Influence of structural parameters on the degradation of ultrahigh-molecular-weight vinyl-type network-polymer precursors during elution through size exclusion chromatography columns

• Published in: Journal of applied polymer science Vol. 90; no. 2; pp. 577 - 582
• Main Authors: Ikeda, Jun-Ichi, Oe, Hiroaki, Aota, Hiroyuki, Matsumoto, Akira
• Format: Journal Article
• Language: English
• Published: Hoboken Wiley Subscription Services, Inc., A Wiley Company 10.10.2003; Wiley
• Subjects: Applied sciences; branched; Chemical reactions and properties; copolymerization; crosslinking; Degradation; Exact sciences and technology; networks; Organic polymers; Physicochemistry of polymers; Structure effect; copolymerization; Elution; Molecular structure; Crosslink density; Solution copolymerization; networks; Benzoic derivative copolymer; Gel permeation chromatography; Crosslinked copolymer; Degradation; Acrylate copolymer; Prepolymer; Methacrylate copolymer; Radical copolymerization; Adipate copolymer; Vinylidene derivative copolymer; branched; crosslinking

Network‐polymer precursors obtained in various crosslinking monovinyl/divinyl copolymerization systems, including benzyl methacrylate/1,6‐hexanediol dimethacrylate, benzyl acrylate (BzA)/1,6‐hexanediol diacrylate (HDDA), and vinyl benzoate/divinyl adipate, were subjected to degradation during elutio...