An electrochemical nanofilm sensor for determination of 1-hydroxypyrene using molecularly imprinted receptors
[Display omitted] A novel electrochemical nanofilm sensor for 1-hydroxypyrene (1-OHP) was developed based on a molecular imprinted TiO2 gel matrix, which was prepared with Ti(O-n-Bu)4 and 1-OHP using sol–gel technology. Cyclic voltammetry (CV) showed that guest binding on the non-imprinted sensor re...
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| Published in | Journal of industrial and engineering chemistry (Seoul, Korea) Vol. 51; pp. 106 - 112 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
25.07.2017
한국공업화학회 |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1226-086X 1876-794X |
| DOI | 10.1016/j.jiec.2017.02.020 |
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| Abstract | [Display omitted]
A novel electrochemical nanofilm sensor for 1-hydroxypyrene (1-OHP) was developed based on a molecular imprinted TiO2 gel matrix, which was prepared with Ti(O-n-Bu)4 and 1-OHP using sol–gel technology. Cyclic voltammetry (CV) showed that guest binding on the non-imprinted sensor resulted in nearly the same current changes for all guest molecules, indicating non-specific binding onto the TiO2 gel matrix. In contrast, binding at the molecular imprinted sensor revealed that the selectivity for 1-OHP relative to structurally related guest molecules was estimated to be 1.8–6.7 times greater at 1×10−9M, reflecting its specific adsorption and binding capacity for the template molecule. |
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| AbstractList | A novel electrochemical nanofilm sensor for 1-hydroxypyrene (1-OHP) was developed based on amolecular imprinted TiO2 gel matrix, which was prepared with Ti(O-n-Bu)4 and 1-OHP using sol–geltechnology. Cyclic voltammetry (CV) showed that guest binding on the non-imprinted sensor resulted innearly the same current changes for all guest molecules, indicating non-specific binding onto the TiO2 gelmatrix. In contrast, binding at the molecular imprinted sensor revealed that the selectivity for 1-OHPrelative to structurally related guest molecules was estimated to be 1.8–6.7 times greater at 110 9 M,reflecting its specific adsorption and binding capacity for the template molecule KCI Citation Count: 16 [Display omitted] A novel electrochemical nanofilm sensor for 1-hydroxypyrene (1-OHP) was developed based on a molecular imprinted TiO2 gel matrix, which was prepared with Ti(O-n-Bu)4 and 1-OHP using sol–gel technology. Cyclic voltammetry (CV) showed that guest binding on the non-imprinted sensor resulted in nearly the same current changes for all guest molecules, indicating non-specific binding onto the TiO2 gel matrix. In contrast, binding at the molecular imprinted sensor revealed that the selectivity for 1-OHP relative to structurally related guest molecules was estimated to be 1.8–6.7 times greater at 1×10−9M, reflecting its specific adsorption and binding capacity for the template molecule. |
| Author | Jeon, Beung-Hoon Choi, Sung Mook Kim, Yong-Dae Shin, Jae Sup Yang, Do-Hyeon Kim, Heon Lee, Chang-Soo |
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| Keywords | NIPY PYCA 1-OHP MIP TiO2 gel matrix PAH Polycyclic aromatic hydrocarbon 1-Hydroxypyrene AMPY Electrochemical sensor Molecular imprinting |
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A novel electrochemical nanofilm sensor for 1-hydroxypyrene (1-OHP) was developed based on a molecular imprinted TiO2 gel matrix, which was... A novel electrochemical nanofilm sensor for 1-hydroxypyrene (1-OHP) was developed based on amolecular imprinted TiO2 gel matrix, which was prepared with... |
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| SubjectTerms | 1-Hydroxypyrene Electrochemical sensor Molecular imprinting Polycyclic aromatic hydrocarbon TiO2 gel matrix 화학공학 |
| Title | An electrochemical nanofilm sensor for determination of 1-hydroxypyrene using molecularly imprinted receptors |
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