Stability of ordered L12 and B2 precipitates in face centered cubic based high entropy alloys - Al0.3CoFeCrNi and Al0.3CuFeCrNi2
Adding a small amount of Al to the well-known high entropy alloy (HEA), Al0.1CoCrFeNi, to form Al0.3CoCrFeNi, leads to the precipitation of highly refined ordered L12 precipitates, which are stable at 550°C. However, the L12 precipitates (stoichiometry of (Ni,Cr)3(Al,Fe,Co)) are de-stabilized and re...
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Published in | Scripta materialia Vol. 123; pp. 130 - 134 |
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Main Authors | , , , , , , , , |
Format | Journal Article |
Language | English |
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Elsevier Ltd
01.10.2016
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Abstract | Adding a small amount of Al to the well-known high entropy alloy (HEA), Al0.1CoCrFeNi, to form Al0.3CoCrFeNi, leads to the precipitation of highly refined ordered L12 precipitates, which are stable at 550°C. However, the L12 precipitates (stoichiometry of (Ni,Cr)3(Al,Fe,Co)) are de-stabilized and replaced by coarser B2 precipitates on annealing at 700°C. Contrastingly, in the Co-free, Al0.3CuCrFeNi2 high entropy alloy, the L12 precipitates are stable at both 550°C (~5nm) and 700°C (~50nm), and exhibit a stoichiometry of (Ni,Cu)3(Al,Fe,Cr). These results lead to interesting insights into the stability of ordered phases in HEAs as a function of composition and temperature.
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AbstractList | Adding a small amount of Al to the well-known high entropy alloy (HEA), Al0.1CoCrFeNi, to form Al0.3CoCrFeNi, leads to the precipitation of highly refined ordered L12 precipitates, which are stable at 550°C. However, the L12 precipitates (stoichiometry of (Ni,Cr)3(Al,Fe,Co)) are de-stabilized and replaced by coarser B2 precipitates on annealing at 700°C. Contrastingly, in the Co-free, Al0.3CuCrFeNi2 high entropy alloy, the L12 precipitates are stable at both 550°C (~5nm) and 700°C (~50nm), and exhibit a stoichiometry of (Ni,Cu)3(Al,Fe,Cr). These results lead to interesting insights into the stability of ordered phases in HEAs as a function of composition and temperature.
[Display omitted] Adding a small amount of Al to the well-known high entropy alloy (HEA), Al0.1CoCrFeNi, to form Al0.3CoCrFeNi, leads to the precipitation of highly refined ordered L12 precipitates, which are stable at 550 degree C. However, the L12 precipitates (stoichiometry of (Ni,Cr)3(Al,Fe,Co)) are de-stabilized and replaced by coarser B2 precipitates on annealing at 700 degree C. Contrastingly, in the Co-free, Al0.3CuCrFeNi2 high entropy alloy, the L12 precipitates are stable at both 550 degree C (~5nm) and 700 degree C (~50nm), and exhibit a stoichiometry of (Ni,Cu)3(Al,Fe,Cr). These results lead to interesting insights into the stability of ordered phases in HEAs as a function of composition and temperature. |
Author | Hong, S.H. Banerjee, R. Soni, V. Ryu, H. Lee, M. Choudhuri, D. Hwang, J.Y. Gwalani, B. Nam, S.J. |
Author_xml | – sequence: 1 givenname: B. surname: Gwalani fullname: Gwalani, B. organization: Advanced Materials and Manufacturing Processes Institute, University of North Texas, Denton, TX-76207, USA – sequence: 2 givenname: V. surname: Soni fullname: Soni, V. organization: Department of Materials Science and Engineering, University of North Texas, Denton, TX-76207, USA – sequence: 3 givenname: D. surname: Choudhuri fullname: Choudhuri, D. organization: Department of Materials Science and Engineering, University of North Texas, Denton, TX-76207, USA – sequence: 4 givenname: M. surname: Lee fullname: Lee, M. organization: Department of Materials Science and Engineering, University of North Texas, Denton, TX-76207, USA – sequence: 5 givenname: J.Y. surname: Hwang fullname: Hwang, J.Y. organization: Institute of Advanced Composite Materials, Korea Institute of Science and Technology, Jeonbuk 565-905, South Korea – sequence: 6 givenname: S.J. surname: Nam fullname: Nam, S.J. organization: Institute of Advanced Composite Materials, Korea Institute of Science and Technology, Jeonbuk 565-905, South Korea – sequence: 7 givenname: H. surname: Ryu fullname: Ryu, H. organization: Department of Nuclear and Quantum Engineering, Korea Advanced Institute of Science and Technology, Daejeon 305-701, South Korea – sequence: 8 givenname: S.H. surname: Hong fullname: Hong, S.H. organization: Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology, Daejeon 305-701, South Korea – sequence: 9 givenname: R. surname: Banerjee fullname: Banerjee, R. email: Rajarshi.Banerjee@unt.edu organization: Advanced Materials and Manufacturing Processes Institute, University of North Texas, Denton, TX-76207, USA |
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Snippet | Adding a small amount of Al to the well-known high entropy alloy (HEA), Al0.1CoCrFeNi, to form Al0.3CoCrFeNi, leads to the precipitation of highly refined... |
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SubjectTerms | Alloys Atom probe tomography Entropy High entropy alloys L12 Phases Positioning Precipitates Precipitation Solute partitioning Stability Stoichiometry |
Title | Stability of ordered L12 and B2 precipitates in face centered cubic based high entropy alloys - Al0.3CoFeCrNi and Al0.3CuFeCrNi2 |
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