3D-supermolecular structure and electronic absorption of uranyl β-diketone [UO 2(tfa) 2(L)] (L = H 2O, OHCH 2CH 3) complex
► The reaction of UO 2 2 + ion with 4,4,4,-trifluoro-1-(2-furyl)-1,3-butanedione yielded a mononuclear [UO 2(tfa) 2(H 2O)] (3) complex. ► The electronic absorption for 3 shows LMCT (384 nm (<10)), wherein the U(VI) center is only capable to function as acceptor site. ► Dissolving 3 in ethanol gav...
Saved in:
| Published in | Journal of molecular structure Vol. 997; no. 1; pp. 1 - 6 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
2011
|
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | ► The reaction of
UO
2
2
+
ion with 4,4,4,-trifluoro-1-(2-furyl)-1,3-butanedione yielded a mononuclear [UO
2(tfa)
2(H
2O)]
(3) complex. ► The electronic absorption for
3 shows LMCT (384 nm (<10)), wherein the U(VI) center is only capable to function as acceptor site. ► Dissolving
3 in ethanol gave a single crystals of 3D-supramilecular polymer of [UO
2(tfa)
2(HOCH
2CH
3)]
n (
4).
Uranyl β-diketone complex UO
2(tfa)
2·H
2O (
3) (tfa
=
deprotonated 4,4,4,-trifluoro-1-(2-furyl)-1,3-butanedione) has been successfully prepared by reacting UO
2(OAc)
2·2H
2O (OAc
=
O
2CMe) with two equivalents of 4,4,4,-trifluoro-1-(2-furyl)-1,3-butanedione (
H-tfa:
1) in ethanol. Complex
3 was characterized by elemental analysis and FT-IR. Dissolving
3 in ethanol gave during several days single crystals of [UO
2(tfa)
2(OHCH
2CH
3)] (
4), wherein one ethanol molecule replaces aqua ligand. The solid-state structure of
4 was determined by a single X-ray analysis. Crystal data of C
18H
14F
6O
9U:
a
=
13.7163(7),
b
=
20.7528(10),
c
=
7.4664(4)
Å, β
=
90.818(4)°, space group P2(1)/c,
Z
=
4 and
d
calc
=
2.270
mg/m
3. Complex
4 adopted a distorted pentagonal bipyramidal geometry. The coordinated oxygen atoms of
tfa (
deprotonated-
1) ligands are occupying equatorial positions, while the oxygen atoms of
UO
2
2
+
are still in the axial positions. The formation of the π–π interactions together with hydrogen bonded result in the set up a 3D-supramolecular architecture. The electronic absorption of
3 is reported and discussed. |
|---|---|
| AbstractList | Uranyl β-diketone complex UO₂(tfa)₂·H₂O (3) (tfa=deprotonated 4,4,4,-trifluoro-1-(2-furyl)-1,3-butanedione) has been successfully prepared by reacting UO₂(OAc)₂·2H₂O (OAc=O₂CMe) with two equivalents of 4,4,4,-trifluoro-1-(2-furyl)-1,3-butanedione (H-tfa: 1) in ethanol. Complex 3 was characterized by elemental analysis and FT-IR. Dissolving 3 in ethanol gave during several days single crystals of [UO₂(tfa)₂(OHCH₂CH₃)] (4), wherein one ethanol molecule replaces aqua ligand. The solid-state structure of 4 was determined by a single X-ray analysis. Crystal data of C₁₈H₁₄F₆O₉U: a=13.7163(7), b=20.7528(10), c=7.4664(4)Å, β=90.818(4)°, space group P2(1)/c, Z=4 and dcₐₗc=2.270mg/m³. Complex 4 adopted a distorted pentagonal bipyramidal geometry. The coordinated oxygen atoms of tfa (deprotonated-1) ligands are occupying equatorial positions, while the oxygen atoms of UO₂ ²⁺ are still in the axial positions. The formation of the π–π interactions together with hydrogen bonded result in the set up a 3D-supramolecular architecture. The electronic absorption of 3 is reported and discussed. ► The reaction of UO 2 2 + ion with 4,4,4,-trifluoro-1-(2-furyl)-1,3-butanedione yielded a mononuclear [UO 2(tfa) 2(H 2O)] (3) complex. ► The electronic absorption for 3 shows LMCT (384 nm (<10)), wherein the U(VI) center is only capable to function as acceptor site. ► Dissolving 3 in ethanol gave a single crystals of 3D-supramilecular polymer of [UO 2(tfa) 2(HOCH 2CH 3)] n ( 4). Uranyl β-diketone complex UO 2(tfa) 2·H 2O ( 3) (tfa = deprotonated 4,4,4,-trifluoro-1-(2-furyl)-1,3-butanedione) has been successfully prepared by reacting UO 2(OAc) 2·2H 2O (OAc = O 2CMe) with two equivalents of 4,4,4,-trifluoro-1-(2-furyl)-1,3-butanedione ( H-tfa: 1) in ethanol. Complex 3 was characterized by elemental analysis and FT-IR. Dissolving 3 in ethanol gave during several days single crystals of [UO 2(tfa) 2(OHCH 2CH 3)] ( 4), wherein one ethanol molecule replaces aqua ligand. The solid-state structure of 4 was determined by a single X-ray analysis. Crystal data of C 18H 14F 6O 9U: a = 13.7163(7), b = 20.7528(10), c = 7.4664(4) Å, β = 90.818(4)°, space group P2(1)/c, Z = 4 and d calc = 2.270 mg/m 3. Complex 4 adopted a distorted pentagonal bipyramidal geometry. The coordinated oxygen atoms of tfa ( deprotonated- 1) ligands are occupying equatorial positions, while the oxygen atoms of UO 2 2 + are still in the axial positions. The formation of the π–π interactions together with hydrogen bonded result in the set up a 3D-supramolecular architecture. The electronic absorption of 3 is reported and discussed. |
| Author | Daoud, Haneen M. Rüffer, Tobias Al-Anber, Mohammed A. Lang, Heinrich |
| Author_xml | – sequence: 1 givenname: Mohammed A. surname: Al-Anber fullname: Al-Anber, Mohammed A. email: masachem@mutah.edu.jo organization: Department of Chemical Science, Faculty of Science, Mu´tah University, P.O. Box 7, 61710-Al-Kark, Jordan – sequence: 2 givenname: Haneen M. surname: Daoud fullname: Daoud, Haneen M. organization: Department of Chemical Science, Faculty of Science, Mu´tah University, P.O. Box 7, 61710-Al-Kark, Jordan – sequence: 3 givenname: Tobias surname: Rüffer fullname: Rüffer, Tobias organization: Anorganische Chemie, Fakultät für Naturwissenschaften, Institut für Chemie, Technische Universität Chemnitz, Straße der Nationen 62, 09111 Chemnitz, Germany – sequence: 4 givenname: Heinrich surname: Lang fullname: Lang, Heinrich organization: Anorganische Chemie, Fakultät für Naturwissenschaften, Institut für Chemie, Technische Universität Chemnitz, Straße der Nationen 62, 09111 Chemnitz, Germany |
| BookMark | eNqFkM9qGzEQxkVJoE7SV2h1jKG7GUm72t1DocH544DBh9anUoSsHQW565WRdktM3ioPkmeqEqfnHIZvGL75ZvidkKPe90jIZwY5AyYvNvnWd3EIo8k5MJaDyKGAD2TC6opnNbDiiEwAOM94LeEjOYlxA5CcwCbkUVxlcdxhSBloxk4H-ho1jAGp7luKaTwE3ztD9Tr6sBuc76m3dAy633f0-Slr3R8c0k_012pJ-flg9TTJYvqbni_oNzqnfPmVLuez1KQSU2r8dtfhwxk5trqL-OlNT8nq5vrnbJ4tlrd3s8tFZoSQQ1YWvNZYVqALKZmQa-S2asG2WBsBrYbGNmVZrA1i1VQMtG5kjbbhZSUqqZk4JfKQa4KPMaBVu-C2OuwVA_WCUG3Uf4TqBaECoRLCtPjlsGi1V_o-uKhWP5KhTPhkwzlPju8HB6b__zoMKhqHvcHWhcRNtd69d-QfB-iHGQ |
| CitedBy_id | crossref_primary_10_1080_00958972_2014_936860 crossref_primary_10_1007_s10967_021_07811_y crossref_primary_10_1016_j_solidstatesciences_2017_12_002 crossref_primary_10_1002_open_202300219 crossref_primary_10_1021_cr300198m crossref_primary_10_1016_j_arabjc_2012_04_048 |
| Cites_doi | 10.1016/S0020-1693(00)95588-9 10.1021/ic50061a024 10.1039/a900845d 10.1107/S0108768192012278 10.1002/(SICI)1521-3773(19980904)37:16<2214::AID-ANIE2214>3.0.CO;2-V 10.1002/crat.200800552 10.1107/S1600536804011122 10.1016/j.tsf.2004.12.038 10.1021/ja0485964 10.1038/384341a0 10.1016/j.electacta.2008.02.042 10.1016/j.jfluchem.2006.02.012 10.1515/znb-2002-0307 10.1351/pac199567010135 10.1021/ic020121v 10.1016/0010-8545(93)85056-A 10.1021/ja039101y 10.1016/S0277-5387(01)00815-4 10.1016/j.inoche.2008.08.005 10.1007/BFb0036825 10.1039/b212635d 10.1002/anie.200250506 10.1006/mchj.1996.0006 10.1016/0924-2031(94)00084-T 10.1039/B304414A 10.1016/j.ccr.2008.07.013 10.1107/S0108767390000277 10.1021/ic8008317 10.1039/b304602h 10.1039/b405287k 10.1007/s10904-008-9251-7 10.1021/ic030196e 10.1039/B306733P 10.1002/anie.200300588 10.1021/ic00101a004 10.1039/b608187h 10.1016/j.molstruc.2007.09.023 10.1002/ejic.200300483 10.1016/0584-8539(94)E0119-U 10.1246/bcsj.46.2096 10.1021/ic00019a046 10.1016/S1387-7003(02)00354-4 10.1039/B500127G 10.1021/cm0008922 10.1016/0022-1902(63)80036-6 |
| ContentType | Journal Article |
| Copyright | 2011 Elsevier B.V. |
| Copyright_xml | – notice: 2011 Elsevier B.V. |
| DBID | FBQ AAYXX CITATION |
| DOI | 10.1016/j.molstruc.2011.03.040 |
| DatabaseName | AGRIS CrossRef |
| DatabaseTitle | CrossRef |
| DatabaseTitleList | |
| Database_xml | – sequence: 1 dbid: FBQ name: AGRIS url: http://www.fao.org/agris/Centre.asp?Menu_1ID=DB&Menu_2ID=DB1&Language=EN&Content=http://www.fao.org/agris/search?Language=EN sourceTypes: Publisher |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry Physics |
| EISSN | 1872-8014 |
| EndPage | 6 |
| ExternalDocumentID | 10_1016_j_molstruc_2011_03_040 US201500069222 S0022286011002584 |
| GroupedDBID | --K --M -~X .~1 0R~ 1B1 1RT 1~. 1~5 29L 3O- 4.4 457 4G. 53G 5GY 5VS 7-5 71M 8P~ 9JM 9JN AACTN AAEDT AAEDW AAIAV AAIKJ AAKOC AALRI AAOAW AAQFI AAQXK AARLI AAXUO ABEFU ABFNM ABGSF ABJNI ABMAC ABNEU ABUDA ABXDB ABYKQ ACDAQ ACFVG ACGFS ACNNM ACRLP ADBBV ADECG ADEZE ADIYS ADMUD ADUVX AEBSH AEHWI AEKER AENEX AFKWA AFTJW AFXIZ AFZHZ AGHFR AGRDE AGUBO AGYEJ AHHHB AIEXJ AIKHN AITUG AIVDX AJBFU AJOXV AJQLL AJSZI ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ ASPBG AVWKF AXJTR AZFZN BKOJK BLXMC CS3 DOVZS DU5 EBS EFJIC EFLBG EJD EO8 EO9 EP2 EP3 F5P FDB FEDTE FGOYB FIRID FLBIZ FNPLU FYGXN G-Q GBLVA HMU HVGLF HZ~ H~9 IHE J1W KOM M36 M41 MO0 N9A O-L O9- OAUVE OGIMB OZT P-8 P-9 P2P PC. Q38 R2- RIG RNS ROL RPZ SCB SCH SDF SDG SES SEW SPC SPCBC SSK SSQ SSU SSZ T5K TN5 UPT UQL WUQ XJT XOL XPP YK3 YQT ZMT ~02 ~G- ABPIF ABPTK FBQ AAXKI AAYXX AFJKZ AKRWK CITATION |
| ID | FETCH-LOGICAL-c336t-5428ae570a466136be2f7d0fde8c30da09f9554bcee79710aa968ef9257376a13 |
| IEDL.DBID | AIKHN |
| ISSN | 0022-2860 |
| IngestDate | Thu Sep 26 17:10:11 EDT 2024 Wed Dec 27 19:03:50 EST 2023 Fri Feb 23 02:26:10 EST 2024 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 1 |
| Keywords | Uranyl ion Supramolecular Butanedione β-diketone π–π interaction Hydrogen bond |
| Language | English |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c336t-5428ae570a466136be2f7d0fde8c30da09f9554bcee79710aa968ef9257376a13 |
| Notes | http://dx.doi.org/10.1016/j.molstruc.2011.03.040 |
| PageCount | 6 |
| ParticipantIDs | crossref_primary_10_1016_j_molstruc_2011_03_040 fao_agris_US201500069222 elsevier_sciencedirect_doi_10_1016_j_molstruc_2011_03_040 |
| PublicationCentury | 2000 |
| PublicationDate | 2011-00-00 |
| PublicationDateYYYYMMDD | 2011-01-01 |
| PublicationDate_xml | – year: 2011 text: 2011-00-00 |
| PublicationDecade | 2010 |
| PublicationTitle | Journal of molecular structure |
| PublicationYear | 2011 |
| Publisher | Elsevier B.V |
| Publisher_xml | – name: Elsevier B.V |
| References | Tellez, Lara, Mondragon, Castano, Mena (b0100) 1995; 9 Gallardo, Conte, Tuzimoto, Bortoluzzi, Peralta, Neves (b0055) 2008; 11 International Nuclear Atlantic Conference – INAC 2007 Santos, SP, Brazil, September 30 to October 5, 2007 ASSOCIAÇÃO BRASILEIRA DE ENERGIA NUCLEAR – ABEN. Vigato, Peruzzo, Tamburini (b0060) 2009; 253 G.M. Sheldrick, SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, 1997. H Cotton, Wilkinson (b0040) 1988 Kunkely, Vogler (b0135) 2002; 57b Li, Li, Zhang, Li (b0140) 2009; 44 Yoshimura, Miyake, Imoto (b0050) 1973; 46 K. Nakamoto, Coordination compounds, in: Infrared and Raman Spectra Inorganic and Coordination Compounds, John Wiley, New York, 1976 (Chapter 3) Fay, Pinnavaia, Baskin, Prasad (b0085) 1968; 7 O Eu Al-Anber, Mild, Alhalasah, Lang, Holze, Dryden, Winston, Sloop, Bumgardner, Washington, Loehle, Sankar, Lewis (b0115) 2008; 53 Rao, Natarajan, Vaidhyanathan (b0015) 2004; 43 Alagar, Kannan, Rajagopal, Venugopal, Krishnakumar, Nandhini, Natarajan (b0155) 2004; 60 Rose, Chang, Chen, Zubieta (b0030) 1994; 33 Jiang, Sarsfield, Renshaw, Livens, Collison, Charnock, Helliwell, Eccles (b0075) 2002; 41 Sabbatini, Guardigh, Manet, Ungaro, Casnati, Ziessel, Ulriich, Asfari, Lehn (b0045) 1995; 67 ACAC Thue´ry, Villiers, Jaud, Ephritikhine, Masci, Berthet, Nierlich, Ephritikhine, Salmon, Thue´ry, ivie‘re, Girerd, Ephritikhine, Salmon, Thue´ry, Rivie‘re, Girerd, Ephritikhine (b0020) 2004; 126 J.C. Craciet, Euro Patent Nos. 1516894, 1516895, 1517316, 1502917, 2005. Téllez, Gómez, Mondrágon, Castaño, Mena (b0090) 1995; 9 T. Miyazawa, S. Maeda, T. Murayama, Jpn. Patant No. 2004025834, 2004; jpn. Patant No. JP2003191642, 2003019867, 2003266954, 2003. Sarsfield, Helliwell, Berthet, Nierlich, Ephritikhine, Sarsfield, Steele, Helliwell, Teat, Berthet, Nierlich, Ephritikhine (b0025) 2004; 126 Kannan, Shanmugasundara Raj, Fun (b0150) 2001; 20 Tellez, Lara (b0095) 1995; 51A Thue´ry, Nierlich, Baldwin, Komatsuzaki, Hirose, Borkowski, Cahill, Xie, Zhao, Wang, Qu, Xiong, Xue, Xue, You, Frisch, Cahill, Kim, Norquist, O_Hare (b0035) 1999; 42 Tayyari, Nekoei, Rahemi (b0120) 2008; 882 I.A. Hemmila, Applications of Fluoroescence in Immunoassays, Wiley, New York, 1991. Gilli, Bertolasi, Ferretti, Gilli (b0130) 1993; 49 Casellato, Vidali, Vigato (b0065) 1976; 18 Song, Iyoda (b0165) 2009; 19 Frisch, Cahill, Pyykko, Zhao (b0145) 2006; 30 Zheng, Sun (b0160) 2009; 224 T. Ishida, H. Shiozaki, A. Ogiso, jpn., Patent No. 2004330614, 2004306306, 2004306307, 2004291281, 2004291253, 2004249635, 2004243596, 2004. Sheldrick (b0105) 1990; 46 Maria Claudia F.C. Felinto, José Eduardo M., Sá Luiz, Fábio T. Nakagawa Hermi F. Brito, Ercules E.S. Teotonio, spectroscopic properties of the UO Leciejewicz, Alcock, Kamp (b0070) 1995; 82 Gerasko, Mainicheva, Naumova, Neumaier, Kappes, Lebedkin, Fenske, Fedin, Mehrotra, Bohra, Gaur, Clark, Elliott, Chipperfield, Styring, Sinn (b0080) 2008; 47 Alagar (10.1016/j.molstruc.2011.03.040_b0155) 2004; 60 Sarsfield (10.1016/j.molstruc.2011.03.040_b0025_3) 2003 Xie (10.1016/j.molstruc.2011.03.040_b0035_3) 2003 Song (10.1016/j.molstruc.2011.03.040_b0165) 2009; 19 10.1016/j.molstruc.2011.03.040_b0010_3 Thue´ry (10.1016/j.molstruc.2011.03.040_b0035_1) 1999 Baskin (10.1016/j.molstruc.2011.03.040_b0085_2) 1963; 25 Téllez (10.1016/j.molstruc.2011.03.040_b0090) 1995; 9 Borkowski (10.1016/j.molstruc.2011.03.040_b0035_2) 2003; 42 10.1016/j.molstruc.2011.03.040_b0010_1 Tellez (10.1016/j.molstruc.2011.03.040_b0095) 1995; 51A Gallardo (10.1016/j.molstruc.2011.03.040_b0055) 2008; 11 Al-Anber (10.1016/j.molstruc.2011.03.040_b0115_1) 2008; 53 Salmon (10.1016/j.molstruc.2011.03.040_b0020_4) 2003 Sarsfield (10.1016/j.molstruc.2011.03.040_b0025_1) 2004; 126 Pyykko (10.1016/j.molstruc.2011.03.040_b0145_2) 1991; 30 Dryden (10.1016/j.molstruc.2011.03.040_b0115_2) 1996; 53 Berthet (10.1016/j.molstruc.2011.03.040_b0025_2) 2003 Hutchings (10.1016/j.molstruc.2011.03.040_b0005_3) 1996; 384 X Huang (10.1016/j.molstruc.2011.03.040_b0005_4) 2005; 483 Sheldrick (10.1016/j.molstruc.2011.03.040_b0105) 1990; 46 Kunkely (10.1016/j.molstruc.2011.03.040_b0135) 2002; 57b Gerasko (10.1016/j.molstruc.2011.03.040_b0080_1) 2008; 47 Kim (10.1016/j.molstruc.2011.03.040_b0035_5) 2003 Li (10.1016/j.molstruc.2011.03.040_b0140) 2009; 44 Casellato (10.1016/j.molstruc.2011.03.040_b0065) 1976; 18 10.1016/j.molstruc.2011.03.040_b0005_5 Mehrotra (10.1016/j.molstruc.2011.03.040_b0080_2) 1978 10.1016/j.molstruc.2011.03.040_b0005_6 10.1016/j.molstruc.2011.03.040_b0125 Salmon (10.1016/j.molstruc.2011.03.040_b0020_3) 2003 10.1016/j.molstruc.2011.03.040_b0005_7 Tellez (10.1016/j.molstruc.2011.03.040_b0100) 1995; 9 Clark (10.1016/j.molstruc.2011.03.040_b0080_3) 2002; 5 Berthet (10.1016/j.molstruc.2011.03.040_b0020_2) 2003; 42 Sabbatini (10.1016/j.molstruc.2011.03.040_b0010_2) 1993; 123 Francis (10.1016/j.molstruc.2011.03.040_b0005_2) 1998; 37 Frisch (10.1016/j.molstruc.2011.03.040_b0145_1) 2006 Sloop (10.1016/j.molstruc.2011.03.040_b0115_3) 2006; 127 Yoshimura (10.1016/j.molstruc.2011.03.040_b0050) 1973; 46 10.1016/j.molstruc.2011.03.040_b0110 Sabbatini (10.1016/j.molstruc.2011.03.040_b0045) 1995; 67 Gilli (10.1016/j.molstruc.2011.03.040_b0130) 1993; 49 Leciejewicz (10.1016/j.molstruc.2011.03.040_b0070) 1995; 82 Bean (10.1016/j.molstruc.2011.03.040_b0005_1) 2001; 13 Tayyari (10.1016/j.molstruc.2011.03.040_b0120) 2008; 882 Jiang (10.1016/j.molstruc.2011.03.040_b0075) 2002; 41 Thue´ry (10.1016/j.molstruc.2011.03.040_b0020_1) 2004; 126 Rose (10.1016/j.molstruc.2011.03.040_b0030) 1994; 33 Frisch (10.1016/j.molstruc.2011.03.040_b0035_4) 2005 Vigato (10.1016/j.molstruc.2011.03.040_b0060) 2009; 253 Fay (10.1016/j.molstruc.2011.03.040_b0085_1) 1968; 7 Berthet (10.1016/j.molstruc.2011.03.040_b0025_4) 2004 Kannan (10.1016/j.molstruc.2011.03.040_b0150) 2001; 20 Rao (10.1016/j.molstruc.2011.03.040_b0015) 2004; 43 Cotton (10.1016/j.molstruc.2011.03.040_b0040) 1988 Zheng (10.1016/j.molstruc.2011.03.040_b0160) 2009; 224 |
| References_xml | – volume: 9 start-page: 279 year: 1995 ident: b0100 publication-title: Vib. Spectrosc. contributor: fullname: Mena – volume: 30 start-page: 4679 year: 2006 end-page: 4690 ident: b0145 publication-title: Dalton Trans. contributor: fullname: Zhao – volume: 47 start-page: 8869 year: 2008 end-page: 8880 ident: b0080 article-title: Metal β-diketonates and allied derivatives publication-title: Inorg. Chem. contributor: fullname: Sinn – volume: 882 start-page: 153 year: 2008 end-page: 167 ident: b0120 publication-title: J. Mol. Struct. contributor: fullname: Rahemi – volume: 49 start-page: 564 year: 1993 end-page: 576 ident: b0130 publication-title: J. Acta Crystallogr., B contributor: fullname: Gilli – year: 1988 ident: b0040 article-title: Advanced Inorganic Chemistry contributor: fullname: Wilkinson – volume: 67 start-page: 135 year: 1995 ident: b0045 publication-title: Pure Appl. Chem. contributor: fullname: Lehn – volume: 46 start-page: 467 year: 1990 ident: b0105 publication-title: Acta Crystallogr. Sect. A contributor: fullname: Sheldrick – volume: 46 start-page: 2096 year: 1973 ident: b0050 publication-title: Bull. Chem. Soc. Jpn. contributor: fullname: Imoto – volume: 9 start-page: 279 year: 1995 end-page: 285 ident: b0090 publication-title: Vib. Spectrosc. contributor: fullname: Mena – volume: 20 start-page: 2145 year: 2001 end-page: 2150 ident: b0150 publication-title: Polyhedron contributor: fullname: Fun – volume: 41 start-page: 2799 year: 2002 ident: b0075 publication-title: Inorg. Chem. contributor: fullname: Eccles – volume: 43 start-page: 1466 year: 2004 ident: b0015 publication-title: Angew. Chem. Int. Ed. contributor: fullname: Vaidhyanathan – volume: 82 start-page: 43 year: 1995 ident: b0070 publication-title: J. Struct. Bond. (Berline) contributor: fullname: Kamp – volume: 126 start-page: 036 year: 2004 ident: b0025 publication-title: J. Am. Chem. Soc. contributor: fullname: Ephritikhine – volume: 33 start-page: 5167 year: 1994 ident: b0030 publication-title: Inorg. Chem. contributor: fullname: Zubieta – volume: 126 start-page: 6838 year: 2004 ident: b0020 publication-title: J. Am. Chem. Soc. contributor: fullname: Ephritikhine – volume: 253 start-page: 1099 year: 2009 end-page: 1201 ident: b0060 publication-title: Coord. Chem. Rev. contributor: fullname: Tamburini – volume: 44 start-page: 669 year: 2009 end-page: 674 ident: b0140 publication-title: Cryst. Res. Technol. contributor: fullname: Li – volume: 224 start-page: 457 year: 2009 end-page: 458 ident: b0160 publication-title: Z. Kristallogr. NCS contributor: fullname: Sun – volume: 53 start-page: 6038 year: 2008 end-page: 6047 ident: b0115 publication-title: Electrochim. Acta contributor: fullname: Lewis – volume: 18 start-page: 77 year: 1976 ident: b0065 publication-title: Inorg. Chim. Acta contributor: fullname: Vigato – volume: 42 start-page: 1047 year: 1999 ident: b0035 publication-title: J. Chem. Soc. Dalton Trans. contributor: fullname: O_Hare – volume: 51A start-page: 395 year: 1995 ident: b0095 publication-title: J. Spectrochim. Acta contributor: fullname: Lara – volume: 11 start-page: 1292 year: 2008 end-page: 1296 ident: b0055 publication-title: Inorg. Chem. Commun. contributor: fullname: Neves – volume: 7 start-page: 508 year: 1968 ident: b0085 publication-title: Inorg. Chem. contributor: fullname: Prasad – volume: 60 start-page: 773 year: 2004 end-page: 775 ident: b0155 publication-title: Acta Cryst. E contributor: fullname: Natarajan – volume: 19 start-page: 124 year: 2009 end-page: 132 ident: b0165 publication-title: J. Inorg. Organomet. Polym. contributor: fullname: Iyoda – volume: 57b start-page: 301 year: 2002 end-page: 304 ident: b0135 publication-title: Z. Naturforsch. contributor: fullname: Vogler – volume: 18 start-page: 77 year: 1976 ident: 10.1016/j.molstruc.2011.03.040_b0065 publication-title: Inorg. Chim. Acta doi: 10.1016/S0020-1693(00)95588-9 contributor: fullname: Casellato – ident: 10.1016/j.molstruc.2011.03.040_b0010_3 – volume: 7 start-page: 508 issue: 3 year: 1968 ident: 10.1016/j.molstruc.2011.03.040_b0085_1 publication-title: Inorg. Chem. doi: 10.1021/ic50061a024 contributor: fullname: Fay – start-page: 1047 year: 1999 ident: 10.1016/j.molstruc.2011.03.040_b0035_1 publication-title: J. Chem. Soc. Dalton Trans. doi: 10.1039/a900845d contributor: fullname: Thue´ry – ident: 10.1016/j.molstruc.2011.03.040_b0005_5 – start-page: 660 year: 2003 ident: 10.1016/j.molstruc.2011.03.040_b0025_2 publication-title: Chem. Commun. contributor: fullname: Berthet – volume: 49 start-page: 564 year: 1993 ident: 10.1016/j.molstruc.2011.03.040_b0130 publication-title: J. Acta Crystallogr., B doi: 10.1107/S0108768192012278 contributor: fullname: Gilli – ident: 10.1016/j.molstruc.2011.03.040_b0110 – volume: 37 start-page: 2214 year: 1998 ident: 10.1016/j.molstruc.2011.03.040_b0005_2 publication-title: Angew. Chem., Int. Ed. doi: 10.1002/(SICI)1521-3773(19980904)37:16<2214::AID-ANIE2214>3.0.CO;2-V contributor: fullname: Francis – volume: 44 start-page: 669 issue: 6 year: 2009 ident: 10.1016/j.molstruc.2011.03.040_b0140 publication-title: Cryst. Res. Technol. doi: 10.1002/crat.200800552 contributor: fullname: Li – volume: 60 start-page: 773 year: 2004 ident: 10.1016/j.molstruc.2011.03.040_b0155 publication-title: Acta Cryst. E doi: 10.1107/S1600536804011122 contributor: fullname: Alagar – volume: 483 start-page: 251 year: 2005 ident: 10.1016/j.molstruc.2011.03.040_b0005_4 publication-title: Thin Solid Films doi: 10.1016/j.tsf.2004.12.038 contributor: fullname: X Huang – volume: 126 start-page: 6838 year: 2004 ident: 10.1016/j.molstruc.2011.03.040_b0020_1 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja0485964 contributor: fullname: Thue´ry – volume: 384 start-page: 341 year: 1996 ident: 10.1016/j.molstruc.2011.03.040_b0005_3 publication-title: Nature doi: 10.1038/384341a0 contributor: fullname: Hutchings – volume: 53 start-page: 6038 year: 2008 ident: 10.1016/j.molstruc.2011.03.040_b0115_1 publication-title: Electrochim. Acta doi: 10.1016/j.electacta.2008.02.042 contributor: fullname: Al-Anber – volume: 127 start-page: 780 year: 2006 ident: 10.1016/j.molstruc.2011.03.040_b0115_3 publication-title: J. Fluorine Chem. doi: 10.1016/j.jfluchem.2006.02.012 contributor: fullname: Sloop – volume: 57b start-page: 301 year: 2002 ident: 10.1016/j.molstruc.2011.03.040_b0135 publication-title: Z. Naturforsch. doi: 10.1515/znb-2002-0307 contributor: fullname: Kunkely – year: 1988 ident: 10.1016/j.molstruc.2011.03.040_b0040 contributor: fullname: Cotton – volume: 67 start-page: 135 issue: 1 year: 1995 ident: 10.1016/j.molstruc.2011.03.040_b0045 publication-title: Pure Appl. Chem. doi: 10.1351/pac199567010135 contributor: fullname: Sabbatini – volume: 41 start-page: 2799 year: 2002 ident: 10.1016/j.molstruc.2011.03.040_b0075 publication-title: Inorg. Chem. doi: 10.1021/ic020121v contributor: fullname: Jiang – volume: 123 start-page: 201 year: 1993 ident: 10.1016/j.molstruc.2011.03.040_b0010_2 publication-title: Coord. J. Chem. Rev. doi: 10.1016/0010-8545(93)85056-A contributor: fullname: Sabbatini – volume: 126 start-page: 036 year: 2004 ident: 10.1016/j.molstruc.2011.03.040_b0025_1 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja039101y contributor: fullname: Sarsfield – volume: 20 start-page: 2145 year: 2001 ident: 10.1016/j.molstruc.2011.03.040_b0150 publication-title: Polyhedron doi: 10.1016/S0277-5387(01)00815-4 contributor: fullname: Kannan – ident: 10.1016/j.molstruc.2011.03.040_b0010_1 – volume: 11 start-page: 1292 year: 2008 ident: 10.1016/j.molstruc.2011.03.040_b0055 publication-title: Inorg. Chem. Commun. doi: 10.1016/j.inoche.2008.08.005 contributor: fullname: Gallardo – volume: 82 start-page: 43 year: 1995 ident: 10.1016/j.molstruc.2011.03.040_b0070 publication-title: J. Struct. Bond. (Berline) doi: 10.1007/BFb0036825 contributor: fullname: Leciejewicz – start-page: 762 year: 2003 ident: 10.1016/j.molstruc.2011.03.040_b0020_4 publication-title: Chem. Commun. doi: 10.1039/b212635d contributor: fullname: Salmon – volume: 42 start-page: 1952 year: 2003 ident: 10.1016/j.molstruc.2011.03.040_b0020_2 publication-title: Angew. Chem., Int. Ed. Engl. doi: 10.1002/anie.200250506 contributor: fullname: Berthet – volume: 224 start-page: 457 year: 2009 ident: 10.1016/j.molstruc.2011.03.040_b0160 publication-title: Z. Kristallogr. NCS contributor: fullname: Zheng – volume: 53 start-page: 34 year: 1996 ident: 10.1016/j.molstruc.2011.03.040_b0115_2 publication-title: J. Microchem. doi: 10.1006/mchj.1996.0006 contributor: fullname: Dryden – volume: 9 start-page: 279 year: 1995 ident: 10.1016/j.molstruc.2011.03.040_b0100 publication-title: Vib. Spectrosc. doi: 10.1016/0924-2031(94)00084-T contributor: fullname: Tellez – ident: 10.1016/j.molstruc.2011.03.040_b0005_7 – year: 1978 ident: 10.1016/j.molstruc.2011.03.040_b0080_2 contributor: fullname: Mehrotra – volume: 9 start-page: 279 issue: 3 year: 1995 ident: 10.1016/j.molstruc.2011.03.040_b0090 publication-title: Vib. Spectrosc. doi: 10.1016/0924-2031(94)00084-T contributor: fullname: Téllez – start-page: 2872 year: 2003 ident: 10.1016/j.molstruc.2011.03.040_b0020_3 publication-title: J. Chem. Soc., Dalton Trans. doi: 10.1039/B304414A contributor: fullname: Salmon – volume: 253 start-page: 1099 year: 2009 ident: 10.1016/j.molstruc.2011.03.040_b0060 publication-title: Coord. Chem. Rev. doi: 10.1016/j.ccr.2008.07.013 contributor: fullname: Vigato – volume: 46 start-page: 467 year: 1990 ident: 10.1016/j.molstruc.2011.03.040_b0105 publication-title: Acta Crystallogr. Sect. A doi: 10.1107/S0108767390000277 contributor: fullname: Sheldrick – volume: 47 start-page: 8869 issue: 19 year: 2008 ident: 10.1016/j.molstruc.2011.03.040_b0080_1 publication-title: Inorg. Chem. doi: 10.1021/ic8008317 contributor: fullname: Gerasko – start-page: 3443 year: 2003 ident: 10.1016/j.molstruc.2011.03.040_b0025_3 publication-title: J. Chem. Soc., Dalton Trans. doi: 10.1039/b304602h contributor: fullname: Sarsfield – start-page: 2814 year: 2004 ident: 10.1016/j.molstruc.2011.03.040_b0025_4 publication-title: J. Chem. Soc., Dalton Trans. doi: 10.1039/b405287k contributor: fullname: Berthet – volume: 19 start-page: 124 year: 2009 ident: 10.1016/j.molstruc.2011.03.040_b0165 publication-title: J. Inorg. Organomet. Polym. doi: 10.1007/s10904-008-9251-7 contributor: fullname: Song – volume: 42 start-page: 7041 year: 2003 ident: 10.1016/j.molstruc.2011.03.040_b0035_2 publication-title: Inorg. Chem. doi: 10.1021/ic030196e contributor: fullname: Borkowski – start-page: 2813 year: 2003 ident: 10.1016/j.molstruc.2011.03.040_b0035_5 publication-title: J. Chem. Soc., Dalton Trans. doi: 10.1039/B306733P contributor: fullname: Kim – volume: 43 start-page: 1466 year: 2004 ident: 10.1016/j.molstruc.2011.03.040_b0015 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.200300588 contributor: fullname: Rao – volume: 33 start-page: 5167 year: 1994 ident: 10.1016/j.molstruc.2011.03.040_b0030 publication-title: Inorg. Chem. doi: 10.1021/ic00101a004 contributor: fullname: Rose – ident: 10.1016/j.molstruc.2011.03.040_b0005_6 – start-page: 4679 year: 2006 ident: 10.1016/j.molstruc.2011.03.040_b0145_1 publication-title: Dalton Trans. doi: 10.1039/b608187h contributor: fullname: Frisch – volume: 882 start-page: 153 year: 2008 ident: 10.1016/j.molstruc.2011.03.040_b0120 publication-title: J. Mol. Struct. doi: 10.1016/j.molstruc.2007.09.023 contributor: fullname: Tayyari – start-page: 3712 year: 2003 ident: 10.1016/j.molstruc.2011.03.040_b0035_3 publication-title: Eur. J. Inorg. Chem. doi: 10.1002/ejic.200300483 contributor: fullname: Xie – volume: 51A start-page: 395 issue: N3 year: 1995 ident: 10.1016/j.molstruc.2011.03.040_b0095 publication-title: J. Spectrochim. Acta doi: 10.1016/0584-8539(94)E0119-U contributor: fullname: Tellez – volume: 46 start-page: 2096 year: 1973 ident: 10.1016/j.molstruc.2011.03.040_b0050 publication-title: Bull. Chem. Soc. Jpn. doi: 10.1246/bcsj.46.2096 contributor: fullname: Yoshimura – volume: 30 start-page: 3787 year: 1991 ident: 10.1016/j.molstruc.2011.03.040_b0145_2 publication-title: Inorg. Chem. doi: 10.1021/ic00019a046 contributor: fullname: Pyykko – volume: 5 start-page: 249 year: 2002 ident: 10.1016/j.molstruc.2011.03.040_b0080_3 publication-title: Inorg. Chem. Commun. doi: 10.1016/S1387-7003(02)00354-4 contributor: fullname: Clark – ident: 10.1016/j.molstruc.2011.03.040_b0125 – start-page: 1518 year: 2005 ident: 10.1016/j.molstruc.2011.03.040_b0035_4 publication-title: J. Chem. Soc., Dalton Trans. doi: 10.1039/B500127G contributor: fullname: Frisch – volume: 13 start-page: 1266 year: 2001 ident: 10.1016/j.molstruc.2011.03.040_b0005_1 publication-title: Chem. Mater. doi: 10.1021/cm0008922 contributor: fullname: Bean – volume: 25 start-page: 1001 year: 1963 ident: 10.1016/j.molstruc.2011.03.040_b0085_2 publication-title: J. Inorg. Nucl. Chem. doi: 10.1016/0022-1902(63)80036-6 contributor: fullname: Baskin |
| SSID | ssj0001101 |
| Score | 2.0228634 |
| Snippet | ► The reaction of
UO
2
2
+
ion with 4,4,4,-trifluoro-1-(2-furyl)-1,3-butanedione yielded a mononuclear [UO
2(tfa)
2(H
2O)]
(3) complex. ► The electronic... Uranyl β-diketone complex UO₂(tfa)₂·H₂O (3) (tfa=deprotonated 4,4,4,-trifluoro-1-(2-furyl)-1,3-butanedione) has been successfully prepared by reacting... |
| SourceID | crossref fao elsevier |
| SourceType | Aggregation Database Publisher |
| StartPage | 1 |
| SubjectTerms | absorption Butanedione crystals ethanol hydrogen Hydrogen bond oxygen Supramolecular Uranyl ion X-radiation β-diketone π–π interaction |
| Title | 3D-supermolecular structure and electronic absorption of uranyl β-diketone [UO 2(tfa) 2(L)] (L = H 2O, OHCH 2CH 3) complex |
| URI | https://dx.doi.org/10.1016/j.molstruc.2011.03.040 |
| Volume | 997 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1La9tAEB5ih9JcSpum5NGGOeQQQ2XLWkv2HnoIboOalw-pIVDCMqvdDc7DNrENDYH-qP6Q_qbO6tGmEMghICEhacWys_pmdjTzDcCOliRjazyftiRPqp0FvV5mgkzIDiUUik7sc4ePT5J02Dk4i8-WoF_lwviwyhL7C0zP0bq80ipHszUdjXyOr_deJDnpWcR6tAbL-U-iOizvfT1MT_4CMj_QrkjDfYMHicKXzZvJdc7UWrJ5imbo_SCP66iao4faZ_81vCrNRtwrevYGlux4FV72q2ptq_AiD-XMZm_hXnwOZospI25V-RYLktjFrUUaG_xX-QZJzya3OWjgxOGC9dbdNf7-FZjRlfUs3fh9OMBod-6owYejxjnuHuEnTDEafMRB2ucT3kUD88h0-2MNhvtfvvXToCyxwMIQyTyIefVBNu6G1GFFLRJtI9c1oTO2l4nQUCidZINDsyrtSjZGiGTSs07yh87IRG3xDupj7s46ID_LxhAZl_gllnSa4lBbnTmXdWNt3Aa0qkFV04JJQ1UhZpeqEoPyYlChUCyGDZDV2Kv_5oRiuH-y7ToLS9EFQ6UankbeseNZmXnKbD7jtVuwUjiV_fYe6nzffmCrZK63odb82d4u594fGqbeNw |
| link.rule.ids | 315,783,787,4033,4511,24130,27937,27938,27939,45599,45693 |
| linkProvider | Elsevier |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV3dS9xAEB_UIvaltH6g9mse-uCBuYvZJHf70IdyrUR7eg96IIgss9ldOat3h3cHSqF_VP-Q_k2dzQdaEPogJCQkmxB2Jr-ZHWZ-A_BJS5KJNZ5PW5In1c6DTic3QS5kTCmFIk587fDRcZoN4sOz5GwBunUtjE-rrLC_xPQCrasrrWo2W5Ph0Nf4-uhFWpCeRWxHF-FF7PmzWKmbvx7yPPj2Xk0Z7oc_KhO-at6Mrwue1orLUzRDHwV52kItOnpse_Zfw6vKacQv5Xe9gQU7WoWVbt2rbRWWi0TOfLoGP8XXYDqfMN7WfW-xpIid31qkkcGHvjdIejq-LSADxw7nbLXur_HP78AMf1jP0Y3ngz5GOzNHDT70Ghe408PPmGHU38V-1uUT3kUDi7x0e7cOg_1vp90sqBossChEOgsSXnuQTdohxWymRapt5NomdMZ2chEaCqWT7G5oNqRtya4IkUw71kn-zRmXaE9swNKIP2cTkMeyK0TGpX6BJZ2mJNRW587l7UQbtwWtelLVpOTRUHWC2ZWqxaC8GFQoFIthC2Q99-ofjVAM9v99dpOFpeiSgVINTiIf1vGczKww28947UdYyU6Peqp3cPz9Lbwsw8t-ewdLPNa-Z_9kpj8U-vcXLljfGQ |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=3D-supermolecular+structure+and+electronic+absorption+of+uranyl+%CE%B2-diketone+%5BUO+2%28tfa%29+2%28L%29%5D+%28L+%3D+H+2O%2C+OHCH+2CH+3%29+complex&rft.jtitle=Journal+of+molecular+structure&rft.au=Al-Anber%2C+Mohammed+A.&rft.au=Daoud%2C+Haneen+M.&rft.au=R%C3%BCffer%2C+Tobias&rft.au=Lang%2C+Heinrich&rft.date=2011&rft.pub=Elsevier+B.V&rft.issn=0022-2860&rft.eissn=1872-8014&rft.volume=997&rft.issue=1&rft.spage=1&rft.epage=6&rft_id=info:doi/10.1016%2Fj.molstruc.2011.03.040&rft.externalDocID=S0022286011002584 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0022-2860&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0022-2860&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0022-2860&client=summon |