Measurement of ion transport in soils by a radioabsorption method
The transport of ions was investigated in industrial bentonites, montmorillonites, in soils of different nature and in soils of original structure using radioactive isotopes by a radioabsorption method. The effective diffusion coefficient and activation energy characteristic of the transport process...
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Published in | Colloids and surfaces Vol. 54; no. 1-2; pp. 61 - 74 |
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Main Author | |
Format | Journal Article |
Language | English |
Published |
Amsterdam
Elsevier B.V
1991
Elsevier |
Subjects | |
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Abstract | The transport of ions was investigated in industrial bentonites, montmorillonites, in soils of different nature and in soils of original structure using radioactive isotopes by a radioabsorption method. The effective diffusion coefficient and activation energy characteristic of the transport process were determined.
The radioabsorption method sensitively follows the micromigration of radioactive ions in soils; it is rapid, applicable to the determination of diffusion coefficients in a wide range (10
−18-10
−9 m
2 s
−1), gives results with good reproducibility (Sd 30%) and makes possible the comprehensive investigation of factors influencing transport processes in soils. |
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AbstractList | The transport of ions was investigated in industrial bentonites, montmorillonites, in soils of different nature and in soils of original structure using radioactive isotopes by a radioabsorption method. The effective diffusion coefficient and activation energy characteristic of the transport process were determined.
The radioabsorption method sensitively follows the micromigration of radioactive ions in soils; it is rapid, applicable to the determination of diffusion coefficients in a wide range (10
−18-10
−9 m
2 s
−1), gives results with good reproducibility (Sd 30%) and makes possible the comprehensive investigation of factors influencing transport processes in soils. |
Author | Varró, Tibor |
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Copyright | 1991 1991 INIST-CNRS |
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Keywords | Clay Montmorillonite Ion transport Experimental study Alkaline earth metal Ions Transition metal Ions Bentonite Alkali metal Ions Ion exchanger Diffusion coefficient Ion exchange Thermodynamic properties Activation energy |
Language | English |
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References | Nye (BIB7) 1979; 31 Krjukov, Zhuhovickij (BIB16) 1953; 90 Porter, Kemper, Jackson, Stewart (BIB8) 1960; 24 Bresler (BIB4) 1973 Warneke, Barber (BIB10) 1972; 36 Lai, Mortland (BIB17) 1961; 25 Baligar, Barber (BIB3) 1978; 42 Anderson, Richards (BIB13) 1946 Zimen, Johansson, Hillert (BIB14) 1950 Greenland, Hayes (BIB6) 1981 Rajan (BIB9) 1978; 42 Bolt (BIB2) 1979 M.T. Beck, I. Országh and G. Rábai, Hung. Pat., 1. 26. 1979. Chao, Harward, Fang (BIB5) 1965; 99 Hevesy, Seith (BIB12) 1929; 56 Lapidus, Amundson (BIB1) 1952; 66 Sparks (BIB11) 1986 Lindner, Johansson (BIB15) 1950; 4 Bolt (10.1016/0166-6622(91)80049-T_BIB2) 1979 10.1016/0166-6622(91)80049-T_BIB18 Baligar (10.1016/0166-6622(91)80049-T_BIB3) 1978; 42 Lai (10.1016/0166-6622(91)80049-T_BIB17) 1961; 25 Anderson (10.1016/0166-6622(91)80049-T_BIB13) 1946 Krjukov (10.1016/0166-6622(91)80049-T_BIB16) 1953; 90 Greenland (10.1016/0166-6622(91)80049-T_BIB6) 1981 Rajan (10.1016/0166-6622(91)80049-T_BIB9) 1978; 42 Zimen (10.1016/0166-6622(91)80049-T_BIB14) 1950 Hevesy (10.1016/0166-6622(91)80049-T_BIB12) 1929; 56 Lapidus (10.1016/0166-6622(91)80049-T_BIB1) 1952; 66 Chao (10.1016/0166-6622(91)80049-T_BIB5) 1965; 99 Lindner (10.1016/0166-6622(91)80049-T_BIB15) 1950; 4 Bresler (10.1016/0166-6622(91)80049-T_BIB4) 1973 Nye (10.1016/0166-6622(91)80049-T_BIB7) 1979; 31 Warneke (10.1016/0166-6622(91)80049-T_BIB10) 1972; 36 Sparks (10.1016/0166-6622(91)80049-T_BIB11) 1986 Porter (10.1016/0166-6622(91)80049-T_BIB8) 1960; 24 |
References_xml | – volume: 56 start-page: 790 year: 1929 ident: BIB12 publication-title: Z. Phys. contributor: fullname: Seith – year: 1979 ident: BIB2 publication-title: Soil Chemistry contributor: fullname: Bolt – volume: 24 start-page: 460 year: 1960 ident: BIB8 publication-title: Soil Sci. Soc. Am. J. contributor: fullname: Stewart – volume: 25 start-page: 353 year: 1961 ident: BIB17 publication-title: Soil Sci. Soc. Am. Proc. contributor: fullname: Mortland – volume: 66 start-page: 984 year: 1952 ident: BIB1 publication-title: J. Phys. Chem. contributor: fullname: Amundson – start-page: 392 year: 1950 ident: BIB14 publication-title: J. Chem. Soc. contributor: fullname: Hillert – volume: 42 start-page: 39 year: 1978 ident: BIB9 publication-title: Soil Sci. Soc. Am. J. contributor: fullname: Rajan – volume: 4 start-page: 307 year: 1950 ident: BIB15 publication-title: Acta Chem. Scand. contributor: fullname: Johansson – year: 1981 ident: BIB6 publication-title: The Chemistry of Soil Processes contributor: fullname: Hayes – start-page: 537 year: 1946 ident: BIB13 publication-title: J. Chem. Soc. contributor: fullname: Richards – volume: 42 start-page: 251 year: 1978 ident: BIB3 publication-title: Soil Sci. Soc. Am. J. contributor: fullname: Barber – volume: 36 start-page: 39 year: 1972 ident: BIB10 publication-title: Soil Sci. Soc. Am. Proc. contributor: fullname: Barber – year: 1986 ident: BIB11 publication-title: Soil Physical Chemistry contributor: fullname: Sparks – volume: 90 start-page: 379 year: 1953 ident: BIB16 publication-title: Dokl. Akad. Nauk. USSR contributor: fullname: Zhuhovickij – volume: 99 start-page: 104 year: 1965 ident: BIB5 publication-title: Soil Sci. contributor: fullname: Fang – volume: 31 start-page: 225 year: 1979 ident: BIB7 publication-title: Adv. Agron. contributor: fullname: Nye – start-page: 72 year: 1973 end-page: 83 ident: BIB4 publication-title: Ecological Studies contributor: fullname: Bresler – year: 1981 ident: 10.1016/0166-6622(91)80049-T_BIB6 contributor: fullname: Greenland – ident: 10.1016/0166-6622(91)80049-T_BIB18 – volume: 36 start-page: 39 year: 1972 ident: 10.1016/0166-6622(91)80049-T_BIB10 publication-title: Soil Sci. Soc. Am. Proc. doi: 10.2136/sssaj1972.03615995003600010008x contributor: fullname: Warneke – start-page: 72 year: 1973 ident: 10.1016/0166-6622(91)80049-T_BIB4 contributor: fullname: Bresler – volume: 42 start-page: 39 year: 1978 ident: 10.1016/0166-6622(91)80049-T_BIB9 publication-title: Soil Sci. Soc. Am. J. doi: 10.2136/sssaj1978.03615995004200010009x contributor: fullname: Rajan – start-page: 537 year: 1946 ident: 10.1016/0166-6622(91)80049-T_BIB13 publication-title: J. Chem. Soc. doi: 10.1039/jr9460000537 contributor: fullname: Anderson – volume: 24 start-page: 460 year: 1960 ident: 10.1016/0166-6622(91)80049-T_BIB8 publication-title: Soil Sci. Soc. Am. J. doi: 10.2136/sssaj1960.03615995002400060014x contributor: fullname: Porter – year: 1979 ident: 10.1016/0166-6622(91)80049-T_BIB2 contributor: fullname: Bolt – volume: 99 start-page: 104 year: 1965 ident: 10.1016/0166-6622(91)80049-T_BIB5 publication-title: Soil Sci. doi: 10.1097/00010694-196502000-00007 contributor: fullname: Chao – start-page: 392 year: 1950 ident: 10.1016/0166-6622(91)80049-T_BIB14 publication-title: J. Chem. Soc. contributor: fullname: Zimen – volume: 56 start-page: 790 year: 1929 ident: 10.1016/0166-6622(91)80049-T_BIB12 publication-title: Z. Phys. doi: 10.1007/BF01340139 contributor: fullname: Hevesy – volume: 31 start-page: 225 year: 1979 ident: 10.1016/0166-6622(91)80049-T_BIB7 publication-title: Adv. Agron. doi: 10.1016/S0065-2113(08)60141-8 contributor: fullname: Nye – volume: 4 start-page: 307 year: 1950 ident: 10.1016/0166-6622(91)80049-T_BIB15 publication-title: Acta Chem. Scand. doi: 10.3891/acta.chem.scand.04-0307 contributor: fullname: Lindner – volume: 90 start-page: 379 year: 1953 ident: 10.1016/0166-6622(91)80049-T_BIB16 publication-title: Dokl. Akad. Nauk. USSR contributor: fullname: Krjukov – volume: 66 start-page: 984 year: 1952 ident: 10.1016/0166-6622(91)80049-T_BIB1 publication-title: J. Phys. Chem. doi: 10.1021/j150500a014 contributor: fullname: Lapidus – volume: 25 start-page: 353 year: 1961 ident: 10.1016/0166-6622(91)80049-T_BIB17 publication-title: Soil Sci. Soc. Am. Proc. doi: 10.2136/sssaj1961.03615995002500050014x contributor: fullname: Lai – volume: 42 start-page: 251 year: 1978 ident: 10.1016/0166-6622(91)80049-T_BIB3 publication-title: Soil Sci. Soc. Am. J. doi: 10.2136/sssaj1978.03615995004200020008x contributor: fullname: Baligar – year: 1986 ident: 10.1016/0166-6622(91)80049-T_BIB11 contributor: fullname: Sparks |
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SubjectTerms | Chemistry Exact sciences and technology General and physical chemistry Ion-exchange Surface physical chemistry |
Title | Measurement of ion transport in soils by a radioabsorption method |
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