Study on the different effects of aluminum doping on Fe-Mn and Ni-Mn based compounds as cathode material for sodium-ion batteries
Al-doped Fe-Mn and Ni-Mn based materials with P2-type layered structure has been synthesized and tested as a positive electrode material for rechargeable sodium batteries. The modification mechanisms of Al doping in Fe-Mn and Ni-Mn based materials have been discussed. The synthesized Al-doped Ni-Mn...
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| Published in | Journal of industrial and engineering chemistry (Seoul, Korea) Vol. 124; pp. 287 - 293 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
25.08.2023
한국공업화학회 |
| Subjects | |
| Online Access | Get full text |
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| Abstract | Al-doped Fe-Mn and Ni-Mn based materials with P2-type layered structure has been synthesized and tested as a positive electrode material for rechargeable sodium batteries. The modification mechanisms of Al doping in Fe-Mn and Ni-Mn based materials have been discussed. The synthesized Al-doped Ni-Mn based material Na0.67Mn0.8Ni0.16Al0.04O2 delivers a reversible capacity of 135.1 mAh g−1, which corresponds to 92.1% of the initial capacity with excellent cyclability for 200 cycles. What’s more, it can still remain a capacity of 96.2 mAh g−1 at a current density of 2000 mA g−1. When the voltage range increase to 1.5 – 4.3 V, its initial discharge capacity can reach 190.3 mAh g−1. |
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| AbstractList | Al-doped Fe-Mn and Ni-Mn based materials with P2-type layered structure has been synthesized and tested as a positive electrode material for rechargeable sodium batteries. The modification mechanisms of Al doping in Fe-Mn and Ni-Mn based materials have been discussed. The synthesized Al-doped Ni-Mn based material Na0.67Mn0.8Ni0.16Al0.04O2 delivers a reversible capacity of 135.1 mAh g−1, which corresponds to 92.1% of the initial capacity with excellent cyclability for 200 cycles. What’s more, it can still remain a capacity of 96.2 mAh g−1 at a current density of 2000 mA g−1. When the voltage range increase to 1.5 – 4.3 V, its initial discharge capacity can reach 190.3 mAh g−1. Al-doped Fe-Mn and Ni-Mn based materials with P2-type layered structure has been synthesized andtested as a positive electrode material for rechargeable sodium batteries. The modification mechanismsof Al doping in Fe-Mn and Ni-Mn based materials have been discussed. The synthesized Al-doped Ni-Mnbased material Na0.67Mn0.8Ni0.16Al0.04O2 delivers a reversible capacity of 135.1 mAh g1, which correspondsto 92.1% of the initial capacity with excellent cyclability for 200 cycles. What’s more, it can stillremain a capacity of 96.2 mAh g1 at a current density of 2000 mA g1. When the voltage range increaseto 1.5 – 4.3 V, its initial discharge capacity can reach 190.3 mAh g1. KCI Citation Count: 2 |
| Author | Wen, Lei Qiao, Danlei Su, Chang Liu, Guoqiang Wang, Qingxiang Zhang, Yixuan |
| Author_xml | – sequence: 1 givenname: Danlei surname: Qiao fullname: Qiao, Danlei organization: Key Laboratory for Ecological Metallurgy of Multimetallic Mineral (Ministry of Education), School of Metallurgy, Northeastern University, Shenyang 110819, China – sequence: 2 givenname: Yixuan surname: Zhang fullname: Zhang, Yixuan organization: Key Laboratory for Ecological Metallurgy of Multimetallic Mineral (Ministry of Education), School of Metallurgy, Northeastern University, Shenyang 110819, China – sequence: 3 givenname: Chang surname: Su fullname: Su, Chang organization: Key Laboratory for Ecological Metallurgy of Multimetallic Mineral (Ministry of Education), School of Metallurgy, Northeastern University, Shenyang 110819, China – sequence: 4 givenname: Guoqiang surname: Liu fullname: Liu, Guoqiang email: liugq@smm.neu.edu.cn organization: Key Laboratory for Ecological Metallurgy of Multimetallic Mineral (Ministry of Education), School of Metallurgy, Northeastern University, Shenyang 110819, China – sequence: 5 givenname: Qingxiang surname: Wang fullname: Wang, Qingxiang organization: Key Laboratory for Ecological Metallurgy of Multimetallic Mineral (Ministry of Education), School of Metallurgy, Northeastern University, Shenyang 110819, China – sequence: 6 givenname: Lei surname: Wen fullname: Wen, Lei email: leiwen@imr.ac.cn organization: Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, Liaoning, China |
| BackLink | https://www.kci.go.kr/kciportal/ci/sereArticleSearch/ciSereArtiView.kci?sereArticleSearchBean.artiId=ART002997061$$DAccess content in National Research Foundation of Korea (NRF) |
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| CitedBy_id | crossref_primary_10_1016_j_catcom_2023_106832 crossref_primary_10_1016_j_jiec_2024_10_058 crossref_primary_10_1021_acsami_4c15881 crossref_primary_10_1021_acs_energyfuels_4c05552 crossref_primary_10_1149_1945_7111_ad7291 crossref_primary_10_1016_j_est_2025_115909 crossref_primary_10_1016_j_mtcomm_2024_109552 |
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| Keywords | Fe-Mn based oxide P2-type cathode Al-substitution Electrochemical properties Sodium ion batteries Ni-Mn based oxide |
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| Snippet | Al-doped Fe-Mn and Ni-Mn based materials with P2-type layered structure has been synthesized and tested as a positive electrode material for rechargeable... Al-doped Fe-Mn and Ni-Mn based materials with P2-type layered structure has been synthesized andtested as a positive electrode material for rechargeable sodium... |
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| SubjectTerms | Al-substitution Electrochemical properties Fe-Mn based oxide Ni-Mn based oxide P2-type cathode Sodium ion batteries 화학공학 |
| Title | Study on the different effects of aluminum doping on Fe-Mn and Ni-Mn based compounds as cathode material for sodium-ion batteries |
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