Preparation and characterization of polystyrene films containing PbS nanoparticles
Lead sulfide, a narrow band gap semiconductor (Eg = 0.41 eV at room temperature), is very sensitive to finite size effects due to a large exciton Bohr radius (180 A). Since a large blue shift occurs when the size of the PbS nanoparticles falls below the radius of the bulk exciton, this offers the po...
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| Published in | Journal of materials science Vol. 40; no. 16; pp. 4407 - 4409 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Heidelberg
Springer
01.08.2005
Springer Nature B.V |
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| Online Access | Get full text |
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| Abstract | Lead sulfide, a narrow band gap semiconductor (Eg = 0.41 eV at room temperature), is very sensitive to finite size effects due to a large exciton Bohr radius (180 A). Since a large blue shift occurs when the size of the PbS nanoparticles falls below the radius of the bulk exciton, this offers the possibility to adjust their optical properties in the spectral region between 1 and 2 mm, which is important for many technological applications In the present letter we suggest a procedure for the incorporation PbS nanoparticles in a polystyrene (PS) matrix. The method is based on the thermal decomposition of a lead xanthate complex within the solid polymer. |
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| AbstractList | Lead sulfide, a narrow band gap semiconductor (Eg = 0.41 eV at room temperature), is very sensitive to finite size effects due to a large exciton Bohr radius (180 A). Since a large blue shift occurs when the size of the PbS nanoparticles falls below the radius of the bulk exciton, this offers the possibility to adjust their optical properties in the spectral region between 1 and 2 mm, which is important for many technological applications In the present letter we suggest a procedure for the incorporation PbS nanoparticles in a polystyrene (PS) matrix. The method is based on the thermal decomposition of a lead xanthate complex within the solid polymer. |
| Author | LUYT, A. S REVAPRASADU, N SREEKUMARI NAIR, P RADHAKRISHNAN, T KOLAWOLE, G. A DJOKOVIC, V |
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| Cites_doi | 10.1021/la990780t 10.1021/cm034505a 10.1021/cm990425o 10.1021/ic00314a009 10.1016/S0014-3057(02)00043-5 10.1039/a808965e 10.1063/1.453325 10.1016/S0167-577X(03)00501-9 10.1002/1521-3927(20000701)21:11<705::AID-MARC705>3.0.CO;2-3 10.1016/S0009-2614(00)00377-8 10.1021/cm010622z 10.1016/S0009-2614(00)00990-8 10.1006/jcis.1993.1472 10.1002/1521-3927(20000901)21:14<994::AID-MARC994>3.0.CO;2-W 10.1021/la00051a018 10.1021/cm960072i 10.1021/la000941p 10.1016/S0022-2313(99)00220-3 |
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| Issue | 16 |
| Keywords | Semiconductor materials Thermal decomposition Morphology Optical properties Preparation Styrene polymer Nanocomposite Lead sulfide Experimental study Optical absorption Composite material |
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| References | D. ŠAJINOVIČ (3831_CR11) 2000; 329 Z. QIAO (3831_CR3) 1999; 9 W. CASERI (3831_CR2) 2000; 21 D. Y. GODOVSKY (3831_CR1) 2000; 165 H. DU (3831_CR9) 2002; 14 A. J. I. WARD (3831_CR14) 1993; 161 R. S. KANE (3831_CR6) 1996; 8 Y. WANG (3831_CR5) 1987; 87 V. DJOKOVIĆ (3831_CR12) 2000; 21 Z. H. MBHELE (3831_CR18) 2003; 15 S. WANG (3831_CR7) 2000; 16 K. MOLLER (3831_CR16) 1989; 28 T. OKUNO (3831_CR17) 2000; 87-89 P. SREKUMARI NAIR (3831_CR13) 2004; 58 Z. QIAO (3831_CR4) 2000; 321 X. K. ZHAO (3831_CR15) 1991; 7 Z. ZHENG (3831_CR8) 1999; 11 J. KULJANIN (3831_CR19) 2002; 38 S.-H. YU (3831_CR10) 2001; 17 |
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| Snippet | Lead sulfide, a narrow band gap semiconductor (Eg = 0.41 eV at room temperature), is very sensitive to finite size effects due to a large exciton Bohr radius... |
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| SubjectTerms | Applied sciences Composites Exact sciences and technology Forms of application and semi-finished materials Materials science Nanoparticles Polymer industry, paints, wood Polystyrene resins Technology of polymers |
| Title | Preparation and characterization of polystyrene films containing PbS nanoparticles |
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