Preparation of activated carbons from bituminous coal pitches

High-porosity carbons were prepared from bituminous coal pitches by combining chemical and physical activation. The chemical activation process consisted of potassium hydroxide impregnation followed by carbonization in nitrogen atmosphere. The effect of the KOH impregnation ratio on the surface area...

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Published in	Applied surface science Vol. 238; no. 1-4; pp. 347 - 354
Main Authors	Gañan, J., González-Garcı́a, C.M., González, J.F., Sabio, E., Macı́as-Garcı́a, A., Dı́az-Dı́ez, M.A.
Format	Journal Article Conference Proceeding
Language	English
Published	Amsterdam Elsevier B.V 15.11.2004 Elsevier Science
Subjects	Activated carbons Anisotropic phase Chemical activation Cross-disciplinary physics: materials science; rheology Exact sciences and technology Materials science Physical activation Physics Pitch Porous materials; granular materials Specific materials 81.20.E Physical activation 68.35.B Chemical activation Anisotropic phase Activated carbons Pitch Activated carbon Porous materials Preparation Activation Bituminous coal
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Abstract	High-porosity carbons were prepared from bituminous coal pitches by combining chemical and physical activation. The chemical activation process consisted of potassium hydroxide impregnation followed by carbonization in nitrogen atmosphere. The effect of the KOH impregnation ratio on the surface area and pore volumes evolution of the carbons derived from mesophase pitch was studied. The optimum KOH:pitch ratio was fixed to realize a physical activation process in order to increase the textural parameters of the KOH-activated carbons. Physical activation was performed by carbonizing the KOH-activated carbons followed by gasifying with air. The influence of the carbonization temperature and the residence time of the gasification with air were explored to optimize those preparation parameters.
AbstractList	High-porosity carbons were prepared from bituminous coal pitches by combining chemical and physical activation. The chemical activation process consisted of potassium hydroxide impregnation followed by carbonization in nitrogen atmosphere. The effect of the KOH impregnation ratio on the surface area and pore volumes evolution of the carbons derived from mesophase pitch was studied. The optimum KOH:pitch ratio was fixed to realize a physical activation process in order to increase the textural parameters of the KOH-activated carbons. Physical activation was performed by carbonizing the KOH-activated carbons followed by gasifying with air. The influence of the carbonization temperature and the residence time of the gasification with air were explored to optimize those preparation parameters.
Author	Dı́az-Dı́ez, M.A. González-Garcı́a, C.M. Macı́as-Garcı́a, A. Sabio, E. González, J.F. Gañan, J.
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SubjectTerms	Activated carbons Anisotropic phase Chemical activation Cross-disciplinary physics: materials science; rheology Exact sciences and technology Materials science Physical activation Physics Pitch Porous materials; granular materials Specific materials
Title	Preparation of activated carbons from bituminous coal pitches
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