Decarboxylative bromination of α,β-unsaturated carboxylic acids via an anodic oxidation

A novel bromination of α,β-unsaturated carboxylic acids was developed via a decarboxylation by virtue of a direct anodic electro-oxidation.In this method,ammonium bromide was employed as a bromine source and the reaction features transition-metal-free,short time,and no additional supporting electrol...

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Bibliographic Details
Published inChinese chemical letters Vol. 28; no. 6; pp. 1159 - 1162
Main Authors Bi, Mei-Xiang, Qian, Peng, Wang, Yu-Kang, Zha, Zheng-Gen, Wang, Zhi-Yong
Format Journal Article
LanguageEnglish
Published NEW YORK Elsevier B.V 01.06.2017
Elsevier
Subjects
Ammonium bromide
Anodic oxidation
Chemistry
Chemistry, Multidisciplinary
Decarboxylative bromination
Electro-oxidation
Physical Sciences
Science & Technology
α,β-Unsaturated carboxylic acids
Anodic oxidation
Decarboxylative bromination
α,β-Unsaturated carboxylic acids
Electro-oxidation
Ammonium bromide
ELECTROSYNTHESIS
DIFUNCTIONALIZATION
ALCOHOLS
KETONES
alpha,beta-Unsaturated carboxylic acids
EFFICIENT
ACCESS
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Summary:A novel bromination of α,β-unsaturated carboxylic acids was developed via a decarboxylation by virtue of a direct anodic electro-oxidation.In this method,ammonium bromide was employed as a bromine source and the reaction features transition-metal-free,short time,and no additional supporting electrolyte.
Bibliography:A novel bromination of α,β-unsaturated carboxylic acids was developed via a decarboxylation by virtue of a direct anodic electro-oxidation.In this method,ammonium bromide was employed as a bromine source and the reaction features transition-metal-free,short time,and no additional supporting electrolyte.
11-2710/O6
Decarboxylative bromination α β-Unsaturated carboxylic acids Ammonium bromide Anodic oxidation Electro-oxidation
ISSN:1001-8417
1878-5964
DOI:10.1016/j.cclet.2017.04.030