Effect of Crosslinking Agents on the Morphology of Polymer Particles Produced by One-Step Seeded Polymerization

One-step seeded polymerization was used to prepare 7∼10 μm of crosslinked monodisperse spheres with four crosslinking agents using 4.68 μm poly(methyl methacrylate) (PMMA) seed particles in aqueous-alcoholic media in the absence of the swelling process. The crosslinking agents used were ethylene gly...

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Published inMacromolecular research Vol. 17; no. 4; pp. 250 - 258
Main Authors Kim, Donghee, Lee, Do Yang, Lee, Kangseok, Choe, Soonja
Format Journal Article
LanguageEnglish
Published Berlin/Heidelberg 한국고분자학회 01.04.2009
Springer-Verlag
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Abstract One-step seeded polymerization was used to prepare 7∼10 μm of crosslinked monodisperse spheres with four crosslinking agents using 4.68 μm poly(methyl methacrylate) (PMMA) seed particles in aqueous-alcoholic media in the absence of the swelling process. The crosslinking agents used were ethylene glycol dimethacrylate (EGDMA), allyl methacrylate (AMA), 1,6-hexanediol diacrylate (HDDA) and trimethylolpropane trimethacrylate (TMPTMA). The effects of the type and concentration of the crosslinking agents on the swelling, pore size, thermal property of the networks and morphology of the particles were studied. The chemical structures and concentrations of the crosslinking agents affected both the swelling ratio and the porosity of the networks. In addition, the chemistry of the reactive vinyl group and chain length of the crosslinking agents affected the stability of the monodisperse particles of the ultimate morphology.
AbstractList One-step seeded polymerization was used to prepare 7~10 μm of crosslinked monodisperse spheres with four crosslinking agents using 4.68 μm poly(methyl methacrylate) (PMMA) seed particles in aqueous-alcoholic media in the absence of the swelling process. The crosslinking agents used were ethylene glycol dimethacrylate (EGDMA), allyl methacrylate (AMA), 1,6-hexanediol diacrylate (HDDA) and trimethylolpropane trimethacrylate (TMPTMA). The effects of the type and concentration of the crosslinking agents on the swelling, pore size, thermal property of the networks and morphology of the particles were studied. The chemical structures and concentrations of the crosslinking agents affected both the swelling ratio and the porosity of the networks. In addition, the chemistry of the reactive vinyl group and chain length of the crosslinking agents affected the stability of the monodisperse particles of the ultimate morphology. KCI Citation Count: 30
One-step seeded polymerization was used to prepare 7∼10 μm of crosslinked monodisperse spheres with four crosslinking agents using 4.68 μm poly(methyl methacrylate) (PMMA) seed particles in aqueous-alcoholic media in the absence of the swelling process. The crosslinking agents used were ethylene glycol dimethacrylate (EGDMA), allyl methacrylate (AMA), 1,6-hexanediol diacrylate (HDDA) and trimethylolpropane trimethacrylate (TMPTMA). The effects of the type and concentration of the crosslinking agents on the swelling, pore size, thermal property of the networks and morphology of the particles were studied. The chemical structures and concentrations of the crosslinking agents affected both the swelling ratio and the porosity of the networks. In addition, the chemistry of the reactive vinyl group and chain length of the crosslinking agents affected the stability of the monodisperse particles of the ultimate morphology.
Author Do Yang Lee
Soon Ja Choe
Dong Hee Kim
Kang Seok Lee
Author_xml – sequence: 1
  givenname: Donghee
  surname: Kim
  fullname: Kim, Donghee
  organization: Department of Chemical Engineering, Inha University
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  givenname: Do Yang
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  fullname: Lee, Do Yang
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  givenname: Soonja
  surname: Choe
  fullname: Choe, Soonja
  email: sjchoe@inha.ac.kr
  organization: Department of Chemical Engineering, Inha University
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Keywords PMMA seed
one-step seeded polymerization
crosslinking agent
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Snippet One-step seeded polymerization was used to prepare 7∼10 μm of crosslinked monodisperse spheres with four crosslinking agents using 4.68 μm poly(methyl...
One-step seeded polymerization was used to prepare 7~10 μm of crosslinked monodisperse spheres with four crosslinking agents using 4.68 μm poly(methyl...
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SubjectTerms Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Complex Fluids and Microfluidics
Nanochemistry
Nanotechnology
Physical Chemistry
Polymer Sciences
Soft and Granular Matter
고분자공학
Title Effect of Crosslinking Agents on the Morphology of Polymer Particles Produced by One-Step Seeded Polymerization
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Volume 17
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