Adsorption properties of biomass-based activated carbon prepared with spent coffee grounds and pomelo skin by phosphoric acid activation
► AC prepared from coffee grounds and pomelo skin were activated by phosphoric acid. ► Adsorption of ethylene and n-butane fitted well with Langmuir equation at 308K. ► PS-AC could adsorb 129cm3/g n-butane at room temperature up to 1atm. ► Micropore filling effect was explained in a thermodynamic wa...
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| Published in | Applied surface science Vol. 268; pp. 566 - 570 |
|---|---|
| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Amsterdam
Elsevier B.V
01.03.2013
Elsevier |
| Subjects | |
| Online Access | Get full text |
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| Abstract | ► AC prepared from coffee grounds and pomelo skin were activated by phosphoric acid. ► Adsorption of ethylene and n-butane fitted well with Langmuir equation at 308K. ► PS-AC could adsorb 129cm3/g n-butane at room temperature up to 1atm. ► Micropore filling effect was explained in a thermodynamic way.
Activated carbon prepared from spent coffee grounds and pomelo skin by phosphoric acid activation had been employed as the adsorbent for ethylene and n-butane at room temperature. Prepared activated carbon was characterized by means of nitrogen adsorption–desorption, X-ray powder diffraction, scanning electron microscope and Fourier transform infrared spectroscope. It was confirmed that pore structure played an important role during the adsorption testes. Adsorption isotherms of ethylene and n-butane fitted well with Langmuir equation. The prepared samples owned better adsorption capacity for n-butane than commercial activated carbon. Isosteric heats of adsorptions at different coverage were calculated through Clausius–Clapeyron equation. Micropore filling effect was explained in a thermodynamic way. |
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| AbstractList | ► AC prepared from coffee grounds and pomelo skin were activated by phosphoric acid. ► Adsorption of ethylene and n-butane fitted well with Langmuir equation at 308K. ► PS-AC could adsorb 129cm3/g n-butane at room temperature up to 1atm. ► Micropore filling effect was explained in a thermodynamic way.
Activated carbon prepared from spent coffee grounds and pomelo skin by phosphoric acid activation had been employed as the adsorbent for ethylene and n-butane at room temperature. Prepared activated carbon was characterized by means of nitrogen adsorption–desorption, X-ray powder diffraction, scanning electron microscope and Fourier transform infrared spectroscope. It was confirmed that pore structure played an important role during the adsorption testes. Adsorption isotherms of ethylene and n-butane fitted well with Langmuir equation. The prepared samples owned better adsorption capacity for n-butane than commercial activated carbon. Isosteric heats of adsorptions at different coverage were calculated through Clausius–Clapeyron equation. Micropore filling effect was explained in a thermodynamic way. |
| Author | Ma, Xiaodong Ouyang, Feng |
| Author_xml | – sequence: 1 givenname: Xiaodong surname: Ma fullname: Ma, Xiaodong – sequence: 2 givenname: Feng surname: Ouyang fullname: Ouyang, Feng email: ouyangfh@hit.edu.cn |
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| Snippet | ► AC prepared from coffee grounds and pomelo skin were activated by phosphoric acid. ► Adsorption of ethylene and n-butane fitted well with Langmuir equation... |
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| SubjectTerms | Activated carbon Adsorption Coffee grounds Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Cross-disciplinary physics: materials science; rheology Exact sciences and technology Physics Pomelo skin |
| Title | Adsorption properties of biomass-based activated carbon prepared with spent coffee grounds and pomelo skin by phosphoric acid activation |
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