A new selective dichlorination of CC double bonds
A new dichlorination procedure of CC double bond was developed with hexachloroethane as chlorinating agent and RuCl 2(PPh 3) 3 as catalyst. The reaction is highly selective for CC double bond; other functional groups are unaffected by these conditions. The reaction proceeded at the existence of va...
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Published in | Tetrahedron letters Vol. 35; no. 5; pp. 737 - 740 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
OXFORD
Elsevier Ltd
01.01.1994
Elsevier |
Subjects | |
Online Access | Get full text |
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Summary: | A new dichlorination procedure of CC double bond was developed with hexachloroethane as chlorinating agent and RuCl
2(PPh
3)
3 as catalyst. The reaction is highly selective for CC double bond; other functional groups are unaffected by these conditions.
The reaction proceeded at the existence of various kinds of functional groups, such as hydoxy, carboxyl, ester phenyl, of active methylene in the structure. |
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ISSN: | 0040-4039 1873-3581 |
DOI: | 10.1016/S0040-4039(00)75804-7 |