Thermodynamic Properties of Eutectic Silumins Doped by Transition Metals
The thermodynamic properties of the liquid silumins (Al Si Tr , where Tr = Cu, Fe, Ni and Ti, have been measured, using the electromotive force method at 1040 K. It has been found that diluted solutions of Fe or Ni in eutectic silumins at Tr molar fractions of 0 < x ≤ 0.035 and 0 < x ≤ 0.027 a...
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| Published in | Zeitschrift für Naturforschung. A, A journal of physical sciences Vol. 59; no. 4; pp. 288 - 290 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Verlag der Zeitschrift für Naturforschung
01.05.2004
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| Subjects | |
| Online Access | Get full text |
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| Abstract | The thermodynamic properties of the liquid silumins (Al
Si
Tr
, where Tr = Cu, Fe, Ni and Ti, have been measured, using the electromotive force method at 1040 K. It has been found that diluted solutions of Fe or Ni in eutectic silumins at Tr molar fractions of 0 < x
≤ 0.035 and 0 < x
≤ 0.027 are characterized by positive deviations from ideality for aluminium. However, the deviations become negative at increasing of the Tr concentration. However, molten silumins doped by Ti and Cu show negative deviations from Raoult’s law for aluminium at the studied concentrations. Thermodynamic activity of Al in the silumins decreases in the sequence of Fe→Ni→Cu→Ti for the dopants. |
|---|---|
| AbstractList | The thermodynamic properties of the liquid silumins (Al
Si
Tr
, where Tr = Cu, Fe, Ni and Ti, have been measured, using the electromotive force method at 1040 K. It has been found that diluted solutions of Fe or Ni in eutectic silumins at Tr molar fractions of 0 < x
≤ 0.035 and 0 < x
≤ 0.027 are characterized by positive deviations from ideality for aluminium. However, the deviations become negative at increasing of the Tr concentration. However, molten silumins doped by Ti and Cu show negative deviations from Raoult’s law for aluminium at the studied concentrations. Thermodynamic activity of Al in the silumins decreases in the sequence of Fe→Ni→Cu→Ti for the dopants. The thermodynamic properties of the liquid silumins (Al 0.879 Si 0.121 ) 1−x Tr x , where Tr = Cu, Fe, Ni and Ti, have been measured, using the electromotive force method at 1040 K. It has been found that diluted solutions of Fe or Ni in eutectic silumins at Tr molar fractions of 0 < x Fe ≤ 0.035 and 0 < x Ni ≤ 0.027 are characterized by positive deviations from ideality for aluminium. However, the deviations become negative at increasing of the Tr concentration. However, molten silumins doped by Ti and Cu show negative deviations from Raoult’s law for aluminium at the studied concentrations. Thermodynamic activity of Al in the silumins decreases in the sequence of Fe→Ni→Cu→Ti for the dopants. |
| Author | Lisnyak, V. V. Stukalo, V. A. Kanibolotsky, D. S. |
| Author_xml | – sequence: 1 givenname: D. S. surname: Kanibolotsky fullname: Kanibolotsky, D. S. organization: Biophysical Department, Academician Peter Bogach Institute, Glushkova Ave. 2, corpus 12, Kiev 03022, Ukraine – sequence: 2 givenname: V. A. surname: Stukalo fullname: Stukalo, V. A. organization: Chemical Department of Kiev National Taras Shevchenko University, Vladimirskaya Street 64, Kiev 01033, Ukraine – sequence: 3 givenname: V. V. surname: Lisnyak fullname: Lisnyak, V. V. email: lisnyak@chem.univ.kiev.ua organization: Chemical Department of Kiev National Taras Shevchenko University, Vladimirskaya Street 64, Kiev 01033, Ukraine |
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| Snippet | The thermodynamic properties of the liquid silumins (Al
Si
Tr
, where Tr = Cu, Fe, Ni and Ti, have been measured, using the electromotive force method at 1040... The thermodynamic properties of the liquid silumins (Al 0.879 Si 0.121 ) 1−x Tr x , where Tr = Cu, Fe, Ni and Ti, have been measured, using the electromotive... |
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| SubjectTerms | Al-Si-(Cu Electromotive Force Method Gibbs Energy Liquid Alloys Silumins Thermodynamic Activity Ti |
| Title | Thermodynamic Properties of Eutectic Silumins Doped by Transition Metals |
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