Separation Process and Microstructure-Chemical Composition Relationship of Cenospheres from Lignite Fly Ash Produced from Coal-Fired Power Plant in Thailand
The cenosphere is one becoming a focus of the power plant in terms of value addition and ash management. This study presents a systematic investigation and characterization of physical properties, morphological structures, and chemical composition of cenospheres separated from fly ash produced from...
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| Published in | Applied sciences Vol. 10; no. 16; p. 5512 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
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01.08.2020
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| ISSN | 2076-3417 2076-3417 |
| DOI | 10.3390/app10165512 |
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| Abstract | The cenosphere is one becoming a focus of the power plant in terms of value addition and ash management. This study presents a systematic investigation and characterization of physical properties, morphological structures, and chemical composition of cenospheres separated from fly ash produced from the Mae Moh coal-fired power plant, Thailand. To our knowledge, this is the first report on cenospheres separation from Mae Moh class C fly ash, with high calcium content ~24 wt.%, by adopting the traditional wet separation method (using water as the medium) to separate the lightweight cenospheres. Various effects of process parameters (fly ash-to-water ratio, stirring method, ultrasonication, and size classification) were designed to examine the cenosphere recovery yield in comparison. The result has revealed the limit of physical stirring-settling effect associated with the cenospheres content by nature governing the percent recovery. The bulk cenospheres were subject to size sieving into different sized fractions, with the structure-chemical composition relationship established for more insight. The particle diameter/shell thickness ratio revealed its significant correlation with the aluminosilicate glass composition, with the relating cenosphere shell structures (single-ring and porous) mapped to compare for a better elucidation of their structure-property relationship. The phase composition was also studied. |
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| AbstractList | The cenosphere is one becoming a focus of the power plant in terms of value addition and ash management. This study presents a systematic investigation and characterization of physical properties, morphological structures, and chemical composition of cenospheres separated from fly ash produced from the Mae Moh coal-fired power plant, Thailand. To our knowledge, this is the first report on cenospheres separation from Mae Moh class C fly ash, with high calcium content ~24 wt.%, by adopting the traditional wet separation method (using water as the medium) to separate the lightweight cenospheres. Various effects of process parameters (fly ash-to-water ratio, stirring method, ultrasonication, and size classification) were designed to examine the cenosphere recovery yield in comparison. The result has revealed the limit of physical stirring-settling effect associated with the cenospheres content by nature governing the percent recovery. The bulk cenospheres were subject to size sieving into different sized fractions, with the structure-chemical composition relationship established for more insight. The particle diameter/shell thickness ratio revealed its significant correlation with the aluminosilicate glass composition, with the relating cenosphere shell structures (single-ring and porous) mapped to compare for a better elucidation of their structure-property relationship. The phase composition was also studied. |
| Author | Yoriya, Sorachon Tepsri, Phattarathicha |
| Author_xml | – sequence: 1 givenname: Sorachon orcidid: 0000-0002-8890-5407 surname: Yoriya fullname: Yoriya, Sorachon – sequence: 2 givenname: Phattarathicha surname: Tepsri fullname: Tepsri, Phattarathicha |
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| CitedBy_id | crossref_primary_10_1016_j_clwas_2023_100109 crossref_primary_10_1016_j_conbuildmat_2024_135035 crossref_primary_10_1016_j_jclepro_2021_129475 crossref_primary_10_1088_1757_899X_1120_1_012025 crossref_primary_10_1108_SASBE_09_2024_0395 crossref_primary_10_3390_w13202935 crossref_primary_10_3390_cryst11080919 crossref_primary_10_3390_cryst11091067 crossref_primary_10_3389_feart_2023_1160448 crossref_primary_10_1016_j_conbuildmat_2021_124847 |
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| Title | Separation Process and Microstructure-Chemical Composition Relationship of Cenospheres from Lignite Fly Ash Produced from Coal-Fired Power Plant in Thailand |
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