Anchoring CoP nanoparticles on the octahedral CoO by self-phosphating for enhanced photocatalytic overall water splitting activity under visible light

• Published in: Chinese journal of chemical engineering Vol. 40; no. 12; pp. 114 - 123
• Main Authors: Guo, Feng, Huang, Xiliu, Chen, Zhihao, Sun, Haoran, Chen, Lizhuang
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.12.2021; School of Energy and Power,Jiangsu University of Science and Technology,Zhenjiang 212003,China%School of Environmental and Chemical Engineering,Jiangsu University of Science and Technology,Zhenjiang 212003,China
• Subjects: Catalyst; CoO octahedrons; CoP nanoparticles; Overall water splitting; Photochemistry; Solar energy; Overall water splitting; CoP nanoparticles; CoO octahedrons; Catalyst; Solar energy; Photochemistry
• ISSN: 1004-9541; 2210-321X
• DOI: 10.1016/j.cjche.2020.11.030

[Display omitted] Designing an effective and stable composite photocatalyst is of significance for the further realization of practical applications. In this study, a series of CoP/CoO composites are successfully prepared by a straight one-step phosphating method. The reasonable design and controllable preparation of CoP/CoO composite make it exhibit improved photocatalytic performance for overall water splitting and excellent stability under visible light irradiation in comparison with pure CoO, which is derived from the CoP nanoparticles well dispersed on the (111) facets of CoO octahedrons, intimate interface between them and efficiently accelerated of photo-induced electrons from CoO to CoP. This study presents a simple method to design highly-effective composite photocatalysts for overall water splitting to meet the energy demand.