Recent trends in carbon negative electrode materials
The use of graphite-type materials as the negative electrodes for rechargeable lithium batteries is increasing. For graphite-type materials, we proposed the intercalation mechanism taking into account the influence of crystallite size and stacking of the graphitic layers. We found graphite-type mate...
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| Published in | Journal of power sources Vol. 68; no. 1; pp. 99 - 101 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article Conference Proceeding |
| Language | English |
| Published |
Lausanne
Elsevier B.V
01.09.1997
Elsevier Sequoia |
| Subjects | |
| Online Access | Get full text |
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| Abstract | The use of graphite-type materials as the negative electrodes for rechargeable lithium batteries is increasing. For graphite-type materials, we proposed the intercalation mechanism taking into account the influence of crystallite size and stacking of the graphitic layers. We found graphite-type materials with a reversible capacity of 430 mAh g
−1 over a theoretical limit capacity of 372 mAh g
−1. This higher capacity is due to cavities existing in carbon that are capable of storing lithium ions. |
|---|---|
| AbstractList | The use of graphite-type materials as the negative electrodes for rechargeable lithium batteries is increasing. For graphite-type materials, we proposed the intercalation mechanism taking into account the influence of crystallite size and stacking of the graphitic layers. We found graphite-type materials with a reversible capacity of 430 mAh g
−1 over a theoretical limit capacity of 372 mAh g
−1. This higher capacity is due to cavities existing in carbon that are capable of storing lithium ions. |
| Author | Mabuchi, A. Tokumitsu, K. Fujimoto, H. Kasuh, T. |
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| Cites_doi | 10.1149/1.2044128 10.1016/0008-6223(94)90109-0 10.1016/0379-6779(94)90306-9 10.1149/1.2050057 10.1016/0008-6223(94)90182-1 10.1149/1.2048523 10.1149/1.2048684 10.1126/science.264.5158.556 |
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| Keywords | Electrode materials Rechargeable lithium batteries Carbon Negative electrodes Secondary batteries Graphite Lithium batteries Intercalation compounds Electrode material Negative electrode Carbonaceous material Specific capacity Lithium ion Electrochemical characteristic |
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| References_xml | – volume: 142 start-page: 2581 year: 1995 ident: bib10 publication-title: J. Electrochem. Soc. contributor: fullname: Dahn – start-page: 3A09 year: 1995 ident: bib5 publication-title: Proc. 22nd Annual Meet. Carbon Society of Japan contributor: fullname: Kasuh – volume: 32 start-page: 1249 year: 1994 ident: bib7 publication-title: Carbon contributor: fullname: Kasuh – volume: 142 start-page: 1041 year: 1995 ident: bib1 publication-title: J. Electrochem. Soc. contributor: fullname: Kasuh – volume: 32 start-page: 193 year: 1994 ident: bib3 publication-title: Carbon contributor: fullname: Akuzawa – volume: 264 start-page: 556 year: 1994 ident: bib9 publication-title: Science contributor: fullname: Endo – volume: 142 start-page: 716 year: 1995 ident: bib4 publication-title: J. Electrochem. Soc. contributor: fullname: Fujimoto – volume: 142 start-page: 3049 year: 1995 ident: bib2 publication-title: J. Electrochem. Soc. contributor: fullname: Kasuh – volume: 62 start-page: 153 year: 1994 ident: bib8 publication-title: Synth. Met. contributor: fullname: Yamabe – volume: 142 start-page: 1041 year: 1995 ident: 10.1016/S0378-7753(97)02582-2_bib1 publication-title: J. Electrochem. Soc. doi: 10.1149/1.2044128 contributor: fullname: Mabuchi – start-page: 3A09 year: 1995 ident: 10.1016/S0378-7753(97)02582-2_bib5 contributor: fullname: Fujimoto – volume: 32 start-page: 1249 year: 1994 ident: 10.1016/S0378-7753(97)02582-2_bib7 publication-title: Carbon doi: 10.1016/0008-6223(94)90109-0 contributor: fullname: Fujimoto – volume: 62 start-page: 153 year: 1994 ident: 10.1016/S0378-7753(97)02582-2_bib8 publication-title: Synth. Met. doi: 10.1016/0379-6779(94)90306-9 contributor: fullname: Yata – volume: 142 start-page: 2581 year: 1995 ident: 10.1016/S0378-7753(97)02582-2_bib10 publication-title: J. Electrochem. Soc. doi: 10.1149/1.2050057 contributor: fullname: Zheng – ident: 10.1016/S0378-7753(97)02582-2_bib6 – volume: 32 start-page: 193 year: 1994 ident: 10.1016/S0378-7753(97)02582-2_bib3 publication-title: Carbon doi: 10.1016/0008-6223(94)90182-1 contributor: fullname: Fujimoto – volume: 142 start-page: 716 year: 1995 ident: 10.1016/S0378-7753(97)02582-2_bib4 publication-title: J. Electrochem. Soc. doi: 10.1149/1.2048523 contributor: fullname: Tatsumi – volume: 142 start-page: 3049 year: 1995 ident: 10.1016/S0378-7753(97)02582-2_bib2 publication-title: J. Electrochem. Soc. doi: 10.1149/1.2048684 contributor: fullname: Mabuchi – volume: 264 start-page: 556 year: 1994 ident: 10.1016/S0378-7753(97)02582-2_bib9 publication-title: Science doi: 10.1126/science.264.5158.556 contributor: fullname: Sato |
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| SubjectTerms | Applied sciences Carbon Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Electrode materials Exact sciences and technology Negative electrodes Rechargeable lithium batteries |
| Title | Recent trends in carbon negative electrode materials |
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