The spin-filter capability and giant magnetoresistance effect in vanadium–naphthalene sandwich cluster
The giant magnetoresistance effects of different-sized vanadium–naphthalene sandwich clusters. [Display omitted] •Different-sized vanadium–naphthalene sandwich clusters are all very stable and could exhibit rich magnetic properties.•The spin-filter capability and negative differential resistance can...
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Published in | Organic electronics Vol. 14; no. 11; pp. 2916 - 2924 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
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Amsterdam
Elsevier B.V
01.11.2013
Elsevier |
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Abstract | The giant magnetoresistance effects of different-sized vanadium–naphthalene sandwich clusters. [Display omitted]
•Different-sized vanadium–naphthalene sandwich clusters are all very stable and could exhibit rich magnetic properties.•The spin-filter capability and negative differential resistance can be observed in these systems.•The giant magnetoresistance effect was also found in the sandwiches and the transport properties can be adjusted according to cluster size.
Using density functional theory and non-equilibrium Green’s function technique, we performed theoretical investigations on the magnetic and transport properties of V2n(C10H8)n+1 (n=1–4) sandwich clusters. For the ground states, our results show that all the clusters are stable and possess ferromagnetic orders. The smaller clusters have higher stabilities, and our predictions are in agreement with the experimental observation. The double exchange mechanism plays an important role in determining the magnetic properties of the systems. Furthermore, with Ni as electrodes, the clusters exhibit interesting transport properties such as significant spin-filter capability, negative differential resistance feature and giant magnetoresistance effect. These findings suggest that V2n(C10H8)n+1 sandwiches are excellent candidates for application in spintronics and organic electronics. |
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AbstractList | The giant magnetoresistance effects of different-sized vanadium–naphthalene sandwich clusters. [Display omitted]
•Different-sized vanadium–naphthalene sandwich clusters are all very stable and could exhibit rich magnetic properties.•The spin-filter capability and negative differential resistance can be observed in these systems.•The giant magnetoresistance effect was also found in the sandwiches and the transport properties can be adjusted according to cluster size.
Using density functional theory and non-equilibrium Green’s function technique, we performed theoretical investigations on the magnetic and transport properties of V2n(C10H8)n+1 (n=1–4) sandwich clusters. For the ground states, our results show that all the clusters are stable and possess ferromagnetic orders. The smaller clusters have higher stabilities, and our predictions are in agreement with the experimental observation. The double exchange mechanism plays an important role in determining the magnetic properties of the systems. Furthermore, with Ni as electrodes, the clusters exhibit interesting transport properties such as significant spin-filter capability, negative differential resistance feature and giant magnetoresistance effect. These findings suggest that V2n(C10H8)n+1 sandwiches are excellent candidates for application in spintronics and organic electronics. |
Author | Li, Xiuyan Zhang, Baolong Liu, Xuguang Xu, Bingshe Yang, Yongzhen Xiong, Shijie Yang, Zhi |
Author_xml | – sequence: 1 givenname: Zhi surname: Yang fullname: Yang, Zhi email: yangzhi@tyut.edu.cn organization: Key Laboratory of Advanced Transducers and Intelligent Control System, Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, China – sequence: 2 givenname: Baolong surname: Zhang fullname: Zhang, Baolong organization: Key Laboratory of Advanced Transducers and Intelligent Control System, Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, China – sequence: 3 givenname: Xuguang surname: Liu fullname: Liu, Xuguang email: liuxuguang@tyut.edu.cn organization: Key Laboratory of Interface Science and Engineering in Advanced Materials, Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, China – sequence: 4 givenname: Yongzhen surname: Yang fullname: Yang, Yongzhen organization: Key Laboratory of Interface Science and Engineering in Advanced Materials, Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, China – sequence: 5 givenname: Xiuyan surname: Li fullname: Li, Xiuyan organization: Key Laboratory of Advanced Transducers and Intelligent Control System, Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, China – sequence: 6 givenname: Shijie surname: Xiong fullname: Xiong, Shijie organization: National Laboratory of Solid State Microstructures and Department of Physics, Nanjing University, Nanjing 210093, China – sequence: 7 givenname: Bingshe surname: Xu fullname: Xu, Bingshe organization: Key Laboratory of Interface Science and Engineering in Advanced Materials, Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, China |
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CitedBy_id | crossref_primary_10_1002_qua_24843 crossref_primary_10_1021_jp511443j crossref_primary_10_1142_S0217979218500339 crossref_primary_10_1002_qua_26832 crossref_primary_10_1016_j_physe_2019_05_003 crossref_primary_10_1039_D3NA00926B crossref_primary_10_1063_1_5115176 |
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Keywords | Sandwich cluster Giant magnetoresistance Negative differential resistance Spin-filter capability Double exchange Transport properties Ground states Vanadium Ferromagnetic materials Magnetoresistive devices Non equilibrium conditions Ferromagnetism Spin filter Organic electronics Magnetic properties Negative differential conductivity Forecasting Sandwich structures Naphthalene Density functional method Nickel Transport processes Green's function methods Exchange interactions Spintronics |
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Snippet | The giant magnetoresistance effects of different-sized vanadium–naphthalene sandwich clusters. [Display omitted]
•Different-sized vanadium–naphthalene sandwich... |
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SubjectTerms | Applied sciences Compound structure devices Condensed matter: electronic structure, electrical, magnetic, and optical properties Electronic transport in condensed matter Electronics Exact sciences and technology Exchange and superexchange interactions Giant magnetoresistance Magnetic properties and materials Magnetically ordered materials: other intrinsic properties Magnetotransport phenomena, materials for magnetotransport Negative differential resistance Physics Sandwich cluster Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices Spin polarized transport Spin-filter capability |
Title | The spin-filter capability and giant magnetoresistance effect in vanadium–naphthalene sandwich cluster |
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