Visible light harvesting alkyne hydrosilylation mediated by pincer platinum complexes

• Published in: Journal of catalysis Vol. 428; p. 115155
• Main Authors: Ibáñez-Ibáñez, Laura, Lázaro, Ariadna, Mejuto, Carmen, Crespo, Margarita, Vicent, Cristian, Rodríguez, Laura, Mata, Jose A.
• Format: Journal Article
• Language: English
• Published: Elsevier Inc 01.12.2023
• Subjects: alkynes; ambient temperature; catalysts; HAT; Hydrosilylation; light; Mechanisms; Photocatalysis; photosensitizing agents; Platinum; reaction mechanisms; species; stereoselectivity; ESI-MS; Mechanisms; Hydrosilylation; HAT; Platinum; Photocatalysis

Increasing the efficiency of hydrosilylation assisted by visible-light. Catalytic properties and reaction mechanism with the formation of radicals where the platinum complexes play a dual role as harvesting light species and enabling bond breaking/forming transformations. [Display omitted] •Platinum...