New optimized triazene radical initiators for thermal polymerization
[Display omitted] New phenyl-triazine-containing thermal radical initiators (TRIs), namely 3,3-dimethyl-1-phenyltriazene (BTAM), 3,3-diethyl-1-phenyltriazene (BTAE), 2,2,6,6-tetramethyl-1-(phenyldiazenyl)piperidine (BTACM), 2,2,6,6-tetramethyl-1-(phenyldiazenyl)piperidin-4-ol (BTACH−OH), and 2,2,6,-...
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| Published in | Journal of industrial and engineering chemistry (Seoul, Korea) Vol. 79; pp. 274 - 278 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
25.11.2019
한국공업화학회 |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1226-086X 1876-794X |
| DOI | 10.1016/j.jiec.2019.06.053 |
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| Abstract | [Display omitted]
New phenyl-triazine-containing thermal radical initiators (TRIs), namely 3,3-dimethyl-1-phenyltriazene (BTAM), 3,3-diethyl-1-phenyltriazene (BTAE), 2,2,6,6-tetramethyl-1-(phenyldiazenyl)piperidine (BTACM), 2,2,6,6-tetramethyl-1-(phenyldiazenyl)piperidin-4-ol (BTACH−OH), and 2,2,6,-tetramethyl-1-(phenyldiazenyl)piperidin-4-ol (BTACM−OH), were designed and synthesized for use in radical polymerization. The method used to synthesize the initiators was simple, and the synthesized initiators did not change the color of the polymer. For these five new initiators as well as four related previously designed ones, the polymerization conversion rate was in each case over 92%. BTACM, which also included a six-membered aliphatic ring substituted with two dimethyl groups, showed a polymerization time 81.9% less than that without initiator and showed according to DSC experiments the lowest peak polymerization temperature of 137°C. These results represent a new promising thermal initiator system expected to be effective for various applications, especially those involving polymer coating. |
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| AbstractList | New phenyl-triazine-containing thermal radical initiators (TRIs), namely 3,3-dimethyl-1-phenyltriazene(BTAM), 3,3-diethyl-1-phenyltriazene (BTAE), 2,2,6,6-tetramethyl-1-(phenyldiazenyl)piperidine (BTACM),2,2,6,6-tetramethyl-1-(phenyldiazenyl)piperidin-4-ol (BTACH OH), and 2,2,6,-tetramethyl-1-(phenyldia-zenyl)piperidin-4-ol (BTACM OH), were designed and synthesized for use in radical polymerization. Themethod used to synthesize the initiators was simple, and the synthesized initiators did not change the colorof the polymer. For thesefive new initiators as well as four related previously designed ones, thepolymerization conversion rate was in each case over 92%. BTACM, which also included a six-memberedaliphatic ring substituted with two dimethyl groups, showed a polymerization time 81.9% less than thatwithout initiatorand showed according to DSC experiments the lowest peak polymerization temperature of137 C. These results represent a new promising thermal initiator system expected to be effective for variousapplications, especially those involving polymer coating. KCI Citation Count: 1 [Display omitted] New phenyl-triazine-containing thermal radical initiators (TRIs), namely 3,3-dimethyl-1-phenyltriazene (BTAM), 3,3-diethyl-1-phenyltriazene (BTAE), 2,2,6,6-tetramethyl-1-(phenyldiazenyl)piperidine (BTACM), 2,2,6,6-tetramethyl-1-(phenyldiazenyl)piperidin-4-ol (BTACH−OH), and 2,2,6,-tetramethyl-1-(phenyldiazenyl)piperidin-4-ol (BTACM−OH), were designed and synthesized for use in radical polymerization. The method used to synthesize the initiators was simple, and the synthesized initiators did not change the color of the polymer. For these five new initiators as well as four related previously designed ones, the polymerization conversion rate was in each case over 92%. BTACM, which also included a six-membered aliphatic ring substituted with two dimethyl groups, showed a polymerization time 81.9% less than that without initiator and showed according to DSC experiments the lowest peak polymerization temperature of 137°C. These results represent a new promising thermal initiator system expected to be effective for various applications, especially those involving polymer coating. |
| Author | Noh, Seung Man Kim, Beomjin Jeong, Jinwook Park, Young Il Park, Jongwook Kang, Seokwoo |
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New phenyl-triazine-containing thermal radical initiators (TRIs), namely 3,3-dimethyl-1-phenyltriazene (BTAM), 3,3-diethyl-1-phenyltriazene... New phenyl-triazine-containing thermal radical initiators (TRIs), namely 3,3-dimethyl-1-phenyltriazene(BTAM), 3,3-diethyl-1-phenyltriazene (BTAE),... |
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| SubjectTerms | Thermal polymerization Thermal radical initiator Triazene initiator 화학공학 |
| Title | New optimized triazene radical initiators for thermal polymerization |
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