Absorption of the flavin dimers

The electronic absorption spectra of the flavomononucleotide (FMN) in aqueous solution and in glycerine-water solution with change of the dye concentration have been measured. The FMN dimer absorption spectrum, monomer absorption spectrum, dimerization constant K and molar fraction of the monomer we...

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Published inBiochimica et biophysica acta Vol. 801; no. 3; pp. 456 - 460
Main Authors Grajek, Hanna, Drabent, Regina, Żurkowska, Grażyna, Bojarski, Czesław
Format Journal Article
LanguageEnglish
Published Amsterdam Elsevier B.V 01.01.1984
Elsevier
North-Holland
Subjects
Absorption spectrum
Biological and medical sciences
Flavin dimer
FMN
Fundamental and applied biological sciences. Psychology
Molecular biophysics
Spectroscopy : techniques and spectras
Flavin dimer
FMN
Absorption spectrum
Flavin
Dimer
Aqueous solution
Hydroorganic solvent
Coenzyme
Online AccessGet full text

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Abstract The electronic absorption spectra of the flavomononucleotide (FMN) in aqueous solution and in glycerine-water solution with change of the dye concentration have been measured. The FMN dimer absorption spectrum, monomer absorption spectrum, dimerization constant K and molar fraction of the monomer were calculated. It was found that FMN dimerization constants in aqueous solution were K a = 118.0 l/mol and in glycerine K g = 20.5 l/mol. In the region of the monomer absorption band two dimer absorption bands appear, in accordance with the Kasha molecular exciton theory.
AbstractList The electronic absorption spectra of the flavomononucleotide (FMN) in aqueous solution and in glycerine-water solution with change of the dye concentration have been measured. The FMN dimer absorption spectrum, monomer absorption spectrum, dimerization constant K and molar fraction of the monomer were calculated. It was found that FMN dimerization constants in aqueous solution were K a = 118.0 l/mol and in glycerine K g = 20.5 l/mol. In the region of the monomer absorption band two dimer absorption bands appear, in accordance with the Kasha molecular exciton theory.
Author Grajek, Hanna
Żurkowska, Grażyna
Drabent, Regina
Bojarski, Czesław
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  givenname: Czesław
  surname: Bojarski
  fullname: Bojarski, Czesław
  organization: Institute of Physics, Technical University, 80-952 Gdańsk, Poland
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Cites_doi 10.1111/j.1751-1097.1981.tb09314.x
10.1021/j100717a002
10.1515/znb-1972-0901
10.1021/j100679a009
10.1080/00387018308062372
10.1016/0304-4165(83)90289-1
10.1039/F29817701725
10.1042/bj0850369
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Issue 3
Keywords Flavin dimer
FMN
Absorption spectrum
Flavin
Dimer
Aqueous solution
Hydroorganic solvent
Coenzyme
Language English
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Snippet The electronic absorption spectra of the flavomononucleotide (FMN) in aqueous solution and in glycerine-water solution with change of the dye concentration...
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SubjectTerms Absorption spectrum
Biological and medical sciences
Flavin dimer
FMN
Fundamental and applied biological sciences. Psychology
Molecular biophysics
Spectroscopy : techniques and spectras
Title Absorption of the flavin dimers
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