Rotational diffusion and segmental motions in solutions and melts of tetraoctylammonium perchlorate
Relaxation times for the methylene carbon atoms in the aliphatic chains of tetraoctylammonium perchlorate have been measured in different solvents and in the melt. The results have then been interpreted on the basis of a theoretical model which considers the overall rotational diffusion and the inte...
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| Published in | Chemical physics Vol. 123; no. 3; pp. 397 - 403 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Amsterdam
Elsevier B.V
15.07.1988
Elsevier |
| Subjects | |
| Online Access | Get full text |
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| Abstract | Relaxation times for the methylene carbon atoms in the aliphatic chains of tetraoctylammonium perchlorate have been measured in different solvents and in the melt. The results have then been interpreted on the basis of a theoretical model which considers the overall rotational diffusion and the internal conformational transitions in flexible chains attached to massive cores. |
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| AbstractList | Relaxation times for the methylene carbon atoms in the aliphatic chains of tetraoctylammonium perchlorate have been measured in different solvents and in the melt. The results have then been interpreted on the basis of a theoretical model which considers the overall rotational diffusion and the internal conformational transitions in flexible chains attached to massive cores. |
| Author | Coletta, F. Nordio, P.L. Ferrarini, A. |
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| Cites_doi | 10.1021/j100280a066 10.1016/0009-2614(75)85513-8 10.1080/00268978800100181 10.1021/ja00381a009 10.1063/1.440539 10.1063/1.443779 10.1016/0009-2614(79)80114-1 10.1063/1.438965 10.1080/00268978700101771 10.1016/0003-4916(69)90153-5 |
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| Keywords | Solvent effect Liquid state Chemical solution Spin lattice relaxation Conformational dynamics Molecular dynamics Experimental study Relaxation time Quaternary ammonium compound Reorientation diffusion Saturated aliphatic compound Correlation function Diffusion coefficient NMR spectrum Organic compounds |
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| References | Langer (BIB8) 1969; 54 Moro, Freed (BIB12) 1986 Happel, Brenner (BIB10) 1965 Knauss, Evans (BIB14) 1980; 73 P.L. Nordio, A. Ferrarini and G. Moro, in: Chemical reactivity in liquids: fundamental aspects. Proceedings of 42nd International Meeting, Paris 1987, to be published. Coletta, Moro, Nordio (BIB1) 1987; 61 Gal, Paligoric, Antonijevic (BIB4) 1970; 32 Ferrarini, Moro, Nordio (BIB5) 1988; 63 Nery, Söderman, Canet, Walderang, Lindman (BIB3) 1986; 90 Lipari, Szabo (BIB7) 1982; 104 Flory (BIB2) 1969 Skolnick, Helfand, Helfand, Skolnick (BIB9) 1980; 72 Levy, Karplus, McCammon (BIB13) 1979; 65 Ryckaert, Bellemans (BIB11) 1975; 30 Langer (10.1016/0301-0104(88)87049-6_BIB8) 1969; 54 Nery (10.1016/0301-0104(88)87049-6_BIB3) 1986; 90 Knauss (10.1016/0301-0104(88)87049-6_BIB14) 1980; 73 Ferrarini (10.1016/0301-0104(88)87049-6_BIB5) 1988; 63 Skolnick (10.1016/0301-0104(88)87049-6_BIB9_1) 1980; 72 Coletta (10.1016/0301-0104(88)87049-6_BIB1) 1987; 61 Happel (10.1016/0301-0104(88)87049-6_BIB10) 1965 Helfand (10.1016/0301-0104(88)87049-6_BIB9_2) 1982; 77 Gal (10.1016/0301-0104(88)87049-6_BIB4) 1970; 32 Levy (10.1016/0301-0104(88)87049-6_BIB13) 1979; 65 10.1016/0301-0104(88)87049-6_BIB6 Flory (10.1016/0301-0104(88)87049-6_BIB2) 1969 Ryckaert (10.1016/0301-0104(88)87049-6_BIB11) 1975; 30 Lipari (10.1016/0301-0104(88)87049-6_BIB7) 1982; 104 Moro (10.1016/0301-0104(88)87049-6_BIB12) 1986 |
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| SubjectTerms | Atomic and molecular physics Barrier heights (internal rotation, inversion, rotational isomerism, conformational dynamics) Exact sciences and technology Molecular properties and interactions with photons Physics Properties of molecules and molecular ions |
| Title | Rotational diffusion and segmental motions in solutions and melts of tetraoctylammonium perchlorate |
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