Revisiting the structural homogeneity of NU-1000, a Zr-based metal–organic framework

Synthesis and activation of phase-pure and defect-free metal–organic frameworks (MOFs) are essential for establishing accurate structure–property relationships. Primarily suffering from missing linker and/or node defects, Zr 6 -based MOFs can have polymorphs, structures with the identical linker and...

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Published inCrystEngComm Vol. 20; no. 39; pp. 5913 - 5918
Main Authors Islamoglu, Timur, Otake, Ken-ichi, Li, Peng, Buru, Cassandra T., Peters, Aaron W., Akpinar, Isil, Garibay, Sergio J., Farha, Omar K.
Format Journal Article
LanguageEnglish
Published 2018
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Abstract Synthesis and activation of phase-pure and defect-free metal–organic frameworks (MOFs) are essential for establishing accurate structure–property relationships. Primarily suffering from missing linker and/or node defects, Zr 6 -based MOFs can have polymorphs, structures with the identical linker and node but different connectivity, which can create multiple phases in a sample that complicate the characterization. Here, we report the synthesis of phase-pure NU-1000, a mesoporous Zr 6 -based MOF that typically contains a significant secondary phase within the individual crystallites. Large biomolecules and smaller inorganic molecules have been installed in NU-1000 as probes to verify the near elimination of the microporous secondary-phase. Obtaining structurally homogenous MOFs will assist the design of new materials with distinct structural features.
AbstractList Synthesis and activation of phase-pure and defect-free metal–organic frameworks (MOFs) are essential for establishing accurate structure–property relationships. Primarily suffering from missing linker and/or node defects, Zr 6 -based MOFs can have polymorphs, structures with the identical linker and node but different connectivity, which can create multiple phases in a sample that complicate the characterization. Here, we report the synthesis of phase-pure NU-1000, a mesoporous Zr 6 -based MOF that typically contains a significant secondary phase within the individual crystallites. Large biomolecules and smaller inorganic molecules have been installed in NU-1000 as probes to verify the near elimination of the microporous secondary-phase. Obtaining structurally homogenous MOFs will assist the design of new materials with distinct structural features.
Author Akpinar, Isil
Farha, Omar K.
Li, Peng
Garibay, Sergio J.
Islamoglu, Timur
Peters, Aaron W.
Otake, Ken-ichi
Buru, Cassandra T.
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  organization: Department of Chemistry, Northwestern University, Evanston, USA
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  fullname: Farha, Omar K.
  organization: Department of Chemistry, Northwestern University, Evanston, USA, Department of Chemistry
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Snippet Synthesis and activation of phase-pure and defect-free metal–organic frameworks (MOFs) are essential for establishing accurate structure–property...
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Title Revisiting the structural homogeneity of NU-1000, a Zr-based metal–organic framework
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