Barrier to internal rotation of the silyl group in cyclopropyl silane from the MW spectrum in the first excited torsional state

The MW spectrum of the first excited state of the internal rotation of the silyl group in cyclopropyl silane has been recorded and analyzed in the frequency region 6.9–38.0 GHz. Recordings were made with conventional Stark spectroscopy as well as with MW-MW double resonance. From the analysis of the...

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Published inJournal of molecular spectroscopy Vol. 120; no. 2; pp. 435 - 440
Main Authors Typke, Volker, Botskor, Ivan, Wiedenmann, Karl-Heinz
Format Journal Article
LanguageEnglish
Published San Diego, CA Elsevier Inc 01.12.1986
Elsevier
Subjects
Atomic and molecular physics
Barrier heights (internal rotation, inversion, rotational isomerism, conformational dynamics)
Exact sciences and technology
Molecular properties and interactions with photons
Physics
Properties of molecules and molecular ions
Microwave microwave double resonance
Rotation barrier
Internal rotation
Silicon Organic compounds
Rotational transition
Rotational constant
Stark effect
Experimental study
Centrifugal distorsion constant
Saturated cyclic compound
Transition energy
Microwave spectrum
Molecular constant
Vibrationally excited state
Monocyclic compound
Organic compounds
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Abstract The MW spectrum of the first excited state of the internal rotation of the silyl group in cyclopropyl silane has been recorded and analyzed in the frequency region 6.9–38.0 GHz. Recordings were made with conventional Stark spectroscopy as well as with MW-MW double resonance. From the analysis of the torsional splittings the following parameters were derived: V 3=1917.6(44) cal/mole, I α=5.888(14) u ∗ A 2, V a=21.56(21)°
AbstractList The MW spectrum of the first excited state of the internal rotation of the silyl group in cyclopropyl silane has been recorded and analyzed in the frequency region 6.9–38.0 GHz. Recordings were made with conventional Stark spectroscopy as well as with MW-MW double resonance. From the analysis of the torsional splittings the following parameters were derived: V 3=1917.6(44) cal/mole, I α=5.888(14) u ∗ A 2, V a=21.56(21)°
Author Typke, Volker
Botskor, Ivan
Wiedenmann, Karl-Heinz
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  givenname: Ivan
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  fullname: Botskor, Ivan
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  givenname: Karl-Heinz
  surname: Wiedenmann
  fullname: Wiedenmann, Karl-Heinz
  organization: Abteilung fuer Physikalische Chemie, University of Ulm, D-7900 Ulm/Donau, West Germany
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Cites_doi 10.1016/0022-2852(79)90203-0
10.1039/tf9494500179
10.1016/S0040-4039(01)89131-0
10.1016/0584-8539(84)80102-6
10.1103/RevModPhys.31.841
10.1016/0022-2852(74)90129-5
10.1016/0022-2860(79)80243-4
10.1002/cber.19791121020
10.1007/BFb0050802
10.1016/0022-2852(83)90047-4
10.1016/0022-2852(66)90117-2
10.1016/S0040-4039(01)98370-4
10.1021/ja01008a016
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Issue 2
Keywords Microwave microwave double resonance
Rotation barrier
Internal rotation
Silicon Organic compounds
Rotational transition
Rotational constant
Stark effect
Experimental study
Centrifugal distorsion constant
Saturated cyclic compound
Transition energy
Microwave spectrum
Molecular constant
Vibrationally excited state
Monocyclic compound
Organic compounds
Language English
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PublicationTitle Journal of molecular spectroscopy
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Snippet The MW spectrum of the first excited state of the internal rotation of the silyl group in cyclopropyl silane has been recorded and analyzed in the frequency...
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SubjectTerms Atomic and molecular physics
Barrier heights (internal rotation, inversion, rotational isomerism, conformational dynamics)
Exact sciences and technology
Molecular properties and interactions with photons
Physics
Properties of molecules and molecular ions
Title Barrier to internal rotation of the silyl group in cyclopropyl silane from the MW spectrum in the first excited torsional state
URI https://dx.doi.org/10.1016/0022-2852(86)90016-0
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