Bimodal fiber diameter distributed graphene oxide/nylon-6 composite nanofibrous mats via electrospinning

[Display omitted] ► Large scale fabrication of spider-wave-like nano-nets of nylon-6 was carried out by adding suitable amounts of GO. ► The mechanism of formation of bimodal fibers which differs by one order in their diameter was proposed. ► The suitable amounts of GO required to fabricate bimodal...

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Published inColloids and surfaces. A, Physicochemical and engineering aspects Vol. 407; pp. 121 - 125
Main Authors Pant, Hem Raj, Park, Chan Hee, Tijing, Leonard D., Amarjargal, Altangerel, Lee, Do-Hee, Kim, Cheol Sang
Format Journal Article
LanguageEnglish
Published Elsevier B.V 05.08.2012
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Abstract [Display omitted] ► Large scale fabrication of spider-wave-like nano-nets of nylon-6 was carried out by adding suitable amounts of GO. ► The mechanism of formation of bimodal fibers which differs by one order in their diameter was proposed. ► The suitable amounts of GO required to fabricate bimodal spider-wave-like nano-nets was investigated. In this work, nylon-6 spider-wave-like nano-nets are fabricated by regulating the amount of graphene oxide (GO) in polymer solution during electrospinning. The spider-wave-like nano-nets that comprise interlinked thin (≈14nm diameter) and thick fibers (≈192nm diameter) are widely distributed throughout the mat when suitable amount of GO is blended with nylon-6 solution. The heterogeneous composite mats were composed of bimodal nanofibers in which pore diameter was sufficiently decreased. The acceleration in ionization and degradation of nylon-6 (due to formic acid) solution caused by well-dispersed GO sheet as well as the formation of hydrogen bond between nylon-6 molecules and GO sheet during electrospinning are proposed as the possible mechanisms for the formation of these spider-wave-like nano-nets.
AbstractList [Display omitted] ► Large scale fabrication of spider-wave-like nano-nets of nylon-6 was carried out by adding suitable amounts of GO. ► The mechanism of formation of bimodal fibers which differs by one order in their diameter was proposed. ► The suitable amounts of GO required to fabricate bimodal spider-wave-like nano-nets was investigated. In this work, nylon-6 spider-wave-like nano-nets are fabricated by regulating the amount of graphene oxide (GO) in polymer solution during electrospinning. The spider-wave-like nano-nets that comprise interlinked thin (≈14nm diameter) and thick fibers (≈192nm diameter) are widely distributed throughout the mat when suitable amount of GO is blended with nylon-6 solution. The heterogeneous composite mats were composed of bimodal nanofibers in which pore diameter was sufficiently decreased. The acceleration in ionization and degradation of nylon-6 (due to formic acid) solution caused by well-dispersed GO sheet as well as the formation of hydrogen bond between nylon-6 molecules and GO sheet during electrospinning are proposed as the possible mechanisms for the formation of these spider-wave-like nano-nets.
In this work, nylon-6 spider-wave-like nano-nets are fabricated by regulating the amount of graphene oxide (GO) in polymer solution during electrospinning. The spider-wave-like nano-nets that comprise interlinked thin (≈14nm diameter) and thick fibers (≈192nm diameter) are widely distributed throughout the mat when suitable amount of GO is blended with nylon-6 solution. The heterogeneous composite mats were composed of bimodal nanofibers in which pore diameter was sufficiently decreased. The acceleration in ionization and degradation of nylon-6 (due to formic acid) solution caused by well-dispersed GO sheet as well as the formation of hydrogen bond between nylon-6 molecules and GO sheet during electrospinning are proposed as the possible mechanisms for the formation of these spider-wave-like nano-nets.
Author Pant, Hem Raj
Kim, Cheol Sang
Tijing, Leonard D.
Lee, Do-Hee
Amarjargal, Altangerel
Park, Chan Hee
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  organization: Department of Bionanosystem Engineering, Chonbuk National University, Jeonju 561-756, South Korea
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Keywords Electrospinning
Graphene oxide
Nanocomposite
Spider-wave
Nylon-6
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Snippet [Display omitted] ► Large scale fabrication of spider-wave-like nano-nets of nylon-6 was carried out by adding suitable amounts of GO. ► The mechanism of...
In this work, nylon-6 spider-wave-like nano-nets are fabricated by regulating the amount of graphene oxide (GO) in polymer solution during electrospinning. The...
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SubjectTerms colloids
Electrospinning
formic acid
graphene
Graphene oxide
hydrogen bonding
ionization
Nanocomposite
nanofibers
Nylon-6
polymers
Spider-wave
Title Bimodal fiber diameter distributed graphene oxide/nylon-6 composite nanofibrous mats via electrospinning
URI https://dx.doi.org/10.1016/j.colsurfa.2012.05.018
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