Selective reductive annulation reaction for direct synthesis of functionalized quinolines by a cobalt nanocatalyst

• Published in: Journal of catalysis Vol. 383; pp. 239 - 243
• Main Authors: Xie, Rong, Lu, Guang-Peng, Jiang, Huan-Feng, Zhang, Min
• Format: Journal Article
• Language: English
• Published: Elsevier Inc 01.03.2020
• Subjects: catalytic activity; Cobalt; Functionalized quinolines; Heterogeneous catalysis; hydrogen; moieties; nanocatalysts; nanomaterials; quinolines; Reductive annulation; Transfer hydrogenation; zirconium oxide; Reductive annulation; Heterogeneous catalysis; Transfer hydrogenation; Functionalized quinolines; Cobalt
• ISSN: 0021-9517; 1090-2694
• DOI: 10.1016/j.jcat.2020.01.034

By developing a new N-doped ZrO2@C supported cobalt nanomaterial, it has been successfully applied as an efficient catalyst for the reductive annulation of 2-nitroaryl carbonyls with alkynoates and alkynones. The catalytic transformation allows synthesizing a wide array of funcitonalized quinolines...