Study of self-hydrogenation of ethene on clean Ni(111)

The surface composition of a Ni(111) face and the reaction products have been studied during hydogenation of ethene using Auger electron spectroscopy and mass spectrometry. The pressure range has been extended from UHV up to 10 −1 mbar by incorporation of a reaction chamber into a UHV system, which...

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Published inSurface science Vol. 126; no. 1; pp. 479 - 486
Main Authors Hasse, W., Günter, H.-L., Henzler, M.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.03.1983
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Abstract The surface composition of a Ni(111) face and the reaction products have been studied during hydogenation of ethene using Auger electron spectroscopy and mass spectrometry. The pressure range has been extended from UHV up to 10 −1 mbar by incorporation of a reaction chamber into a UHV system, which could be closed with a small orifice close to the mass spectrometer. The reaction was studied starting with a clean surface and avoiding any ion getter and Ti sublimation pumps. The ethene decomposes to acetylene and hydrogen up to half a monolayer. During additional exposure part of the adsorbed hydrogen is replaced by ethene and used for hydrogenation of another ethene molecule. The model is supported by measurements at temperatures up to 100°C. The measured coverages and rates are reproduced by model calculations revealing a high initial sticking coefficient and a low reaction probability during hydrogenation.
AbstractList The surface composition of a Ni(111) face and the reaction products have been studied during hydrogenation of ethene using Auger electron spectroscopy and mass spectrometry. The pressure range has been extended from UHV up to 10 exp --1 mbar by incorporation of a reaction chamber into a UHV system, which could be closed with a small orifice close to the mass spectrometer. The reaction was studied starting with a clean surface and avoiding any ion getter and Ti sublimation pumps. The ethene decomposes to acetylene and hydrogen up to half a monolayer. During additional exposure part of the adsorbed hydrogen is replaced by ethene and used for hydrogenation of another ethene molecule. The model is supported by measurements at temperatures up to 100 deg C. The measured coverages and rates are reproduced by model calculations revealing a high initial sticking coefficient and a low reaction probability during hydrogenation. 12 ref.--AA
The surface composition of a Ni(111) face and the reaction products have been studied during hydogenation of ethene using Auger electron spectroscopy and mass spectrometry. The pressure range has been extended from UHV up to 10 −1 mbar by incorporation of a reaction chamber into a UHV system, which could be closed with a small orifice close to the mass spectrometer. The reaction was studied starting with a clean surface and avoiding any ion getter and Ti sublimation pumps. The ethene decomposes to acetylene and hydrogen up to half a monolayer. During additional exposure part of the adsorbed hydrogen is replaced by ethene and used for hydrogenation of another ethene molecule. The model is supported by measurements at temperatures up to 100°C. The measured coverages and rates are reproduced by model calculations revealing a high initial sticking coefficient and a low reaction probability during hydrogenation.
Author Hasse, W.
Günter, H.-L.
Henzler, M.
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Cites_doi 10.1016/0039-6028(79)90061-X
10.1063/1.1680935
10.1016/0039-6028(79)90219-X
10.1016/0039-6028(79)90628-9
10.1016/0039-6028(78)90120-6
10.1016/0039-6028(79)90009-8
10.1524/zpch.1980.119.2.239
10.1016/0022-2860(80)80166-9
10.1016/0039-6028(78)90225-X
10.1016/0039-6028(77)90028-0
10.1016/0378-5963(80)90018-5
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References Demuth (BIB6) 1978; 76
Wedler, Brenk (BIB10) 1980; 119
Demuth, Ibach (BIB5) 1978; 78
Christmann, Schober, Ertl, Neumann (BIB11) 1974; 60
M.G. Gattania, M. Simonetta and M. Tescani, Surface Sci. 82 91979) L615.
Horiuti, Mijahara (BIB1) 1971
Krauser, Fadini, Rosemuller (BIB4) 1980; 66
Zuhr, Hudson (BIB7) 1977; 66
Klimesch, Henzler (BIB2) 1979; 90
Bertolini, Rousseau (BIB3) 1979; 83
Benninghoven, Beckmann, Greifendorf, Schemmer (BIB9) 1980; 6
Lehwald, Ibach (BIB8) 1979; 89
Klimesch (10.1016/0039-6028(83)90746-X_BIB2) 1979; 90
Bertolini (10.1016/0039-6028(83)90746-X_BIB3) 1979; 83
10.1016/0039-6028(83)90746-X_BIB12
Krauser (10.1016/0039-6028(83)90746-X_BIB4) 1980; 66
Demuth (10.1016/0039-6028(83)90746-X_BIB6) 1978; 76
Lehwald (10.1016/0039-6028(83)90746-X_BIB8) 1979; 89
Benninghoven (10.1016/0039-6028(83)90746-X_BIB9) 1980; 6
Wedler (10.1016/0039-6028(83)90746-X_BIB10) 1980; 119
Demuth (10.1016/0039-6028(83)90746-X_BIB5) 1978; 78
Horiuti (10.1016/0039-6028(83)90746-X_BIB1) 1971
Zuhr (10.1016/0039-6028(83)90746-X_BIB7) 1977; 66
Christmann (10.1016/0039-6028(83)90746-X_BIB11) 1974; 60
References_xml – volume: 66
  start-page: 405
  year: 1977
  ident: BIB7
  publication-title: Surface Sci.
  contributor:
    fullname: Hudson
– volume: 60
  start-page: 4528
  year: 1974
  ident: BIB11
  publication-title: J. Chem. Phys.
  contributor:
    fullname: Neumann
– volume: 76
  start-page: L603
  year: 1978
  ident: BIB6
  publication-title: Surface Sci.
  contributor:
    fullname: Demuth
– volume: 89
  start-page: 425
  year: 1979
  ident: BIB8
  publication-title: Surface Sci.
  contributor:
    fullname: Ibach
– volume: 78
  start-page: L238
  year: 1978
  ident: BIB5
  publication-title: Surface Sci.
  contributor:
    fullname: Ibach
– volume: 66
  start-page: 135
  year: 1980
  ident: BIB4
  publication-title: J. Mol. Struct.
  contributor:
    fullname: Rosemuller
– volume: 6
  start-page: 288
  year: 1980
  ident: BIB9
  publication-title: Appl. Surface Sci.
  contributor:
    fullname: Schemmer
– year: 1971
  ident: BIB1
  article-title: Hydrogenation of Ethylene on Metallic Catalysts
  contributor:
    fullname: Mijahara
– volume: 90
  start-page: 57
  year: 1979
  ident: BIB2
  publication-title: Surface Sci.
  contributor:
    fullname: Henzler
– volume: 119
  start-page: 239
  year: 1980
  ident: BIB10
  publication-title: Z. Physik. Chem. (NF)
  contributor:
    fullname: Brenk
– volume: 83
  start-page: 531
  year: 1979
  ident: BIB3
  publication-title: Surface Sci.
  contributor:
    fullname: Rousseau
– volume: 83
  start-page: 531
  year: 1979
  ident: 10.1016/0039-6028(83)90746-X_BIB3
  publication-title: Surface Sci.
  doi: 10.1016/0039-6028(79)90061-X
  contributor:
    fullname: Bertolini
– volume: 60
  start-page: 4528
  year: 1974
  ident: 10.1016/0039-6028(83)90746-X_BIB11
  publication-title: J. Chem. Phys.
  doi: 10.1063/1.1680935
  contributor:
    fullname: Christmann
– ident: 10.1016/0039-6028(83)90746-X_BIB12
  doi: 10.1016/0039-6028(79)90219-X
– volume: 89
  start-page: 425
  year: 1979
  ident: 10.1016/0039-6028(83)90746-X_BIB8
  publication-title: Surface Sci.
  doi: 10.1016/0039-6028(79)90628-9
  contributor:
    fullname: Lehwald
– year: 1971
  ident: 10.1016/0039-6028(83)90746-X_BIB1
  contributor:
    fullname: Horiuti
– volume: 76
  start-page: L603
  year: 1978
  ident: 10.1016/0039-6028(83)90746-X_BIB6
  publication-title: Surface Sci.
  doi: 10.1016/0039-6028(78)90120-6
  contributor:
    fullname: Demuth
– volume: 90
  start-page: 57
  year: 1979
  ident: 10.1016/0039-6028(83)90746-X_BIB2
  publication-title: Surface Sci.
  doi: 10.1016/0039-6028(79)90009-8
  contributor:
    fullname: Klimesch
– volume: 119
  start-page: 239
  year: 1980
  ident: 10.1016/0039-6028(83)90746-X_BIB10
  publication-title: Z. Physik. Chem. (NF)
  doi: 10.1524/zpch.1980.119.2.239
  contributor:
    fullname: Wedler
– volume: 66
  start-page: 135
  year: 1980
  ident: 10.1016/0039-6028(83)90746-X_BIB4
  publication-title: J. Mol. Struct.
  doi: 10.1016/0022-2860(80)80166-9
  contributor:
    fullname: Krauser
– volume: 78
  start-page: L238
  year: 1978
  ident: 10.1016/0039-6028(83)90746-X_BIB5
  publication-title: Surface Sci.
  doi: 10.1016/0039-6028(78)90225-X
  contributor:
    fullname: Demuth
– volume: 66
  start-page: 405
  year: 1977
  ident: 10.1016/0039-6028(83)90746-X_BIB7
  publication-title: Surface Sci.
  doi: 10.1016/0039-6028(77)90028-0
  contributor:
    fullname: Zuhr
– volume: 6
  start-page: 288
  year: 1980
  ident: 10.1016/0039-6028(83)90746-X_BIB9
  publication-title: Appl. Surface Sci.
  doi: 10.1016/0378-5963(80)90018-5
  contributor:
    fullname: Benninghoven
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Snippet The surface composition of a Ni(111) face and the reaction products have been studied during hydogenation of ethene using Auger electron spectroscopy and mass...
The surface composition of a Ni(111) face and the reaction products have been studied during hydrogenation of ethene using Auger electron spectroscopy and mass...
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