Electrical conductivity anomaly in near-stoichiometric plutonium dioxide

The variation of the electrical conductivity with oxygen pressure has been measured for plutonium dioxide at temperatures between 950 and 1100°C and in the oxygen partial pressure range from 2.1 × 10 4 to 10 −11 Pa. Minima in electrical conductivity and corresponding transitions from n- to p-type co...

Full description

Saved in:
Bibliographic Details
Published inJournal of nuclear materials Vol. 95; no. 1; pp. 181 - 184
Main Authors Naito, Keiji, Tsuji, Toshihide, Ouchi, Kinji, Yahata, Taneaki, Yamashita, Toshiyuki, Tagawa, Hiroaki
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.01.1980
Online AccessGet full text

Cover

Abstract The variation of the electrical conductivity with oxygen pressure has been measured for plutonium dioxide at temperatures between 950 and 1100°C and in the oxygen partial pressure range from 2.1 × 10 4 to 10 −11 Pa. Minima in electrical conductivity and corresponding transitions from n- to p-type conduction as function of the oxygen partial pressure were observed. These minima could occur by the presence of some impurities, but the possibility of the existence of hyperstoichiometric PuO 2 also could not be excluded by considering the concentration of the impurities. An intrinsic band-gap energy of 2.5 eV was calculated from the temperature dependence of the minimum electrical conductivity. The slopes of the plot of log o against log PO 2 for the n-type region were − 1 4.99 , − 1 4.72 , − 1 4.77 and − 1 4.81 at 950,1000, 1050 and 1100°C, respectively, which are in good agreement with the values reported previously. The ionized oxygen vacancy model seems to be reasonable in the n-type region.
AbstractList The variation of the electrical conductivity with oxygen pressure has been measured for plutonium dioxide at temperatures between 950 and 1100°C and in the oxygen partial pressure range from 2.1 × 10 4 to 10 −11 Pa. Minima in electrical conductivity and corresponding transitions from n- to p-type conduction as function of the oxygen partial pressure were observed. These minima could occur by the presence of some impurities, but the possibility of the existence of hyperstoichiometric PuO 2 also could not be excluded by considering the concentration of the impurities. An intrinsic band-gap energy of 2.5 eV was calculated from the temperature dependence of the minimum electrical conductivity. The slopes of the plot of log o against log PO 2 for the n-type region were − 1 4.99 , − 1 4.72 , − 1 4.77 and − 1 4.81 at 950,1000, 1050 and 1100°C, respectively, which are in good agreement with the values reported previously. The ionized oxygen vacancy model seems to be reasonable in the n-type region.
Author Naito, Keiji
Yahata, Taneaki
Tsuji, Toshihide
Ouchi, Kinji
Yamashita, Toshiyuki
Tagawa, Hiroaki
Author_xml – sequence: 1
  givenname: Keiji
  surname: Naito
  fullname: Naito, Keiji
– sequence: 2
  givenname: Toshihide
  surname: Tsuji
  fullname: Tsuji, Toshihide
– sequence: 3
  givenname: Kinji
  surname: Ouchi
  fullname: Ouchi, Kinji
– sequence: 4
  givenname: Taneaki
  surname: Yahata
  fullname: Yahata, Taneaki
– sequence: 5
  givenname: Toshiyuki
  surname: Yamashita
  fullname: Yamashita, Toshiyuki
– sequence: 6
  givenname: Hiroaki
  surname: Tagawa
  fullname: Tagawa, Hiroaki
BookMark eNp9kEtLAzEUhYNUsK3-AxezEl2M3rzmsRGkVCsU3Og6ZPLAyExSk5li_70zVly6uovznQP3W6CZD94gdInhFgMu7gAIySnG_LqCmxqgJnlxgua4KmnOKgIzNP9DztAipQ8A4DXwOdqsW6P66JRsMxW8HlTv9q4_ZNKHTraHzPnMGxnz1Aen3l3ozERnu3bog3dDl2kXvpw25-jUyjaZi9-7RG-P69fVJt--PD2vHra5opT3eWOZhapWnNKCVNKSppJAdV1ZUyrAYEvCdaMZpyUFaphkmjek1lSRMbGELtHVcXcXw-dgUi86l5RpW-lNGJIgtGQEWDmC7AiqGFKKxopddJ2MB4FBTNrE5ERMTkQF4kebKMba_bFmxif2zkSRlDNeGe3iaEro4P4f-AZrr3Zj
CitedBy_id crossref_primary_10_1021_jp013098s
crossref_primary_10_1021_jp035381s
crossref_primary_10_1016_j_jnucmat_2011_01_042
crossref_primary_10_1111_jace_19609
crossref_primary_10_1016_0022_3115_93_90038_Z
crossref_primary_10_1557_opl_2012_1162
crossref_primary_10_1016_S0925_8388_98_00098_X
crossref_primary_10_1016_j_elspec_2020_147030
crossref_primary_10_1111_jace_18249
Cites_doi 10.1515/zna-1959-0807
10.1103/PhysRev.130.1711
10.1016/0022-3115(73)90116-5
10.3327/jnst.12.314
10.1364/JOSA.49.001107
10.1111/j.1151-2916.1966.tb13182.x
10.1016/0022-3115(64)90120-5
10.1016/0022-3115(70)90217-5
10.1063/1.1777139
ContentType Journal Article
Copyright 1980
Copyright_xml – notice: 1980
DBID AAYXX
CITATION
7QQ
8FD
JG9
DOI 10.1016/0022-3115(80)90092-6
DatabaseName CrossRef
Ceramic Abstracts
Technology Research Database
Materials Research Database
DatabaseTitle CrossRef
Materials Research Database
Technology Research Database
Ceramic Abstracts
DatabaseTitleList
DeliveryMethod fulltext_linktorsrc
Discipline Engineering
Physics
EISSN 1873-4820
EndPage 184
ExternalDocumentID 10_1016_0022_3115_80_90092_6
0022311580900926
GroupedDBID --K
--M
-~X
.~1
0R~
1B1
1RT
1~.
1~5
29L
4.4
457
4G.
5GY
5VS
7-5
71M
8P~
9JN
AABXZ
AACTN
AAEDT
AAEDW
AAEPC
AAHCO
AAIAV
AAIKJ
AAKOC
AALRI
AAOAW
AAQFI
AAQXK
AARJD
AAXUO
ABFNM
ABJNI
ABMAC
ABNEU
ABXDB
ABXRA
ABYKQ
ACDAQ
ACFVG
ACGFS
ACIWK
ACNCT
ACNNM
ACRLP
ADBBV
ADEZE
ADMUD
AEBSH
AEKER
AENEX
AEZYN
AFKWA
AFRAH
AFRZQ
AFTJW
AGHFR
AGUBO
AGYEJ
AHHHB
AHIDL
AIEXJ
AIKHN
AITUG
AIVDX
AJBFU
AJOXV
ALMA_UNASSIGNED_HOLDINGS
AMFUW
AMRAJ
ASPBG
AVWKF
AXJTR
AZFZN
BELTK
BKOJK
BLXMC
CS3
DU5
EBS
EFJIC
EFLBG
EJD
EO8
EO9
EP2
EP3
FDB
FEDTE
FGOYB
FIRID
FNPLU
FYGXN
G-2
G-Q
GBLVA
HME
HVGLF
HZ~
IHE
J1W
JARJE
KOM
LY6
LY7
LZ3
M24
M41
MAGPM
MO0
N9A
O-L
O9-
OAUVE
OGIMB
OZT
P-8
P-9
P2P
PC.
Q38
R2-
RIG
RNS
ROL
RPZ
SAC
SDF
SDG
SES
SET
SEW
SHN
SMS
SPC
SPCBC
SPD
SSM
SSQ
SSR
SSZ
T5K
UHS
WUQ
XPP
ZMT
~02
~G-
AAXKI
AAYXX
AFJKZ
AKRWK
CITATION
7QQ
8FD
JG9
ID FETCH-LOGICAL-c335t-bf4f089c533628af2b8a03d98fe7c010f725dbd4537303e4a4d5b29d3c2725f23
ISSN 0022-3115
IngestDate Fri Aug 16 09:20:24 EDT 2024
Thu Sep 26 16:26:25 EDT 2024
Fri Feb 23 02:28:18 EST 2024
IsPeerReviewed true
IsScholarly true
Issue 1
Language English
LinkModel OpenURL
MergedId FETCHMERGED-LOGICAL-c335t-bf4f089c533628af2b8a03d98fe7c010f725dbd4537303e4a4d5b29d3c2725f23
Notes ObjectType-Article-2
SourceType-Scholarly Journals-1
ObjectType-Feature-1
content type line 23
PQID 23742047
PQPubID 23500
PageCount 4
ParticipantIDs proquest_miscellaneous_23742047
crossref_primary_10_1016_0022_3115_80_90092_6
elsevier_sciencedirect_doi_10_1016_0022_3115_80_90092_6
PublicationCentury 1900
PublicationDate 1980-01-01
PublicationDateYYYYMMDD 1980-01-01
PublicationDate_xml – month: 01
  year: 1980
  text: 1980-01-01
  day: 01
PublicationDecade 1980
PublicationTitle Journal of nuclear materials
PublicationYear 1980
Publisher Elsevier B.V
Publisher_xml – name: Elsevier B.V
References Yahia (BIB10) 1963; 130
Chereau, Wadier (BIB3) 1973; 46
Kofstad (BIB11) 1972
K. Naito, N. Kamegashira and T. Yutani, unpublished work.
Ishii, Naito, Oshima (BIB4) 1970; 35
McNeillly (BIB7) 1964; 11
Atlas, Schlehman, Readey (BIB2) 1966; 49
Jackson, Rand (BIB8) 1963
Rudolph (BIB9) 1959; 14a
Atlas, Schlehman (BIB1) 1966; Vol. II
Becker, Frederikse (BIB12) 1962; 33
Naito, Tsuji, Asakura (BIB5) 1975; 12
Ackermann, Thorn, Window (BIB13) 1959; 49
Naito (10.1016/0022-3115(80)90092-6_BIB5) 1975; 12
McNeillly (10.1016/0022-3115(80)90092-6_BIB7) 1964; 11
Yahia (10.1016/0022-3115(80)90092-6_BIB10) 1963; 130
Rudolph (10.1016/0022-3115(80)90092-6_BIB9) 1959; 14a
10.1016/0022-3115(80)90092-6_BIB6
Ishii (10.1016/0022-3115(80)90092-6_BIB4) 1970; 35
Chereau (10.1016/0022-3115(80)90092-6_BIB3) 1973; 46
Atlas (10.1016/0022-3115(80)90092-6_BIB1) 1966; Vol. II
Ackermann (10.1016/0022-3115(80)90092-6_BIB13) 1959; 49
Kofstad (10.1016/0022-3115(80)90092-6_BIB11) 1972
Atlas (10.1016/0022-3115(80)90092-6_BIB2) 1966; 49
Jackson (10.1016/0022-3115(80)90092-6_BIB8) 1963
Becker (10.1016/0022-3115(80)90092-6_BIB12) 1962; 33
References_xml – volume: Vol. II
  start-page: 407
  year: 1966
  ident: BIB1
  publication-title: Thermodynamics
  contributor:
    fullname: Schlehman
– volume: 130
  start-page: 1711
  year: 1963
  ident: BIB10
  publication-title: Phys. Rev.
  contributor:
    fullname: Yahia
– start-page: 137
  year: 1972
  ident: BIB11
  publication-title: Nonstoichiometry, Diffusion and Electrical Conductivity in Binary Metal Oxides
  contributor:
    fullname: Kofstad
– volume: 35
  start-page: 335
  year: 1970
  ident: BIB4
  publication-title: J. Nucl. Mater.
  contributor:
    fullname: Oshima
– volume: 49
  start-page: 1107
  year: 1959
  ident: BIB13
  publication-title: J. Opt. Soc. Am
  contributor:
    fullname: Window
– volume: 14a
  start-page: 727
  year: 1959
  ident: BIB9
  publication-title: Z. Naturforschung
  contributor:
    fullname: Rudolph
– year: 1963
  ident: BIB8
  publication-title: AERE-R-3636
  contributor:
    fullname: Rand
– volume: 12
  start-page: 314
  year: 1975
  ident: BIB5
  publication-title: J. Nucl. Sci. Technol.
  contributor:
    fullname: Asakura
– volume: 11
  start-page: 53
  year: 1964
  ident: BIB7
  publication-title: J. Nucl. Mater.
  contributor:
    fullname: McNeillly
– volume: 49
  start-page: 624
  year: 1966
  ident: BIB2
  publication-title: J. Am. Ceram. Soc.
  contributor:
    fullname: Readey
– volume: 33
  start-page: 447
  year: 1962
  ident: BIB12
  publication-title: J. Appl. Phys.
  contributor:
    fullname: Frederikse
– volume: 46
  start-page: l
  year: 1973
  ident: BIB3
  publication-title: J. Nucl. Mater.
  contributor:
    fullname: Wadier
– volume: 14a
  start-page: 727
  year: 1959
  ident: 10.1016/0022-3115(80)90092-6_BIB9
  publication-title: Z. Naturforschung
  doi: 10.1515/zna-1959-0807
  contributor:
    fullname: Rudolph
– volume: 130
  start-page: 1711
  year: 1963
  ident: 10.1016/0022-3115(80)90092-6_BIB10
  publication-title: Phys. Rev.
  doi: 10.1103/PhysRev.130.1711
  contributor:
    fullname: Yahia
– year: 1963
  ident: 10.1016/0022-3115(80)90092-6_BIB8
  publication-title: AERE-R-3636
  contributor:
    fullname: Jackson
– start-page: 137
  year: 1972
  ident: 10.1016/0022-3115(80)90092-6_BIB11
  contributor:
    fullname: Kofstad
– volume: 46
  start-page: l
  year: 1973
  ident: 10.1016/0022-3115(80)90092-6_BIB3
  publication-title: J. Nucl. Mater.
  doi: 10.1016/0022-3115(73)90116-5
  contributor:
    fullname: Chereau
– volume: Vol. II
  start-page: 407
  year: 1966
  ident: 10.1016/0022-3115(80)90092-6_BIB1
  contributor:
    fullname: Atlas
– volume: 12
  start-page: 314
  year: 1975
  ident: 10.1016/0022-3115(80)90092-6_BIB5
  publication-title: J. Nucl. Sci. Technol.
  doi: 10.3327/jnst.12.314
  contributor:
    fullname: Naito
– ident: 10.1016/0022-3115(80)90092-6_BIB6
– volume: 49
  start-page: 1107
  year: 1959
  ident: 10.1016/0022-3115(80)90092-6_BIB13
  publication-title: J. Opt. Soc. Am
  doi: 10.1364/JOSA.49.001107
  contributor:
    fullname: Ackermann
– volume: 49
  start-page: 624
  year: 1966
  ident: 10.1016/0022-3115(80)90092-6_BIB2
  publication-title: J. Am. Ceram. Soc.
  doi: 10.1111/j.1151-2916.1966.tb13182.x
  contributor:
    fullname: Atlas
– volume: 11
  start-page: 53
  year: 1964
  ident: 10.1016/0022-3115(80)90092-6_BIB7
  publication-title: J. Nucl. Mater.
  doi: 10.1016/0022-3115(64)90120-5
  contributor:
    fullname: McNeillly
– volume: 35
  start-page: 335
  year: 1970
  ident: 10.1016/0022-3115(80)90092-6_BIB4
  publication-title: J. Nucl. Mater.
  doi: 10.1016/0022-3115(70)90217-5
  contributor:
    fullname: Ishii
– volume: 33
  start-page: 447
  year: 1962
  ident: 10.1016/0022-3115(80)90092-6_BIB12
  publication-title: J. Appl. Phys.
  doi: 10.1063/1.1777139
  contributor:
    fullname: Becker
SSID ssj0005905
Score 1.2890326
Snippet The variation of the electrical conductivity with oxygen pressure has been measured for plutonium dioxide at temperatures between 950 and 1100°C and in the...
SourceID proquest
crossref
elsevier
SourceType Aggregation Database
Publisher
StartPage 181
Title Electrical conductivity anomaly in near-stoichiometric plutonium dioxide
URI https://dx.doi.org/10.1016/0022-3115(80)90092-6
https://search.proquest.com/docview/23742047
Volume 95
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1Bb9MwFLagExIcJhggBhvkwAFUBRzbSezjNHWq2CgSakVvVmzHWiXmTlsrTfv1PMdOE6BowCWKnMRt3uc8f07e-x5CbwUDEmq9yie1sEBhZZkq7UOgYGoWxKfNNIo3nyfFeMY-zfN5J-bfZJes1Ad9uzWv5H9QhTbA1WfJ_gOym06hAfYBX9gCwrD9K4xHTQ2bqPHhvHJrKAVRueVF9b3J6HMwklMgeAt97hPt_dnDS_hP8CivL4ZmsbxZmJ-jgTqG6rzWcXU1BFIb7qZ7RZAJjnuvCHoh-1nIm2zdXqhtGeGdpFnPi2WhikqcELNQw-03XxuW_Zu-gRD7aEWY3bAg6RZ568kXeTI7O5PT0Xx6H-0Q8Ax8gHaOTr9-O-2ickSIOm17bbMds-Ljpu0dx-_jr_yJTfwyrzZkYfoY7UYbJkcBsifoXu320KOe9uMeetDE3urrp2jcwZj0YUwijMnCJVtgTDYwJhHGZ2h2Mpoej9NY4CLVlOarVFlmMRcaKHdBeGWJ4hWmRnBblxoWyrYkuVGG5RT8MK1ZxUyuiDBUEzhiCX2OBm7p6hco0VjUpTHMcqyYpkRpzT17KxSrCOZqH6WtoeRl0DGRbYCfN6z0hpUcy8awsthHZWtNGblY4FgS4L_jyjet8SW4Kv_9qXL1cn0tCS0Zwax8eecZr9DDbhwfoMHqal0fAvlbqddxwPwA7KlXow
link.rule.ids 315,783,787,27938,27939
linkProvider Library Specific Holdings
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Electrical+conductivity+anomaly+in+near-stoichiometric+plutonium+dioxide&rft.jtitle=Journal+of+nuclear+materials&rft.date=1980-01-01&rft.issn=0022-3115&rft.volume=95&rft.issue=N-1&rft.spage=181&rft.epage=184&rft_id=info:doi/10.1016%2F0022-3115%2880%2990092-6&rft.externalDBID=NO_FULL_TEXT
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0022-3115&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0022-3115&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0022-3115&client=summon