Thin film composite membrane prepared by interfacial polymerization as an ion exchange membrane for salinity gradient power
[Display omitted] •Thin film composite (TFC) membranes were studied for salinity gradient power (SGP).•Interfacial polymerization mechanisms was understood using partition coefficient values.•Through screening the combinations among aqueous and organic monomers, DBA-TMC TFC membranes were found for...
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| Published in | Journal of industrial and engineering chemistry (Seoul, Korea) Vol. 59; pp. 362 - 371 |
|---|---|
| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
25.03.2018
한국공업화학회 |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1226-086X 1876-794X |
| DOI | 10.1016/j.jiec.2017.10.044 |
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| Abstract | [Display omitted]
•Thin film composite (TFC) membranes were studied for salinity gradient power (SGP).•Interfacial polymerization mechanisms was understood using partition coefficient values.•Through screening the combinations among aqueous and organic monomers, DBA-TMC TFC membranes were found for the best performance for SGP.•The DBA-TMC TFC membrane has a higher normalized power density (7.2W/m2) than the other membranes (e.g., Nafion).
For extracting the salinity gradient energy, membrane is a key material with a high power density. For this purpose, thin film composite (TFC) membranes were synthesized by interfacial polymerization using various acyl chloride and amine monomers. TFC membranes were characterized by FT-IR, SEM, XPS, and AFM. Among the range of TFC, the best candidate was prepared by combining 3,5-diaminebenzonic acid (0.5wt% with distilled water) and 1,3,5-benzenetricarbonyl trichloride (0.2wt% with n-hexane). The TFC membrane (thickness=0.02mm) generated a power density of 7.2W/m2 at salinity gradient between 0.005 and 0.5M KCl solutions. |
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| AbstractList | [Display omitted]
•Thin film composite (TFC) membranes were studied for salinity gradient power (SGP).•Interfacial polymerization mechanisms was understood using partition coefficient values.•Through screening the combinations among aqueous and organic monomers, DBA-TMC TFC membranes were found for the best performance for SGP.•The DBA-TMC TFC membrane has a higher normalized power density (7.2W/m2) than the other membranes (e.g., Nafion).
For extracting the salinity gradient energy, membrane is a key material with a high power density. For this purpose, thin film composite (TFC) membranes were synthesized by interfacial polymerization using various acyl chloride and amine monomers. TFC membranes were characterized by FT-IR, SEM, XPS, and AFM. Among the range of TFC, the best candidate was prepared by combining 3,5-diaminebenzonic acid (0.5wt% with distilled water) and 1,3,5-benzenetricarbonyl trichloride (0.2wt% with n-hexane). The TFC membrane (thickness=0.02mm) generated a power density of 7.2W/m2 at salinity gradient between 0.005 and 0.5M KCl solutions. For extracting the salinity gradient energy, membrane is a key material with a high power density. For this purpose, thin film composite (TFC) membranes were synthesized by interfacial polymerization using various acyl chloride and amine monomers. TFC membranes were characterized by FT-IR, SEM, XPS, and AFM. Among the range of TFC, the best candidate was prepared by combining 3,5-diaminebenzonic acid (0.5 wt% with distilled water) and 1,3,5-benzenetricarbonyl trichloride (0.2 wt% with n-hexane). The TFC membrane (thickness = 0.02 mm) generated a power density of 7.2 W/m2 at salinity gradient between 0.005 and 0.5 M KCl solutions. KCI Citation Count: 13 |
| Author | Choi, Wook Lee, Jonghwi Lee, Kangwon Bae, Harim Lee, Jung-Hyun Oh, Dea-gyun Park, Chul Ho |
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| CitedBy_id | crossref_primary_10_1016_j_compositesa_2018_06_020 crossref_primary_10_1016_j_jiec_2021_08_001 crossref_primary_10_1039_D1SM00187F crossref_primary_10_1016_j_desal_2019_114242 crossref_primary_10_1016_j_jiec_2023_02_011 crossref_primary_10_1016_j_dwt_2024_100092 crossref_primary_10_1016_j_nanoen_2022_106939 crossref_primary_10_3390_membranes11090650 crossref_primary_10_1016_j_nanoen_2020_104906 crossref_primary_10_1016_j_memsci_2020_118081 crossref_primary_10_14579_MEMBRANE_JOURNAL_2020_30_3_200 crossref_primary_10_1016_j_ijhydene_2021_10_074 crossref_primary_10_1016_j_seppur_2021_120228 crossref_primary_10_1016_j_memsci_2020_118946 crossref_primary_10_1007_s00289_023_04897_0 crossref_primary_10_14579_MEMBRANE_JOURNAL_2019_29_1_61 |
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| Keywords | Interfacial polymerization Salinity gradient power Thin film composite Ion exchange membranes |
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•Thin film composite (TFC) membranes were studied for salinity gradient power (SGP).•Interfacial polymerization mechanisms was understood... For extracting the salinity gradient energy, membrane is a key material with a high power density. For this purpose, thin film composite (TFC) membranes were... |
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| SubjectTerms | Interfacial polymerization Ion exchange membranes Salinity gradient power Thin film composite 화학공학 |
| Title | Thin film composite membrane prepared by interfacial polymerization as an ion exchange membrane for salinity gradient power |
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