Polymerizable lipid analogues of diacetylenic phosphonic acids. Synthesis, spreading behaviour and polymerization at the gas-water interface
The subject of this paper is the synthesis and characterization of diacetylenic phosphonates as polymerizable, chemically stable lecithin analogues. One or both of the hydrophobic chains of the lipids contain a diacetylene moiety. The oxygen atoms between the glycerol backbone and the side groups ha...
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| Published in | Chemistry and physics of lipids Vol. 41; no. 3; pp. 265 - 291 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Shannon
Elsevier Ireland Ltd
01.10.1986
Elsevier Science |
| Subjects | |
| Online Access | Get full text |
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| Abstract | The subject of this paper is the synthesis and characterization of diacetylenic phosphonates as polymerizable, chemically stable lecithin analogues. One or both of the hydrophobic chains of the lipids contain a diacetylene moiety. The oxygen atoms between the glycerol backbone and the side groups have been omitted to increase the chemical stability. The monolayer phase diagram at the air-water interface has been measured and the polymerization under UV-irradiation was investigated. These results are compared to the findings with unmodified polymerizable and non-polymerizable analogues. |
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| AbstractList | The subject of this paper is the synthesis and characterization of diacetylenic phosphonates as polymerizable, chemically stable lecithin analogues. One or both of the hydrophobic chains of the lipids contain a diacetylene moiety. The oxygen atoms between the glycerol backbone and the side groups have been omitted to increase the chemical stability. The monolayer phase diagram at the air-water interface has been measured and the polymerization under UV-irradiation was investigated. These results are compared to the findings with unmodified polymerizable and non-polymerizable analogues. |
| Author | Vogt, Walter Albrecht, Otto Ostermayer, Bertram |
| Author_xml | – sequence: 1 givenname: Bertram surname: Ostermayer fullname: Ostermayer, Bertram – sequence: 2 givenname: Otto surname: Albrecht fullname: Albrecht, Otto – sequence: 3 givenname: Walter surname: Vogt fullname: Vogt, Walter |
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| CitedBy_id | crossref_primary_10_1016_0009_3084_91_90080_U crossref_primary_10_1016_j_colsurfa_2019_01_038 crossref_primary_10_1080_02678290601119864 crossref_primary_10_1016_0022_0728_88_87065_7 crossref_primary_10_1016_0022_0728_89_87254_7 crossref_primary_10_1002_anie_198801131 crossref_primary_10_1016_0079_6816_92_90012_7 crossref_primary_10_1002_masy_19910460113 crossref_primary_10_1016_0302_4598_88_80021_7 crossref_primary_10_1021_la990206h crossref_primary_10_1002_ange_19881000111 crossref_primary_10_1080_02678298908045686 crossref_primary_10_1016_0302_4598_89_85031_7 crossref_primary_10_3390_polym10010091 crossref_primary_10_3390_polym6051544 crossref_primary_10_1016_0302_4598_88_80009_6 crossref_primary_10_1021_la100273q crossref_primary_10_1016_0022_0728_88_87077_3 |
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| Keywords | lipids monolayer phosphonic acids UV-polymerizable films synthesis of polymerizable lipids Gas liquid interface Monolayer Ultraviolet radiation Lecithin Photopolymerization Spreading Preparation Lipids Organic phosphonate Diacetylene polymer Polymorphism Phosphorus polymer |
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| SubjectTerms | Applied sciences Exact sciences and technology lipids monolayer phosphonic acids Physicochemistry of polymers Polymerization Polymers and radiations synthesis of polymerizable lipids UV-polymerizable films |
| Title | Polymerizable lipid analogues of diacetylenic phosphonic acids. Synthesis, spreading behaviour and polymerization at the gas-water interface |
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