Cyclic voltammetry at constant sphericity

• Published in: Journal of electroanalytical chemistry (Lausanne, Switzerland) Vol. 443; no. 2; pp. 243 - 252
• Main Authors: Martínez-Ortiz, F., Alcaraz, M.L., Roca, I., López-Tenés, M.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 20.02.1998; Elsevier Science
• Subjects: Chemistry; Cyclic voltammetry; Electrochemistry; Electrodes: preparations and properties; Exact sciences and technology; General and physical chemistry; Heterogeneous kinetic parameters; Other electrodes; Spherical electrode; Cyclic voltammetry; Heterogeneous kinetic parameters; Spherical electrode; Stationary electrode; Electrode reaction; Cadmium II Ions; Theoretical study; Potassium Nitrates; Kinetic parameter; Experimental study; Electrochemical reaction; Mercury

Cyclic voltammetry has been applied to the study of a simple charge transfer reaction at a spherical electrode such as the static mercury drop electrode. Theoretical and experimental curves have been obtained at constant sphericity both for a reversible and slow electrode process, taking into accoun...