Multi-interpenetration driven ultra-robust ionic HOF with high proton conductivity for DMFCs
Herein, a novel ionic hydrogen-bonded organic framework (iHOF-12) was synthesized. The 5-fold interpenetrating network structure and charge-assisted synergistic effects enable iHOF-12 to maintain robustness under demanding conditions and attain excellent proton conductivity of 1.23 × 10 −2 S cm −1 ,...
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| Published in | Chemical communications (Cambridge, England) Vol. 6; no. 81; pp. 11576 - 11579 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
Royal Society of Chemistry
08.10.2024
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| Abstract | Herein, a novel ionic hydrogen-bonded organic framework (iHOF-12) was synthesized. The 5-fold interpenetrating network structure and charge-assisted synergistic effects enable iHOF-12 to maintain robustness under demanding conditions and attain excellent proton conductivity of 1.23 × 10
−2
S cm
−1
, which contributes to the enhancement of the DMFC performance.
3D ultra-robust
iHOF-12
exhibits 5-fold interpenetration and its inherent well-defined H-bond network imparts proton conductivity up to 10
−2
S cm
−1
. |
|---|---|
| AbstractList | Herein, a novel ionic hydrogen-bonded organic framework (iHOF-12) was synthesized. The 5-fold interpenetrating network structure and charge-assisted synergistic effects enable iHOF-12 to maintain robustness under demanding conditions and attain excellent proton conductivity of 1.23 × 10
S cm
, which contributes to the enhancement of the DMFC performance. Herein, a novel ionic hydrogen-bonded organic framework (iHOF-12) was synthesized. The 5-fold interpenetrating network structure and charge-assisted synergistic effects enable iHOF-12 to maintain robustness under demanding conditions and attain excellent proton conductivity of 1.23 × 10 −2 S cm −1 , which contributes to the enhancement of the DMFC performance. Herein, a novel ionic hydrogen-bonded organic framework (iHOF-12) was synthesized. The 5-fold interpenetrating network structure and charge-assisted synergistic effects enable iHOF-12 to maintain robustness under demanding conditions and attain excellent proton conductivity of 1.23 × 10 −2 S cm −1 , which contributes to the enhancement of the DMFC performance. 3D ultra-robust iHOF-12 exhibits 5-fold interpenetration and its inherent well-defined H-bond network imparts proton conductivity up to 10 −2 S cm −1 . Herein, a novel ionic hydrogen-bonded organic framework (iHOF-12) was synthesized. The 5-fold interpenetrating network structure and charge-assisted synergistic effects enable iHOF-12 to maintain robustness under demanding conditions and attain excellent proton conductivity of 1.23 × 10−2 S cm−1, which contributes to the enhancement of the DMFC performance. Herein, a novel ionic hydrogen-bonded organic framework (iHOF-12) was synthesized. The 5-fold interpenetrating network structure and charge-assisted synergistic effects enable iHOF-12 to maintain robustness under demanding conditions and attain excellent proton conductivity of 1.23 × 10-2 S cm-1, which contributes to the enhancement of the DMFC performance.Herein, a novel ionic hydrogen-bonded organic framework (iHOF-12) was synthesized. The 5-fold interpenetrating network structure and charge-assisted synergistic effects enable iHOF-12 to maintain robustness under demanding conditions and attain excellent proton conductivity of 1.23 × 10-2 S cm-1, which contributes to the enhancement of the DMFC performance. |
| Author | Bai, Xiang-Tian Yang, Yan Cao, Li-Hui Chen, Xu-Yong |
| AuthorAffiliation | Shaanxi Key Laboratory of Chemical Additives for Industry Shaanxi University of Science and Technology College of Chemistry and Chemical Engineering |
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| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/39314186$$D View this record in MEDLINE/PubMed |
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| CitedBy_id | crossref_primary_10_1016_j_jssc_2024_125109 crossref_primary_10_1002_cssc_202402767 crossref_primary_10_1021_acs_cgd_4c01228 |
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| Notes | For ESI and crystallographic data in CIF or other electronic format see DOI 2233365 Electronic supplementary information (ESI) available: Experimental details, crystal data, crystal structures, thermogravimetric analysis, proton conductivity, scanning electron microscopy and digital images, tapping mode AFM phase image, tensile plots, and stability of membrane performance. CCDC https://doi.org/10.1039/d4cc03957b ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23 |
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| SubjectTerms | Hydrogen bonding Interpenetrating networks Protons Synergistic effect |
| Title | Multi-interpenetration driven ultra-robust ionic HOF with high proton conductivity for DMFCs |
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