Characteristics of third phase for reaction of benzyl chloride with sodium sulfide in phase transfer catalytic system

• Published in: Applied catalysis. A, General Vol. 201; no. 1; pp. 139 - 143
• Main Authors: Ido, Tadaatsu, Susaki, Teruyoshi, Jin, Gong, Goto, Shigeo
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 26.06.2000; Elsevier
• Subjects: Catalysis; Catalytic activity; Catalytic reactions; Chemical reaction; Chemistry; Exact sciences and technology; General and physical chemistry; Phase transfer catalyst; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; Third phase; Phase transfer catalyst; Catalytic activity; Chemical reaction; Third phase; Three phase catalysis; Phase transfer catalysis; Catalytic reaction; Dodecane; Temperature effect; Experimental study; Quaternary ammonium compound; Heterogeneous catalysis; Concentration effect; Benzenic compound; Kinetic parameter; Aqueous solution; Sodium sulfide

The purpose of this study is to investigate how the property of third phase affects the reaction rate in a phase transfer catalytic reaction system. Dibenzyl sulfide was produced by the reaction between sodium sulfide in an aqueous phase and benzyl chloride in an organic phase by using tetrahexylamm...