Synthesis of two new cage molecules containing trinitromethyl group
Two new cage compounds, 4-trinitroethyl-10-nitro-2,6,8,12-tetraacetylhexaazaisowurtzitane ( 3) and 4-trinitroethyl-2,6,8,10,12-pentanitrohexaazaisowurtzitane ( 4), containing trinitromethyl group were synthesized by a novel method, and their structures were confirmed by IR, 1H NMR, MS and single cry...
Saved in:
| Published in | Chinese chemical letters Vol. 21; no. 5; pp. 572 - 575 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.05.2010
School of Material Science & Engineering, Beijing Institute of Technology, Beijing 100081, China |
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | Two new cage compounds, 4-trinitroethyl-10-nitro-2,6,8,12-tetraacetylhexaazaisowurtzitane (
3) and 4-trinitroethyl-2,6,8,10,12-pentanitrohexaazaisowurtzitane (
4), containing trinitromethyl group were synthesized by a novel method, and their structures were confirmed by IR,
1H NMR, MS and single crystal X-ray. DSC result shows that compound
4 has surprising thermal stability and could be a potential energetic compound. |
|---|---|
| AbstractList | O6; Two new cage compounds,4-trinitroethyl-10-nitro-2,6,8,12-tetraacetylhexaazaisowurtzitane (3) and 4-trinitroethyl-2,6,8,10,12-pentanitrohexaazaisowurtzitane (4), containing trinitromethyl group were synthesized by a novel method, and their structures were confirmed by IR, 1H NMR, MS and single crystal X-ray. DSC result shows that compound 4 has surprising thermal stability and could be a potential energetic compound. Two new cage compounds, 4-trinitroethyl-10-nitro-2,6,8,12-tetraacetylhexaazaisowurtzitane ( 3) and 4-trinitroethyl-2,6,8,10,12-pentanitrohexaazaisowurtzitane ( 4), containing trinitromethyl group were synthesized by a novel method, and their structures were confirmed by IR, 1H NMR, MS and single crystal X-ray. DSC result shows that compound 4 has surprising thermal stability and could be a potential energetic compound. |
| Author | Sun, Cheng Hui Pang, Si Ping Zhao, Xin Qi Li, Yu Chuan |
| AuthorAffiliation | School of Material Science & Engineering, Beijing Institute of Technology, Beijing 100081, China |
| AuthorAffiliation_xml | – name: School of Material Science & Engineering, Beijing Institute of Technology, Beijing 100081, China |
| Author_xml | – sequence: 1 givenname: Cheng Hui surname: Sun fullname: Sun, Cheng Hui email: sunch@bit.edu.cn – sequence: 2 givenname: Xin Qi surname: Zhao fullname: Zhao, Xin Qi – sequence: 3 givenname: Yu Chuan surname: Li fullname: Li, Yu Chuan – sequence: 4 givenname: Si Ping surname: Pang fullname: Pang, Si Ping |
| BookMark | eNp9kD9PwzAQxS1UJErhE7B4Y0qw48RxBwZU8U-qxADMlmNf0oTUrmyXUj49LmVmutPpvbt7v3M0sc4CQleU5JRQfjPkWo8Q84KQeU6LnBB6gqZU1CKr5rycpD6NMlHS-gydhzAQUgjB-BQtXvc2riD0AbsWx53DFnZYqw7w2o2gtyMErJ2Nqre97XD0qUbv1hBX-xF33m03F-i0VWOAy786Q-8P92-Lp2z58vi8uFtmmrEqZgbqoiWGl6quTdVypsv0j2gYN0pXXAvVctoIRpWegyKMmZI3XBhSMN6UlWYzdH3cu1O2VbaTg9t6my7K72719dEUJKWsEo-kZEel9i4ED63c-H6t_F5SIg_E5CB_ickDMUkLmfAk1-3RBSnEZw9eBt2D1WB6DzpK4_p__T82QXfO |
| CitedBy_id | crossref_primary_10_1002_ajoc_202300060 crossref_primary_10_1007_s00894_024_05971_8 crossref_primary_10_1007_s11172_016_1367_2 crossref_primary_10_1139_cjc_2012_0468 crossref_primary_10_1007_s11224_012_0196_7 crossref_primary_10_1007_s12039_013_0448_0 crossref_primary_10_1021_jp2049469 crossref_primary_10_1007_s10973_023_12795_w crossref_primary_10_1002_ange_201307118 crossref_primary_10_1002_slct_201801792 crossref_primary_10_1007_s11172_023_3895_x crossref_primary_10_1016_j_ccr_2015_08_006 crossref_primary_10_1007_s00894_011_1259_1 crossref_primary_10_1002_cctc_202001475 crossref_primary_10_1016_j_fpc_2023_05_006 crossref_primary_10_1080_00268976_2013_829588 crossref_primary_10_3390_molecules28227648 crossref_primary_10_1007_s10847_014_0382_x crossref_primary_10_1007_s11172_017_1855_z crossref_primary_10_1016_j_cclet_2019_11_047 crossref_primary_10_1039_D0NJ01453B crossref_primary_10_1007_s11224_012_0167_z crossref_primary_10_1107_S2052520617005935 crossref_primary_10_1002_poc_3452 crossref_primary_10_1007_s11224_016_0819_5 crossref_primary_10_1007_s11172_019_2639_4 crossref_primary_10_1007_s11224_017_1067_z crossref_primary_10_1021_jp1118822 crossref_primary_10_1007_s00894_012_1647_1 crossref_primary_10_1016_j_jaap_2020_104924 crossref_primary_10_1039_c3nj00532a crossref_primary_10_1002_anie_201307118 crossref_primary_10_1007_s00894_011_1053_0 crossref_primary_10_1139_cjc_2013_0359 crossref_primary_10_1007_s11224_012_0171_3 crossref_primary_10_1016_j_comptc_2013_07_010 crossref_primary_10_1016_j_enmf_2024_02_008 crossref_primary_10_1039_D1TA08866A |
| Cites_doi | 10.1080/00397910500214425 10.1002/prep.200400064 10.1002/prep.200700004 10.1080/00397910701820459 10.1007/s10870-005-9012-1 10.1002/prep.200400062 10.1016/S0040-4020(98)00711-X 10.1021/ja970552q 10.1002/(SICI)1521-3773(20000117)39:2<401::AID-ANIE401>3.0.CO;2-P 10.3987/COM-89-5192 10.1021/ja00075a039 |
| ClassificationCodes | O6 |
| ContentType | Journal Article |
| Copyright | 2009 Cheng Hui Sun Copyright © Wanfang Data Co. Ltd. All Rights Reserved. |
| Copyright_xml | – notice: 2009 Cheng Hui Sun – notice: Copyright © Wanfang Data Co. Ltd. All Rights Reserved. |
| DBID | AAYXX CITATION 2B. 4A8 92I 93N PSX TCJ |
| DOI | 10.1016/j.cclet.2009.12.001 |
| DatabaseName | CrossRef Wanfang Data Journals - Hong Kong WANFANG Data Centre Wanfang Data Journals 万方数据期刊 - 香港版 China Online Journals (COJ) China Online Journals (COJ) |
| DatabaseTitle | CrossRef |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1878-5964 |
| EndPage | 575 |
| ExternalDocumentID | zghxkb201005016 10_1016_j_cclet_2009_12_001 S100184170900477X |
| GrantInformation_xml | – fundername: 国家自然科学基金; the Basic Research Foundation of Beijing Institute of Technology funderid: (20772011); (3090050320906) |
| GroupedDBID | --K --M .~1 0R~ 188 1B1 1~. 1~5 29B 2B. 2C. 2WC 4.4 457 4G. 5GY 5VR 5VS 6J9 7-5 71M 8P~ 8RM 92E 92I 92Q 93N AABNK AACTN AAEDT AAEDW AAIAV AAIKJ AAKOC AALRI AAOAW AAQFI AARLI AAXUO ABFNM ABFRF ABJNI ABMAC ABXDB ABYKQ ACDAQ ACGFO ACGFS ACNNM ACRLP ADBBV ADECG ADEZE ADMUD AEBSH AEFWE AEKER AENEX AFKWA AFTJW AFUIB AFZHZ AGHFR AGUBO AGYEJ AIEXJ AIKHN AITUG AJBFU AJOXV AJSZI ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ AXJTR BKOJK BLXMC C1A CCEZO CDRFL CHBEP CS3 CW9 DU5 EBS EFJIC EFLBG EJD EO9 EP2 EP3 F5P FA0 FDB FEDTE FIRID FLBIZ FNPLU FYGXN GBLVA GX1 HVGLF HZ~ J1W KOM M41 MO0 N9A O-L O9- OAUVE OK1 OZT P-8 P-9 P2P PC. Q38 RIG ROL RPZ S.. SDF SDG SDH SES SPC SPCBC SSK SSZ T5K TCJ TGP UNMZH UZ4 ~G- -SB -S~ 5XA 5XC AAXDM AAXKI AAYXX AKRWK CAJEB CITATION Q-- U1G U5L 4A8 PSX |
| ID | FETCH-LOGICAL-c335t-de72f0d64a77d5f63c44178b36dac56c8af61b831ac9ea033d46b68d0236b45c3 |
| IEDL.DBID | AIKHN |
| ISSN | 1001-8417 |
| IngestDate | Tue Feb 13 23:36:40 EST 2024 Thu Sep 12 20:03:20 EDT 2024 Fri Feb 23 02:34:38 EST 2024 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 5 |
| Keywords | X-ray crystal structure Cage compound Synthesis Trinitromethyl group |
| Language | English |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c335t-de72f0d64a77d5f63c44178b36dac56c8af61b831ac9ea033d46b68d0236b45c3 |
| PageCount | 4 |
| ParticipantIDs | wanfang_journals_zghxkb201005016 crossref_primary_10_1016_j_cclet_2009_12_001 elsevier_sciencedirect_doi_10_1016_j_cclet_2009_12_001 |
| PublicationCentury | 2000 |
| PublicationDate | 2010-05-01 |
| PublicationDateYYYYMMDD | 2010-05-01 |
| PublicationDate_xml | – month: 05 year: 2010 text: 2010-05-01 day: 01 |
| PublicationDecade | 2010 |
| PublicationTitle | Chinese chemical letters |
| PublicationTitle_FL | CHINESE CHEMICAL LETTERS |
| PublicationYear | 2010 |
| Publisher | Elsevier B.V School of Material Science & Engineering, Beijing Institute of Technology, Beijing 100081, China |
| Publisher_xml | – name: Elsevier B.V – name: School of Material Science & Engineering, Beijing Institute of Technology, Beijing 100081, China |
| References | C. Then compound At room temperature 10 6.96–6.99 (t, 2H on C4 and C6), 8.026–8.080 (m, 4H on C1, C2, C3 and C5). ESI–MS(Pos. Segment) Duddu, Dave, Damavarapu (bib2) 2008; 38 14.309(5) mm; triclinic 2CH K. Crystallographic data for compound C, the reaction temperature was elevated to 80 ) Langlet, Latypov, Wellmar (bib7) 2004; 29 + . 101.707(4) 1 2 4 mmol) in the mixture of 98% nitric acid (6 ; 543 (M–1, 6), 500(M–Ac–1, 3), 410 (M–2NO = Sun, Zhao (bib8) 2006; 36 93(2) g, 2.5 C. After 2 H MoKa radiation cell parameters from 4418 reflections mL) and 25% Oleum(3 Ac–1, 10), 394 (M–C(NO N 1299.5(7) O 90.096(2) Eaton, Xiong, Gilardi, Lukin, Li, Eaton, Zhang, Eaton, Gilardi (bib5) 1993; 115 g (52.6%) was obtained, which was recrystallized from 67% nitric acid. The data of compound 5.326 (s, 2H, CH 12.4121(15) or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336 033; or e-mail Vayalakkavoor, Vedachalam, Boyer (bib6) 1990; 31 ] 6.049–6.090 (d, 2H on C4 and C6), 6.808–6.739 (t, 2H on C1 and C2), 7.235 (s, 2H on C3 and C5); FD–MS g, 2.96 CH mm; monoclinic cm molecular weight, 660.58; crystal dimensions, 0.50 2.13–2.31 (m, 12H, 4CH m 0.159 molecular weight, 672.44; crystal dimensions, 0.37 94.427(3) mL) at 0 5.58 (s, 2H, CH 3.05–27.51 MHz, CD 510.2[M–NO have been deposited in the Cambridge Crystallographic Data Centre with the deposition numbers of CCDC 754913 and CCDC 754912. Copies of these data can be obtained free of charge via 3.06–27.50 99.918(6) 100). The data of compound empirical formula, C16H20N10O12·2CH Nielsen, Chafin, Christian, Duddu, Dave, Damavarapu, Bellamy, MacCuish, Golding, Propellants (bib1) 1998; 54 3031, 1697, 1655, 1598, 1307 Sun, Zhao (bib4) 2009; 17 556.6[M empirical formula, C mmol) was added into this mixture slowly. The reaction temperature was elevated to 50 mm ESI–MS(Neg. Segment) H NMR (400 1.718 0.18 1.1 mL 98% nitric acid keeping the temperature below 30 Mg mL acetic anhydride was dropped in 10 Wu, Ou, Liu (bib3) 2004; 29 3041, 3026, 1605, 1570.4, 1304, 1265 NO K. Crystal data of compound Å 11.839(4) h .Then the reaction mixture was filtered and compound FTIR IR (KBr 0.126 COCH COCD MoKa radiation cell parameters from 8194 reflections 0.27 and × 1.495 h the mixture was poured into ice-water. Compound g (68.3%) was obtained as white power and purified by recrystallization in acetone. After dissolving compound C and kept for 2 FTIR (KBr 14.4991(17) Crystal data of compound 1.12 346[M–C(NO 0.40 16.309(2) 0.6 8.008(3) 2935.0(6) Nielsen (10.1016/j.cclet.2009.12.001_bib1_1) 1998; 54 Eaton (10.1016/j.cclet.2009.12.001_bib5_1) 1993; 115 Duddu (10.1016/j.cclet.2009.12.001_bib2) 2008; 38 Sun (10.1016/j.cclet.2009.12.001_bib8) 2006; 36 Wu (10.1016/j.cclet.2009.12.001_bib3) 2004; 29 10.1016/j.cclet.2009.12.001_bib10 10.1016/j.cclet.2009.12.001_bib9 Zhang (10.1016/j.cclet.2009.12.001_bib5_3) 2000; 39 Bellamy (10.1016/j.cclet.2009.12.001_bib1_3) 2007; 32 Langlet (10.1016/j.cclet.2009.12.001_bib7) 2004; 29 Sun (10.1016/j.cclet.2009.12.001_bib4) 2009; 17 Lukin (10.1016/j.cclet.2009.12.001_bib5_2) 1997; 119 Duddu (10.1016/j.cclet.2009.12.001_bib1_2) 2005; 35 Vayalakkavoor (10.1016/j.cclet.2009.12.001_bib6) 1990; 31 |
| References_xml | – volume: 31 start-page: 479 year: 1990 ident: bib6 publication-title: Heterocycles contributor: fullname: Boyer – volume: 54 start-page: 11793 year: 1998 ident: bib1 publication-title: Tetrahedron contributor: fullname: Propellants – volume: 38 start-page: 767 year: 2008 ident: bib2 publication-title: Synth. Commun. contributor: fullname: Damavarapu – volume: 29 start-page: 344 year: 2004 ident: bib7 publication-title: Propellants Explos. Pyrotech. contributor: fullname: Wellmar – volume: 115 start-page: 10195 year: 1993 ident: bib5 publication-title: J. Am. Chem. Soc. contributor: fullname: Gilardi – volume: 29 start-page: 155 year: 2004 ident: bib3 publication-title: Propellants Explos. Pyrotech. contributor: fullname: Liu – volume: 17 start-page: 1 year: 2009 ident: bib4 publication-title: Chinese J. Energ. Mater. contributor: fullname: Zhao – volume: 36 start-page: 255 year: 2006 ident: bib8 publication-title: J. Chem. Crystallogr. contributor: fullname: Zhao – volume: 35 start-page: 2709 year: 2005 ident: 10.1016/j.cclet.2009.12.001_bib1_2 publication-title: Synth. Commun. doi: 10.1080/00397910500214425 contributor: fullname: Duddu – volume: 29 start-page: 344 year: 2004 ident: 10.1016/j.cclet.2009.12.001_bib7 publication-title: Propellants Explos. Pyrotech. doi: 10.1002/prep.200400064 contributor: fullname: Langlet – volume: 17 start-page: 1 year: 2009 ident: 10.1016/j.cclet.2009.12.001_bib4 publication-title: Chinese J. Energ. Mater. contributor: fullname: Sun – volume: 32 start-page: 20 year: 2007 ident: 10.1016/j.cclet.2009.12.001_bib1_3 publication-title: Explos. Pyrotech. doi: 10.1002/prep.200700004 contributor: fullname: Bellamy – ident: 10.1016/j.cclet.2009.12.001_bib10 – volume: 38 start-page: 767 year: 2008 ident: 10.1016/j.cclet.2009.12.001_bib2 publication-title: Synth. Commun. doi: 10.1080/00397910701820459 contributor: fullname: Duddu – volume: 36 start-page: 255 year: 2006 ident: 10.1016/j.cclet.2009.12.001_bib8 publication-title: J. Chem. Crystallogr. doi: 10.1007/s10870-005-9012-1 contributor: fullname: Sun – volume: 29 start-page: 155 year: 2004 ident: 10.1016/j.cclet.2009.12.001_bib3 publication-title: Propellants Explos. Pyrotech. doi: 10.1002/prep.200400062 contributor: fullname: Wu – volume: 54 start-page: 11793 year: 1998 ident: 10.1016/j.cclet.2009.12.001_bib1_1 publication-title: Tetrahedron doi: 10.1016/S0040-4020(98)00711-X contributor: fullname: Nielsen – volume: 119 start-page: 9591 year: 1997 ident: 10.1016/j.cclet.2009.12.001_bib5_2 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja970552q contributor: fullname: Lukin – volume: 39 start-page: 401 year: 2000 ident: 10.1016/j.cclet.2009.12.001_bib5_3 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/(SICI)1521-3773(20000117)39:2<401::AID-ANIE401>3.0.CO;2-P contributor: fullname: Zhang – volume: 31 start-page: 479 year: 1990 ident: 10.1016/j.cclet.2009.12.001_bib6 publication-title: Heterocycles doi: 10.3987/COM-89-5192 contributor: fullname: Vayalakkavoor – ident: 10.1016/j.cclet.2009.12.001_bib9 – volume: 115 start-page: 10195 year: 1993 ident: 10.1016/j.cclet.2009.12.001_bib5_1 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00075a039 contributor: fullname: Eaton |
| SSID | ssj0028836 |
| Score | 2.063981 |
| Snippet | Two new cage compounds, 4-trinitroethyl-10-nitro-2,6,8,12-tetraacetylhexaazaisowurtzitane (
3) and 4-trinitroethyl-2,6,8,10,12-pentanitrohexaazaisowurtzitane (... O6; Two new cage compounds,4-trinitroethyl-10-nitro-2,6,8,12-tetraacetylhexaazaisowurtzitane (3) and 4-trinitroethyl-2,6,8,10,12-pentanitrohexaazaisowurtzitane... |
| SourceID | wanfang crossref elsevier |
| SourceType | Aggregation Database Publisher |
| StartPage | 572 |
| SubjectTerms | Cage compound Synthesis Trinitromethyl group X-ray crystal structure |
| Title | Synthesis of two new cage molecules containing trinitromethyl group |
| URI | https://dx.doi.org/10.1016/j.cclet.2009.12.001 https://d.wanfangdata.com.cn/periodical/zghxkb201005016 |
| Volume | 21 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1NT9tAEB2RINReUFtaEaDRHnqsiTe7Xq-PyAIFULnQSLlZ--FNU8CJGlcpHPjt7NhrRKWqB66Wd2XNeGeePTPvAXyhWgirMxqlsRUR1_4oKpGxSGs39j53lnKcd_52JSZTfjFLZluQd7Mw2FYZYn8b05toHa6MgjVHq8VidI3sQZLTNM6Q8jCd9WDbpyPO-7B9cn45uXr-7pKyUQrE-yNc0JEPNW1exu9Xt7yV-FswiMP8I0HtbFTlVDV_kX7O3sFuwI3kpH2097BVVh_gTd7Jte1Bfn1feTC3XqzJ0pF6syQeMBPjwwW5ayVwyzXBxvRWEoLUWLqpkazAu-qWNNMdH2F6dvo9n0RBISEyjCV1ZMt07LyRuUpTmzjBDCqKSc2EVSYRRionqJaMKpOVKmbMcqGFtEgbr3li2CfoV8uq3AciU1tizWwsreGuTJWxwknlEaJCyMMG8LUzS7FqiTCKrkPsZ9FYESUts4KOsU9uAKIzXfGXPwsfqv-_kARDF-E0rYuH-Y8_Nxrr9nHilx28du9DeNsV_2N6BP361-_ys8cUtR5C7_iRDsOb8wTn9Mtq |
| link.rule.ids | 315,786,790,4521,24144,27957,27958,45620,45714 |
| linkProvider | Elsevier |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1Nb9swDCWyBEN7KfaJde02HXacESuSJflYBC2SNc2lLZCboA-ry9Y6xeKi2359RVseOmDYYVfDFAzSop5N8j2Aj9QK4W1JM5l7kXEbt6IRJcusDZMY8-Apx3nns6WYXfLPq2I1gGk_C4NtlSn3dzm9zdbpyjh5c3y7Xo_PkT1IcSrzEikP5eoJjHghKR_C6Gh-Olv-_u5SqlUKxPszNOjJh9o2LxfXazreSvwtmMRh_nJAPb03dTD11aPj5-QZ7CXcSI66R3sOg6p-ATvTXq7tJUzPf9YRzG3XW7IJpLnfkAiYiYvpgtx0ErjVlmBjeicJQRos3TRIVhBDdU3a6Y5XcHlyfDGdZUkhIXOMFU3mKzkJ0cncSOmLIJhDRTFlmfDGFcIpEwS1ilHjysrkjHkurFAeaeMtLxx7DcN6U1dvgCjpK6yZTZR3PFTSOC-CMhEhGoQ8bB8-9W7Rtx0Rhu47xL7q1osoaVlqOsE-uX0Qvev0H_HUMVX_25AkR-u0m7b619WXH98s1u3zIpq9_d-1P8DO7OJsoRfz5ekB7PaNADk9hGHz_a56F_FFY9-n9-cB06zNXA |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Synthesis+of+two+new+cage+molecules+containing+trinitromethyl+group&rft.jtitle=%E4%B8%AD%E5%9B%BD%E5%8C%96%E5%AD%A6%E5%BF%AB%E6%8A%A5%28%E8%8B%B1%E6%96%87%E7%89%88%29&rft.au=Cheng+Hui+Sun&rft.au=Xin+Qi+Zhao&rft.au=Yu+Chuan+Li&rft.au=Si+Ping+Pang&rft.date=2010-05-01&rft.pub=School+of+Material+Science+%26+Engineering%2C+Beijing+Institute+of+Technology%2C+Beijing+100081%2C+China&rft.issn=1001-8417&rft.eissn=1878-5964&rft.volume=21&rft.issue=5&rft.spage=572&rft.epage=575&rft_id=info:doi/10.1016%2Fj.cclet.2009.12.001&rft.externalDocID=zghxkb201005016 |
| thumbnail_s | http://utb.summon.serialssolutions.com/2.0.0/image/custom?url=http%3A%2F%2Fwww.wanfangdata.com.cn%2Fimages%2FPeriodicalImages%2Fzghxkb%2Fzghxkb.jpg |