Surface structure and anion effects in the oxidation of ethanol on platinum nanoparticles
Ethanol oxidation on platinum nanoparticles with well-characterized surfaces is studied using cyclic voltammetry and FTIR techniques. Their behavior is compared with that obtained for platinum single crystal electrodes, in order to rationalize their performance and to understand the effects of the s...
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| Published in | Journal of materials chemistry. A, Materials for energy and sustainability Vol. 1; no. 24; pp. 7068 - 7076 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
01.01.2013
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| Subjects | |
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| Abstract | Ethanol oxidation on platinum nanoparticles with well-characterized surfaces is studied using cyclic voltammetry and FTIR techniques. Their behavior is compared with that obtained for platinum single crystal electrodes, in order to rationalize their performance and to understand the effects of the surface structure and anion adsorption on the reactivity. The results clearly demonstrate that there are strong effects of anion adsorption and surface structure on the measured current and oxidation mechanism. Thus, the main product of ethanol oxidation on (111) preferentially oriented Pt nanoparticles is acetic acid, and the amount of CO sub(2) produced can be considered negligible. On the other hand, (100) preferentially oriented Pt nanoparticles are effective for the cleavage of the C-C bond yielding adsorbed CO, which eventually is oxidized to CO sub(2). This nanoparticles electrode has the highest catalytic activity at high potentials, whereas (111) preferentially oriented Pt nanoparticles are more active at low potentials. In addition, no significant differences in the activity are reported by using different supporting electrolytes, which indicates that adsorbed acetate, which results from the adsorption of acetic acid, hinders ethanol oxidation. |
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| AbstractList | Ethanol oxidation on platinum nanoparticles with well-characterized surfaces is studied using cyclic voltammetry and FTIR techniques. Their behavior is compared with that obtained for platinum single crystal electrodes, in order to rationalize their performance and to understand the effects of the surface structure and anion adsorption on the reactivity. The results clearly demonstrate that there are strong effects of anion adsorption and surface structure on the measured current and oxidation mechanism. Thus, the main product of ethanol oxidation on (111) preferentially oriented Pt nanoparticles is acetic acid, and the amount of CO sub(2) produced can be considered negligible. On the other hand, (100) preferentially oriented Pt nanoparticles are effective for the cleavage of the C-C bond yielding adsorbed CO, which eventually is oxidized to CO sub(2). This nanoparticles electrode has the highest catalytic activity at high potentials, whereas (111) preferentially oriented Pt nanoparticles are more active at low potentials. In addition, no significant differences in the activity are reported by using different supporting electrolytes, which indicates that adsorbed acetate, which results from the adsorption of acetic acid, hinders ethanol oxidation. |
| Author | Feliu, Juan M. Busó-Rogero, Carlos Solla-Gullón, José Vidal-Iglesias, Francisco J. Herrero, Enrique Grozovski, Vitali |
| Author_xml | – sequence: 1 givenname: Carlos surname: Busó-Rogero fullname: Busó-Rogero, Carlos – sequence: 2 givenname: Vitali surname: Grozovski fullname: Grozovski, Vitali – sequence: 3 givenname: Francisco J. surname: Vidal-Iglesias fullname: Vidal-Iglesias, Francisco J. – sequence: 4 givenname: José surname: Solla-Gullón fullname: Solla-Gullón, José – sequence: 5 givenname: Enrique surname: Herrero fullname: Herrero, Enrique – sequence: 6 givenname: Juan M. surname: Feliu fullname: Feliu, Juan M. |
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| Snippet | Ethanol oxidation on platinum nanoparticles with well-characterized surfaces is studied using cyclic voltammetry and FTIR techniques. Their behavior is... |
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| SubjectTerms | Anions Ethanol Ethyl alcohol Nanoparticles Oxidation Platinum Surface chemistry Surface structure |
| Title | Surface structure and anion effects in the oxidation of ethanol on platinum nanoparticles |
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