Introduction to Raman microscopy of prehistoric rock paintings from the Sierra de las Cuerdas, Cuenca, Spain
Selected pictographs from the prehistoric painting panel 2 of Cueva del Tío Modesto shelter in the Sierra de las Cuerdas (Henarejos, Cuenca, Spain) were studied by Raman microscopy in order to determine the chemical composition of the pigments used. Hematite (α‐Fe2O3) was found as the main component...
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| Published in | Journal of Raman spectroscopy Vol. 37; no. 10; pp. 1054 - 1062 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
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Chichester, UK
John Wiley & Sons, Ltd
01.10.2006
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| Abstract | Selected pictographs from the prehistoric painting panel 2 of Cueva del Tío Modesto shelter in the Sierra de las Cuerdas (Henarejos, Cuenca, Spain) were studied by Raman microscopy in order to determine the chemical composition of the pigments used. Hematite (α‐Fe2O3) was found as the main component. The hematite particle size of one motif is much smaller than that observed for the others. No binders were found. A blue‐greyish crust extends over the whole panel. Whewellite, weddellite and amorphous carbon were identified in this crust. The Triassic sandstone on which the paintings are made is found to suffer from a flaking process. Therefore, flakes of the rocky substratum were studied, and α‐quartz, whewellite, magnetite and gypsum were found. A micro‐stratigraphic study of the flakes revealed channels of gypsum from one side of the flake to the other. This result supports the mechanism proposed for this sandstone weathering process. Copyright © 2006 John Wiley & Sons, Ltd. |
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| AbstractList | Selected pictographs from the prehistoric painting panel 2 of Cueva del Tio Modesto shelter in the Sierra de las Cuerdas (Henarejos, Cuenca, Spain) were studied by Raman microscopy in order to determine the chemical composition of the pigments used. Hematite (-Fe2O3) was found as the main component. The hematite particle size of one motif is much smaller than that observed for the others. No binders were found. A blue-greyish crust extends over the whole panel. Whewellite, weddellite and amorphous carbon were identified in this crust. The Triassic sandstone on which the paintings are made is found to suffer from a flaking process. Therefore, flakes of the rocky substratum were studied, and -quartz, whewellite, magnetite and gypsum were found. A micro-stratigraphic study of the flakes revealed channels of gypsum from one side of the flake to the other. This result supports the mechanism proposed for this sandstone weathering process. Abstract Selected pictographs from the prehistoric painting panel 2 of Cueva del Tío Modesto shelter in the Sierra de las Cuerdas (Henarejos, Cuenca, Spain) were studied by Raman microscopy in order to determine the chemical composition of the pigments used. Hematite (α‐Fe 2 O 3 ) was found as the main component. The hematite particle size of one motif is much smaller than that observed for the others. No binders were found. A blue‐greyish crust extends over the whole panel. Whewellite, weddellite and amorphous carbon were identified in this crust. The Triassic sandstone on which the paintings are made is found to suffer from a flaking process. Therefore, flakes of the rocky substratum were studied, and α‐quartz, whewellite, magnetite and gypsum were found. A micro‐stratigraphic study of the flakes revealed channels of gypsum from one side of the flake to the other. This result supports the mechanism proposed for this sandstone weathering process. Copyright © 2006 John Wiley & Sons, Ltd. Selected pictographs from the prehistoric painting panel 2 of Cueva del Tío Modesto shelter in the Sierra de las Cuerdas (Henarejos, Cuenca, Spain) were studied by Raman microscopy in order to determine the chemical composition of the pigments used. Hematite (α‐Fe2O3) was found as the main component. The hematite particle size of one motif is much smaller than that observed for the others. No binders were found. A blue‐greyish crust extends over the whole panel. Whewellite, weddellite and amorphous carbon were identified in this crust. The Triassic sandstone on which the paintings are made is found to suffer from a flaking process. Therefore, flakes of the rocky substratum were studied, and α‐quartz, whewellite, magnetite and gypsum were found. A micro‐stratigraphic study of the flakes revealed channels of gypsum from one side of the flake to the other. This result supports the mechanism proposed for this sandstone weathering process. Copyright © 2006 John Wiley & Sons, Ltd. |
| Author | Gavira-Vallejo, José M. Hernanz, Antonio Ruiz-López, Juan F. |
| Author_xml | – sequence: 1 givenname: Antonio surname: Hernanz fullname: Hernanz, Antonio email: ahernanz@ccia.uned.es organization: Departamento de Ciencias y Técnicas Fisicoquímicas, Facultad de Ciencias, Universidad Nacional de Educación a Distancia (UNED), Senda del Rey 9, E-28040 Madrid, Spain – sequence: 2 givenname: José M. surname: Gavira-Vallejo fullname: Gavira-Vallejo, José M. organization: Departamento de Ciencias y Técnicas Fisicoquímicas, Facultad de Ciencias, Universidad Nacional de Educación a Distancia (UNED), Senda del Rey 9, E-28040 Madrid, Spain – sequence: 3 givenname: Juan F. surname: Ruiz-López fullname: Ruiz-López, Juan F. organization: Departamento de Prehistoria y Arqueología, Facultad de Geografía e Historia, UNED, Senda del Rey 7, E-28040 Madrid, Spain |
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| Cites_doi | 10.1016/S1296-2074(02)01178-0 10.1016/S1296-2074(02)01234-7 10.1016/0371-1951(64)80165-X 10.1111/1475-4754.00029 10.1002/(SICI)1097-4555(199711)28:11<873::AID-JRS177>3.0.CO;2-B 10.1080/014904500270495 10.1021/bk-2002-0831.ch003 10.1016/S1386-1425(03)00070-2 10.1002/(SICI)1520-6343(1997)3:5<347::AID-BSPY3>3.0.CO;2-# 10.1016/S1386-1425(00)00495-9 10.1180/mono-4.16 10.1002/jrs.1052 10.1039/b306991p 10.1039/b501585e 10.1179/sic.1999.44.2.91 10.1002/(SICI)1097-4555(199906)30:6<421::AID-JRS385>3.0.CO;2-U 10.1007/BF00775287 10.1127/zfg/34/1990/165 10.1002/(SICI)1097-4555(199904)30:4<347::AID-JRS379>3.0.CO;2-A 10.1016/j.aca.2004.04.036 10.1016/0022-2860(91)85070-J 10.1088/0957-0233/14/9/310 10.1016/0009-2541(73)90005-3 10.1046/j.1469-8137.2000.00573.x 10.1017/S0033822200032124 10.1016/S0022-2860(00)00389-6 10.1539/joh.45.94 10.1006/qres.1996.0041 10.1002/(SICI)1520-6343(1997)3:5<331::AID-BSPY2>3.0.CO;2-5 10.1007/BF00000875 |
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| Snippet | Selected pictographs from the prehistoric painting panel 2 of Cueva del Tío Modesto shelter in the Sierra de las Cuerdas (Henarejos, Cuenca, Spain) were... Abstract Selected pictographs from the prehistoric painting panel 2 of Cueva del Tío Modesto shelter in the Sierra de las Cuerdas (Henarejos, Cuenca, Spain)... Selected pictographs from the prehistoric painting panel 2 of Cueva del Tio Modesto shelter in the Sierra de las Cuerdas (Henarejos, Cuenca, Spain) were... |
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| SubjectTerms | Flakes Gypsum Hematite Microscopy Panels pigments Prehistoric prehistoric paintings Raman microscopy Sandstone |
| Title | Introduction to Raman microscopy of prehistoric rock paintings from the Sierra de las Cuerdas, Cuenca, Spain |
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