Synthesis and photophysical properties of poly(aryleneethynylene)s containing dibenzosilole unit

A series of poly(aryleneethynylene)s containing dibenzosilole unit has been synthesized by palladium-catalyzed Sonogashira cross-coupling reactions with 2,7-diethynyl-9,9-dihexyl-3,6-dimethoxy-9H-dibenzosilole (4) as the key monomer. Their photo-physical properties in solution were investigated. All...

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Published inChinese chemical letters Vol. 23; no. 11; pp. 1303 - 1306
Main Authors Yang, Qiang, Li, Liang Chun, Li, Shu Hong, Yue, Dong Mei, Xu, Cai Hong
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.11.2012
Beijing University of Chemical Technology, Beijing 100029, China%Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China%Department of Chemistry, School of Science, Beijing Technology and Business University, Beijing 100048, China
Subjects
Dibenzosilole
Photophysics
Poly(aryleneethynylene)s
Sonogashira cross-coupling
Poly(aryleneethynylene)s
Photophysics
Dibenzosilole
Sonogashira cross-coupling
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Abstract A series of poly(aryleneethynylene)s containing dibenzosilole unit has been synthesized by palladium-catalyzed Sonogashira cross-coupling reactions with 2,7-diethynyl-9,9-dihexyl-3,6-dimethoxy-9H-dibenzosilole (4) as the key monomer. Their photo-physical properties in solution were investigated. All of the polymers showed intense fluorescence with high quantum efficiencies.
AbstractList A series of poly(aryleneethynylene)s containing dibenzosilole unit has been synthesized by palladium-catalyzed Sonogashira cross-coupling reactions with 2,7-diethynyl-9,9-dihexyl-3,6-dimethoxy-9H-dibenzosilole (4) as the key monomer. Their photo-physical properties in solution were investigated. All of the polymers showed intense fluorescence with high quantum efficiencies.
Author Li, Liang Chun
Yue, Dong Mei
Li, Shu Hong
Yang, Qiang
Xu, Cai Hong
AuthorAffiliation Beijing University of Chemical Technology, Beijing 100029, China%Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China%Department of Chemistry, School of Science, Beijing Technology and Business University, Beijing 100048, China
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  givenname: Dong Mei
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  organization: Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
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CitedBy_id crossref_primary_10_1016_j_jorganchem_2016_04_004
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10.1002/asia.200800125
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Keywords Poly(aryleneethynylene)s
Photophysics
Dibenzosilole
Sonogashira cross-coupling
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Snippet A series of poly(aryleneethynylene)s containing dibenzosilole unit has been synthesized by palladium-catalyzed Sonogashira cross-coupling reactions with...
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SubjectTerms Dibenzosilole
Photophysics
Poly(aryleneethynylene)s
Sonogashira cross-coupling
Title Synthesis and photophysical properties of poly(aryleneethynylene)s containing dibenzosilole unit
URI https://dx.doi.org/10.1016/j.cclet.2012.09.017
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