Synthesis of two new cage molecules containing trinitromethyl group
Two new cage compounds, 4-trinitroethyl-10-nitro-2,6,8,12-tetraacetylhexaazaisowurtzitane ( 3) and 4-trinitroethyl-2,6,8,10,12-pentanitrohexaazaisowurtzitane ( 4), containing trinitromethyl group were synthesized by a novel method, and their structures were confirmed by IR, 1H NMR, MS and single cry...
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Published in | Chinese chemical letters Vol. 21; no. 5; pp. 572 - 575 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
01.05.2010
School of Material Science & Engineering, Beijing Institute of Technology, Beijing 100081, China |
Subjects | |
Online Access | Get full text |
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Summary: | Two new cage compounds, 4-trinitroethyl-10-nitro-2,6,8,12-tetraacetylhexaazaisowurtzitane (
3) and 4-trinitroethyl-2,6,8,10,12-pentanitrohexaazaisowurtzitane (
4), containing trinitromethyl group were synthesized by a novel method, and their structures were confirmed by IR,
1H NMR, MS and single crystal X-ray. DSC result shows that compound
4 has surprising thermal stability and could be a potential energetic compound. |
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ISSN: | 1001-8417 1878-5964 |
DOI: | 10.1016/j.cclet.2009.12.001 |