Asymmetric hydroformylation of the linear butenes by [( R,R)-Diop]Pt(SnCl 3)Cl

• Published in: Journal of organometallic chemistry Vol. 296; no. 1; pp. 281 - 290
• Main Authors: Haelg, Paul, Consiglio, Giambattista, Pino, Piero
• Format: Journal Article
• Language: English
• Published: Lausanne Elsevier B.V 01.01.1985; Elsevier Science
• Subjects: Chemical reactivity; Chemistry; Exact sciences and technology; Organic chemistry; Reactivity and mechanisms; Platinum Complexes; Catalytic reaction; Hydrocarbon; Regioselectivity; Aliphatic compound; Isomerization; Organic ligand; Asymmetric induction; Hydrogenation; Isomer; Chirality; Ditertiary phosphine; Hydroformylation; Asymmetric reaction; Ethylenic compound

The asymmetric hydroformylation of the three isomeric straight chain butenes catalyzed by [( R, R)-Diop]Pt(SnCl 3)CI (Diop is 2,2-dimethyl-4, 5-bis(diphenylphos- phinomethyl)-l,3-dioxolane) has been reinvestigated. Depending on the conditions, hydroformylation can be accompanied by extensive isomeri...