Extraction of organic acids using imidazolium-based ionic liquids and their toxicity to Lactobacillus rhamnosus
In situ extractive fermentation of lactic acid using organic solvents has already been heavily investigated. Now ionic liquids are emerging as alternative solvents for volatile organic compounds traditionally used in liquid–liquid extraction. In this paper, we examine whether imidazolium-based ionic...
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| Published in | Separation and purification technology Vol. 40; no. 1; pp. 97 - 101 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Amsterdam
Elsevier B.V
15.11.2004
Elsevier Science |
| Subjects | |
| Online Access | Get full text |
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| Abstract | In situ extractive fermentation of lactic acid using organic solvents has already been heavily investigated. Now ionic liquids are emerging as alternative solvents for volatile organic compounds traditionally used in liquid–liquid extraction. In this paper, we examine whether imidazolium-based ionic liquids can replace conventional organic solvents in the extractive fermentation of lactate by investigating their extraction behaviors and solvent toxicity. The extractions of organic acid using imidazolium-based ionic liquids without any extractant are controlled by the hydrophobicity of the acids, and in all cases the extractability is very low. The extraction behaviors of lactic acid with imidazolium-based ionic liquids containing tri-
n-butylphosphate extractant are similar to those of conventional organic solvents. Lactic acid producing bacterium,
Lactobacillus rhamnosus NBRC 3863, grew, consumed glucose and produced lactate in the presence of imidazolium-based ionic liquids. These findings suggest that ionic liquids could be used in an in situ extractive fermentation process. |
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| AbstractList | In situ extractive fermentation of lactic acid using organic solvents has already been heavily investigated. Now ionic liquids are emerging as alternative solvents for volatile organic compounds traditionally used in liquid–liquid extraction. In this paper, we examine whether imidazolium-based ionic liquids can replace conventional organic solvents in the extractive fermentation of lactate by investigating their extraction behaviors and solvent toxicity. The extractions of organic acid using imidazolium-based ionic liquids without any extractant are controlled by the hydrophobicity of the acids, and in all cases the extractability is very low. The extraction behaviors of lactic acid with imidazolium-based ionic liquids containing tri-
n-butylphosphate extractant are similar to those of conventional organic solvents. Lactic acid producing bacterium,
Lactobacillus rhamnosus NBRC 3863, grew, consumed glucose and produced lactate in the presence of imidazolium-based ionic liquids. These findings suggest that ionic liquids could be used in an in situ extractive fermentation process. |
| Author | Kondo, Kazuo Matsumoto, Michiaki Mochiduki, Kenji Fukunishi, Kei |
| Author_xml | – sequence: 1 givenname: Michiaki surname: Matsumoto fullname: Matsumoto, Michiaki email: mmatsumo@mail.doshisha.ac.jp – sequence: 2 givenname: Kenji surname: Mochiduki fullname: Mochiduki, Kenji – sequence: 3 givenname: Kei surname: Fukunishi fullname: Fukunishi, Kei – sequence: 4 givenname: Kazuo surname: Kondo fullname: Kondo, Kazuo |
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| Keywords | Ionic liquids Tri- n-butylphosphate Extraction Green solvent Organic acid Organic solvent Liquid liquid extraction Toxicity In situ Volatile organic compound Hydrophobicity Fermentation Ionic liquid |
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| SubjectTerms | Applied sciences Biological and medical sciences Biotechnology Chemical engineering Exact sciences and technology Extraction Fundamental and applied biological sciences. Psychology Green solvent Ionic liquids Liquid-liquid extraction Methods. Procedures. Technologies Organic acid Others Tri- n-butylphosphate Various methods and equipments |
| Title | Extraction of organic acids using imidazolium-based ionic liquids and their toxicity to Lactobacillus rhamnosus |
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