Bifunctional magnetic-upconverting luminescent cellulose fibers for anticounterfeiting purposes

Counterfeiting of valuable documents, currency and branded products is a growing problem that has serious economic and security implications for governments and companies, as well as for ordinary people/customers. In order to prevent and detect falsification, continuous improvement of anticounterfei...

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Published inJournal of alloys and compounds Vol. 829; p. 154456
Main Authors Skwierczyńska, Małgorzata, Woźny, Przemysław, Runowski, Marcin, Perzanowski, Marcin, Kulpiński, Piotr, Lis, Stefan
Format Journal Article
LanguageEnglish
Published Lausanne Elsevier B.V 15.07.2020
Elsevier BV
Subjects
Cellulose fibers
Continuous improvement
Core/shell nanomaterials
Counterfeiting
Documents and textiles protection
Fluorides
Lanthanide(III) ions
Luminescence & magnetism
Magnetic properties
Mechanical properties
Multifunctional nanoparticles
Nanoparticles
Textiles
Documents and textiles protection
Luminescence & magnetism
Lanthanide(III) ions
Core/shell nanomaterials
Multifunctional nanoparticles
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Abstract Counterfeiting of valuable documents, currency and branded products is a growing problem that has serious economic and security implications for governments and companies, as well as for ordinary people/customers. In order to prevent and detect falsification, continuous improvement of anticounterfeiting technology is required. This article presents the fabrication process and properties of the luminescent (upconverting)-magnetic cellulose fibers and their application in textiles. For the first time such functionalized fibers and corresponding luminescent-magnetic textiles are prepared. Cellulose fibers with bifunctional properties were obtained by core/shell type nanostructures based on lanthanide doped fluorides and magnetite nanoparticles. They show a bright red emission under the NIR excitation and magnetic response, along with very good mechanical properties. The fabric with upconverting-magnetic properties made of the as-prepared fibers is a perfect example of advanced, multimodal protection of materials such as textiles and documents against counterfeiting. [Display omitted] •The novel, upconverting-magnetic cellulose fibers were prepared.•The synthesized bi-functional fibers were modified with core/shell nanostructures.•The modified cellulose fibers were obtained by the NMMO method.•Under NIR irradiation the modified fibers exhibited bright, red emission.•The functionalized fibers responded to the applied external magnetic field.
AbstractList Counterfeiting of valuable documents, currency and branded products is a growing problem that has serious economic and security implications for governments and companies, as well as for ordinary people/customers. In order to prevent and detect falsification, continuous improvement of anticounterfeiting technology is required. This article presents the fabrication process and properties of the luminescent (upconverting)-magnetic cellulose fibers and their application in textiles. For the first time such functionalized fibers and corresponding luminescent-magnetic textiles are prepared. Cellulose fibers with bifunctional properties were obtained by core/shell type nanostructures based on lanthanide doped fluorides and magnetite nanoparticles. They show a bright red emission under the NIR excitation and magnetic response, along with very good mechanical properties. The fabric with upconverting-magnetic properties made of the as-prepared fibers is a perfect example of advanced, multimodal protection of materials such as textiles and documents against counterfeiting.
Counterfeiting of valuable documents, currency and branded products is a growing problem that has serious economic and security implications for governments and companies, as well as for ordinary people/customers. In order to prevent and detect falsification, continuous improvement of anticounterfeiting technology is required. This article presents the fabrication process and properties of the luminescent (upconverting)-magnetic cellulose fibers and their application in textiles. For the first time such functionalized fibers and corresponding luminescent-magnetic textiles are prepared. Cellulose fibers with bifunctional properties were obtained by core/shell type nanostructures based on lanthanide doped fluorides and magnetite nanoparticles. They show a bright red emission under the NIR excitation and magnetic response, along with very good mechanical properties. The fabric with upconverting-magnetic properties made of the as-prepared fibers is a perfect example of advanced, multimodal protection of materials such as textiles and documents against counterfeiting. [Display omitted] •The novel, upconverting-magnetic cellulose fibers were prepared.•The synthesized bi-functional fibers were modified with core/shell nanostructures.•The modified cellulose fibers were obtained by the NMMO method.•Under NIR irradiation the modified fibers exhibited bright, red emission.•The functionalized fibers responded to the applied external magnetic field.
ArticleNumber 154456
Author Perzanowski, Marcin
Kulpiński, Piotr
Lis, Stefan
Skwierczyńska, Małgorzata
Runowski, Marcin
Woźny, Przemysław
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  organization: Adam Mickiewicz University, Faculty of Chemistry, Department of Rare Earths, Uniwersytetu Poznanskiego 8, 61-614, Poznan, Poland
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Luminescence & magnetism
Lanthanide(III) ions
Core/shell nanomaterials
Multifunctional nanoparticles
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Snippet Counterfeiting of valuable documents, currency and branded products is a growing problem that has serious economic and security implications for governments...
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StartPage 154456
SubjectTerms Cellulose fibers
Continuous improvement
Core/shell nanomaterials
Counterfeiting
Documents and textiles protection
Fluorides
Lanthanide(III) ions
Luminescence & magnetism
Magnetic properties
Mechanical properties
Multifunctional nanoparticles
Nanoparticles
Textiles
Title Bifunctional magnetic-upconverting luminescent cellulose fibers for anticounterfeiting purposes
URI https://dx.doi.org/10.1016/j.jallcom.2020.154456
https://www.proquest.com/docview/2434857996/abstract/
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