Revisiting the structural homogeneity of NU-1000, a Zr-based metal–organic framework
Synthesis and activation of phase-pure and defect-free metal–organic frameworks (MOFs) are essential for establishing accurate structure–property relationships. Primarily suffering from missing linker and/or node defects, Zr 6 -based MOFs can have polymorphs, structures with the identical linker and...
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Published in | CrystEngComm Vol. 20; no. 39; pp. 5913 - 5918 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
Published |
2018
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Online Access | Get full text |
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Abstract | Synthesis and activation of phase-pure and defect-free metal–organic frameworks (MOFs) are essential for establishing accurate structure–property relationships. Primarily suffering from missing linker and/or node defects, Zr
6
-based MOFs can have polymorphs, structures with the identical linker and node but different connectivity, which can create multiple phases in a sample that complicate the characterization. Here, we report the synthesis of phase-pure NU-1000, a mesoporous Zr
6
-based MOF that typically contains a significant secondary phase within the individual crystallites. Large biomolecules and smaller inorganic molecules have been installed in NU-1000 as probes to verify the near elimination of the microporous secondary-phase. Obtaining structurally homogenous MOFs will assist the design of new materials with distinct structural features. |
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AbstractList | Synthesis and activation of phase-pure and defect-free metal–organic frameworks (MOFs) are essential for establishing accurate structure–property relationships. Primarily suffering from missing linker and/or node defects, Zr
6
-based MOFs can have polymorphs, structures with the identical linker and node but different connectivity, which can create multiple phases in a sample that complicate the characterization. Here, we report the synthesis of phase-pure NU-1000, a mesoporous Zr
6
-based MOF that typically contains a significant secondary phase within the individual crystallites. Large biomolecules and smaller inorganic molecules have been installed in NU-1000 as probes to verify the near elimination of the microporous secondary-phase. Obtaining structurally homogenous MOFs will assist the design of new materials with distinct structural features. |
Author | Akpinar, Isil Farha, Omar K. Li, Peng Garibay, Sergio J. Islamoglu, Timur Peters, Aaron W. Otake, Ken-ichi Buru, Cassandra T. |
Author_xml | – sequence: 1 givenname: Timur orcidid: 0000-0003-3688-9158 surname: Islamoglu fullname: Islamoglu, Timur organization: Department of Chemistry, Northwestern University, Evanston, USA – sequence: 2 givenname: Ken-ichi surname: Otake fullname: Otake, Ken-ichi organization: Department of Chemistry, Northwestern University, Evanston, USA – sequence: 3 givenname: Peng orcidid: 0000-0002-4273-4577 surname: Li fullname: Li, Peng organization: Department of Chemistry, Northwestern University, Evanston, USA – sequence: 4 givenname: Cassandra T. orcidid: 0000-0001-6142-8252 surname: Buru fullname: Buru, Cassandra T. organization: Department of Chemistry, Northwestern University, Evanston, USA – sequence: 5 givenname: Aaron W. surname: Peters fullname: Peters, Aaron W. organization: Department of Chemistry, Northwestern University, Evanston, USA – sequence: 6 givenname: Isil surname: Akpinar fullname: Akpinar, Isil organization: Department of Chemistry, Northwestern University, Evanston, USA – sequence: 7 givenname: Sergio J. surname: Garibay fullname: Garibay, Sergio J. organization: Department of Chemistry, Northwestern University, Evanston, USA – sequence: 8 givenname: Omar K. surname: Farha fullname: Farha, Omar K. organization: Department of Chemistry, Northwestern University, Evanston, USA, Department of Chemistry |
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