Synthesis and photoinduced birefringence of polymethacrylates with azo-substituted pyrazoline in the side chain
Two azo-containing polymers with pyrazoline group (polymers II and III) have been synthesized and their reversible optical storage properties tested in comparison with electron donor and acceptor substituted azobenzene-containing polymer I. The growth and relaxation process of birefringence signals...
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Published in | Materials chemistry and physics Vol. 82; no. 1; pp. 246 - 252 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
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Elsevier B.V
28.09.2003
Elsevier |
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Abstract | Two azo-containing polymers with pyrazoline group (polymers II and III) have been synthesized and their reversible optical storage properties tested in comparison with electron donor and acceptor substituted azobenzene-containing polymer I. The growth and relaxation process of birefringence signals were fit with biexponential functions. It was found that polymer II, in which azo chromophores are connected with the main chain through pyrazoline groups, has fast storage rate and good storage stability. The storage efficiency indicated that the introduction of pyrazoline groups in the polymers II and III has a positive effect. The birefringence per mole of azo chromophore showed that polymers II and III have four times the value of polymer I. The relative stability of the photoinduced birefringence decreased with the increase of temperature. |
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AbstractList | Two azo-containing polymers with pyrazoline group (polymers II and III) have been synthesized and their reversible optical storage properties tested in comparison with electron donor and acceptor substituted azobenzene-containing polymer I. The growth and relaxation process of birefringence signals were fit with biexponential functions. It was found that polymer II, in which azo chromophores are connected with the main chain through pyrazoline groups, has fast storage rate and good storage stability. The storage efficiency indicated that the introduction of pyrazoline groups in the polymers II and III has a positive effect. The birefringence per mole of azo chromophore showed that polymers II and III have four times the value of polymer I. The relative stability of the photoinduced birefringence decreased with the increase of temperature. |
Author | Qi, Wen Yan Zhao, Ying Ying Pan, Ling Yun Jin, Ming Lu, Ran Yang, Qing Xin |
Author_xml | – sequence: 1 givenname: Ming surname: Jin fullname: Jin, Ming organization: College of Chemistry, Jilin University, 119 Jiefang Road, Changchun 130023, PR China – sequence: 2 givenname: Qing Xin surname: Yang fullname: Yang, Qing Xin organization: College of Physics, Jilin university, 119 Jiefang Road, Changchun 130023, PR China – sequence: 3 givenname: Ran surname: Lu fullname: Lu, Ran email: luran@mail.jlu.edu.cn organization: College of Chemistry, Jilin University, 119 Jiefang Road, Changchun 130023, PR China – sequence: 4 givenname: Ling Yun surname: Pan fullname: Pan, Ling Yun organization: College of Physics, Jilin university, 119 Jiefang Road, Changchun 130023, PR China – sequence: 5 givenname: Wen Yan surname: Qi fullname: Qi, Wen Yan organization: College of Chemistry, Jilin University, 119 Jiefang Road, Changchun 130023, PR China – sequence: 6 givenname: Ying Ying surname: Zhao fullname: Zhao, Ying Ying organization: College of Chemistry, Jilin University, 119 Jiefang Road, Changchun 130023, PR China |
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CitedBy_id | crossref_primary_10_1143_JJAP_47_1642 crossref_primary_10_1016_j_reactfunctpolym_2012_04_010 |
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Keywords | Photoinduced birefringence Azo polymers Pyrazoline Polymethacrylates Optical storage Methacrylate polymer Ultraviolet spectra Visible spectra Chemical structure Photoinduced effect Organic polymers Experimental study Pyrazolines Synthesis Azo polymer Birefringence Optical materials |
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Snippet | Two azo-containing polymers with pyrazoline group (polymers II and III) have been synthesized and their reversible optical storage properties tested in... |
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SubjectTerms | Azo polymers Exact sciences and technology Fundamental areas of phenomenology (including applications) Optical materials Optics Photoinduced birefringence Physics Polymers and organics Polymethacrylates Pyrazoline |
Title | Synthesis and photoinduced birefringence of polymethacrylates with azo-substituted pyrazoline in the side chain |
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