Fabrication of α-Fe2O3@graphene nanostructures for enhanced gas-sensing property to ethanol

•α-Fe2O3@graphene nanocomposites were developed by one-step facile hydrothermal method.•α-Fe2O3@graphene nanocomposites exhibit good gas-sensing performance to ethanol in comparison with pure α-Fe2O3.•The gas sensing mechanism of as-prepared nanocomposites to ethanol is investigated. A simple and st...

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Published inApplied surface science Vol. 292; pp. 278 - 284
Main Authors Liang, Shiming, Zhu, Junwu, Wang, Chao, Yu, Songtao, Bi, Huiping, Liu, Xiaoheng, Wang, Xin
Format Journal Article
LanguageEnglish
Published Amsterdam Elsevier B.V 15.02.2014
Elsevier
Subjects
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science; rheology
Exact sciences and technology
Gas sensor
Graphene
Physics
α-Fe2O3
α-Fe2O3
Graphene
Gas sensor
Inorganic compounds
Iron oxide
α-Fe
Measurement sensor
Transition element compounds
Nanostructures
O
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Abstract •α-Fe2O3@graphene nanocomposites were developed by one-step facile hydrothermal method.•α-Fe2O3@graphene nanocomposites exhibit good gas-sensing performance to ethanol in comparison with pure α-Fe2O3.•The gas sensing mechanism of as-prepared nanocomposites to ethanol is investigated. A simple and straightforward strategy was developed for anchoring α-Fe2O3 nanoparticles on graphene as gas sensor material. The XRD and TEM results indicate that graphene sheets are decorated with α-Fe2O3 nanoparticles with various diameters and shapes. To demonstrate the potential applications, we have fabricated gas sensors using the as-synthesized α-Fe2O3@graphene and investigated sensor activity for ethanol detection. The results show that an appropriate content of graphene dopant could effectively enhance the gas-sensing properties of α-Fe2O3 operated at different temperatures. Especially, the α-Fe2O3@graphene (contained 2wt% of graphene) sensor exhibits better sensor performances in comparison with pure α-Fe2O3 counterpart, indicating the potential applications as sensor material toward ethanol detection.
AbstractList •α-Fe2O3@graphene nanocomposites were developed by one-step facile hydrothermal method.•α-Fe2O3@graphene nanocomposites exhibit good gas-sensing performance to ethanol in comparison with pure α-Fe2O3.•The gas sensing mechanism of as-prepared nanocomposites to ethanol is investigated. A simple and straightforward strategy was developed for anchoring α-Fe2O3 nanoparticles on graphene as gas sensor material. The XRD and TEM results indicate that graphene sheets are decorated with α-Fe2O3 nanoparticles with various diameters and shapes. To demonstrate the potential applications, we have fabricated gas sensors using the as-synthesized α-Fe2O3@graphene and investigated sensor activity for ethanol detection. The results show that an appropriate content of graphene dopant could effectively enhance the gas-sensing properties of α-Fe2O3 operated at different temperatures. Especially, the α-Fe2O3@graphene (contained 2wt% of graphene) sensor exhibits better sensor performances in comparison with pure α-Fe2O3 counterpart, indicating the potential applications as sensor material toward ethanol detection.
Author Bi, Huiping
Wang, Chao
Yu, Songtao
Wang, Xin
Zhu, Junwu
Liang, Shiming
Liu, Xiaoheng
Author_xml – sequence: 1
  givenname: Shiming
  orcidid: 0000-0002-3368-2576
  surname: Liang
  fullname: Liang, Shiming
  organization: Key Laboratory for Soft Chemistry and Functional Materials, Nanjing University of Science and Technology, Ministry of Education, Nanjing 210094, China
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  givenname: Junwu
  surname: Zhu
  fullname: Zhu, Junwu
  email: zhujw@njust.edu.cn
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  givenname: Chao
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  organization: Key Laboratory for Soft Chemistry and Functional Materials, Nanjing University of Science and Technology, Ministry of Education, Nanjing 210094, China
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  givenname: Songtao
  surname: Yu
  fullname: Yu, Songtao
  organization: Shanghai Research Institute of Chemical Industry, Shanghai 200062, China
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  givenname: Huiping
  surname: Bi
  fullname: Bi, Huiping
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  organization: Key Laboratory for Soft Chemistry and Functional Materials, Nanjing University of Science and Technology, Ministry of Education, Nanjing 210094, China
– sequence: 7
  givenname: Xin
  surname: Wang
  fullname: Wang, Xin
  organization: Key Laboratory for Soft Chemistry and Functional Materials, Nanjing University of Science and Technology, Ministry of Education, Nanjing 210094, China
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Keywords α-Fe2O3
Graphene
Gas sensor
Inorganic compounds
Iron oxide
α-Fe
Measurement sensor
Transition element compounds
Nanostructures
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Snippet •α-Fe2O3@graphene nanocomposites were developed by one-step facile hydrothermal method.•α-Fe2O3@graphene nanocomposites exhibit good gas-sensing performance to...
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SubjectTerms Condensed matter: electronic structure, electrical, magnetic, and optical properties
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science; rheology
Exact sciences and technology
Gas sensor
Graphene
Physics
α-Fe2O3
Title Fabrication of α-Fe2O3@graphene nanostructures for enhanced gas-sensing property to ethanol
URI https://dx.doi.org/10.1016/j.apsusc.2013.11.130
Volume 292
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