and technology
Fundamental areas of phenomenology (including applications)
Optical materials
Optics
Photoinduced birefringence
Physics
Polymers and organics
Polymethacrylates
Pyrazoline
Title Synthesis and photoinduced birefringence of polymethacrylates with azo-substituted pyrazoline in the side chain
URI https://dx.doi.org/10.1016/S0254-0584(03)00197-4
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