Sorption studies of toxic cations on ginger root adsorbent

This research reports the feasibility of using pristine ginger root (PGR), base treated ginger root (BTGR) and acid treated ginger root (ATGR) adsorbents to simultaneously remove Cu(II), Pb(II) and Ni(II) ions from aqueous solution under different experimental parameters by batch method. Different s...

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Published inJournal of industrial and engineering chemistry (Seoul, Korea) Vol. 76; pp. 133 - 140
Main Authors Shooto, Ntaote David, Naidoo, Eliazer Bobby, Maubane, Manoko
Format Journal Article
LanguageEnglish
Published Elsevier B.V 25.08.2019
한국공업화학회
Subjects
Adsorption
Equilibrium
Ginger
Heavy metals
Kinetics
화학공학
Ginger
Kinetics
Adsorption
Equilibrium
Heavy metals
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Abstract This research reports the feasibility of using pristine ginger root (PGR), base treated ginger root (BTGR) and acid treated ginger root (ATGR) adsorbents to simultaneously remove Cu(II), Pb(II) and Ni(II) ions from aqueous solution under different experimental parameters by batch method. Different system parameters such as the effect of metal concentration, time dependent studies and temperature effect were evaluated. The sorption trend indicated that the pretreated adsorbents; ATGR and BTGR had better performance than PGR. The sorption of Cu(II), Ni(II) and Pb(II) ions onto BTGR is 16.3, 18.9 and 17.6 mg/g onto ATGR is 15.3, 18.6 and 17.5 mg/g and onto PGR is 1.8, 1.9 and 1.9 mg/g respectively. The overall Cu/Ni/Pb ions sorption trend for the adsorbents is BTGR > ATGR > PGR. Freundlich isotherm best describes all the sorption processes in this work. The sorption rate results of Ni(II) ions was much faster than those of Pb(II) and Cu(II) in all the adsorbents. The good unity fits of PSO data suggests that Cu(II), Ni(II) and Pb(II) is better described by this model and the sorption mechanism is based on electrostatic interactions and adsorption sites. The ΔG° data gave negative values for all samples; suggesting that the sorption processes were spontaneous. The positive ΔS° figures indicated that the degree of freedom for Cu(II), Ni(II) and Pb(II) ions was not restricted on PGR, ATGR and BTGR adsorbents.
AbstractList This research reports the feasibility of using pristine ginger root (PGR), base treated ginger root (BTGR)and acid treated ginger root (ATGR) adsorbents to simultaneously remove Cu(II), Pb(II) and Ni(II) ionsfrom aqueous solution under different experimental parameters by batch method. Different systemparameters such as the effect of metal concentration, time dependent studies and temperature effectwere evaluated. The sorption trend indicated that the pretreated adsorbents; ATGR and BTGR had betterperformance than PGR. The sorption of Cu(II), Ni(II) and Pb(II) ions onto BTGR is 16.3, 18.9 and 17.6 mg/gonto ATGR is 15.3, 18.6 and 17.5 mg/g and onto PGR is 1.8, 1.9 and 1.9 mg/g respectively. The overall Cu/Ni/Pb ions sorption trend for the adsorbents is BTGR > ATGR > PGR. Freundlich isotherm best describes allthe sorption processes in this work. The sorption rate results of Ni(II) ions was much faster than those ofPb(II) and Cu(II) in all the adsorbents. The good unityfits of PSO data suggests that Cu(II), Ni(II) and Pb(II)is better described by this model and the sorption mechanism is based on electrostatic interactions andadsorption sites. The DG data gave negative values for all samples; suggesting that the sorptionprocesses were spontaneous. The positive DS figures indicated that the degree of freedom for Cu(II), Ni(II) and Pb(II) ions was not restricted on PGR, ATGR and BTGR adsorbents. KCI Citation Count: 10
This research reports the feasibility of using pristine ginger root (PGR), base treated ginger root (BTGR) and acid treated ginger root (ATGR) adsorbents to simultaneously remove Cu(II), Pb(II) and Ni(II) ions from aqueous solution under different experimental parameters by batch method. Different system parameters such as the effect of metal concentration, time dependent studies and temperature effect were evaluated. The sorption trend indicated that the pretreated adsorbents; ATGR and BTGR had better performance than PGR. The sorption of Cu(II), Ni(II) and Pb(II) ions onto BTGR is 16.3, 18.9 and 17.6 mg/g onto ATGR is 15.3, 18.6 and 17.5 mg/g and onto PGR is 1.8, 1.9 and 1.9 mg/g respectively. The overall Cu/Ni/Pb ions sorption trend for the adsorbents is BTGR > ATGR > PGR. Freundlich isotherm best describes all the sorption processes in this work. The sorption rate results of Ni(II) ions was much faster than those of Pb(II) and Cu(II) in all the adsorbents. The good unity fits of PSO data suggests that Cu(II), Ni(II) and Pb(II) is better described by this model and the sorption mechanism is based on electrostatic interactions and adsorption sites. The ΔG° data gave negative values for all samples; suggesting that the sorption processes were spontaneous. The positive ΔS° figures indicated that the degree of freedom for Cu(II), Ni(II) and Pb(II) ions was not restricted on PGR, ATGR and BTGR adsorbents.
Author Shooto, Ntaote David
Maubane, Manoko
Naidoo, Eliazer Bobby
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Kinetics
Adsorption
Equilibrium
Heavy metals
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한국공업화학회
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Snippet This research reports the feasibility of using pristine ginger root (PGR), base treated ginger root (BTGR) and acid treated ginger root (ATGR) adsorbents to...
This research reports the feasibility of using pristine ginger root (PGR), base treated ginger root (BTGR)and acid treated ginger root (ATGR) adsorbents to...
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SubjectTerms Adsorption
Equilibrium
Ginger
Heavy metals
Kinetics
화학공학
Title Sorption studies of toxic cations on ginger root adsorbent
URI https://dx.doi.org/10.1016/j.jiec.2019.02.027
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