Triazatruxene based covalent organic framework and its quick-response fluorescence-on nature towards electron rich arenes

Two new 2D covalent organic frameworks (COFs) with a regular honeycomb lattice, TAT-COF-1 and TAT-COF-2, were synthesized based on triazatruxene derivatives. The two COFs, especially TAT-COF-2, have a large BET surface area, good crystallinity, moderate to good hydrogen and carbon dioxide adsorption...

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Published inJournal of materials chemistry. C, Materials for optical and electronic devices Vol. 3; no. 39; pp. 10066 - 10069
Main Authors Xie, Yun-Feng, Ding, San-Yuan, Liu, Jun-Min, Wang, Wei, Zheng, Qi-Yu
Format Journal Article
LanguageEnglish
Published 01.01.2015
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Abstract Two new 2D covalent organic frameworks (COFs) with a regular honeycomb lattice, TAT-COF-1 and TAT-COF-2, were synthesized based on triazatruxene derivatives. The two COFs, especially TAT-COF-2, have a large BET surface area, good crystallinity, moderate to good hydrogen and carbon dioxide adsorption abilities and also possess good CO 2 /N 2 selectivity. When suspended in ethanol, the fluorescence of TAT-COF-2 could be enhanced or quenched by different solvents. It also shows a rapid fluorescence-on and fluorescence-off nature towards electron rich and deficient arene vapors, respectively. After being exposed to electron-rich arene vapors, the enhanced fluorescence intensity can be recovered to normal level after 5 minutes in an ambient atmosphere, which means the sample could be reused conveniently for detecting electron rich arene vapors.
AbstractList Two new 2D covalent organic frameworks (COFs) with a regular honeycomb lattice, TAT-COF-1 and TAT-COF-2, were synthesized based on triazatruxene derivatives. The two COFs, especially TAT-COF-2, have a large BET surface area, good crystallinity, moderate to good hydrogen and carbon dioxide adsorption abilities and also possess good CO sub(2)/N sub(2) selectivity. When suspended in ethanol, the fluorescence of TAT-COF-2 could be enhanced or quenched by different solvents. It also shows a rapid fluorescence-on and fluorescence-off nature towards electron rich and deficient arene vapors, respectively. After being exposed to electron-rich arene vapors, the enhanced fluorescence intensity can be recovered to normal level after 5 minutes in an ambient atmosphere, which means the sample could be reused conveniently for detecting electron rich arene vapors.
Two new 2D covalent organic frameworks (COFs) with a regular honeycomb lattice, TAT-COF-1 and TAT-COF-2, were synthesized based on triazatruxene derivatives. The two COFs, especially TAT-COF-2, have a large BET surface area, good crystallinity, moderate to good hydrogen and carbon dioxide adsorption abilities and also possess good CO 2 /N 2 selectivity. When suspended in ethanol, the fluorescence of TAT-COF-2 could be enhanced or quenched by different solvents. It also shows a rapid fluorescence-on and fluorescence-off nature towards electron rich and deficient arene vapors, respectively. After being exposed to electron-rich arene vapors, the enhanced fluorescence intensity can be recovered to normal level after 5 minutes in an ambient atmosphere, which means the sample could be reused conveniently for detecting electron rich arene vapors.
Author Xie, Yun-Feng
Wang, Wei
Ding, San-Yuan
Liu, Jun-Min
Zheng, Qi-Yu
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  organization: Beijing National Laboratory for Molecular Science, CAS, Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences
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  givenname: San-Yuan
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  fullname: Ding, San-Yuan
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  organization: State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, China
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  givenname: Qi-Yu
  surname: Zheng
  fullname: Zheng, Qi-Yu
  organization: Beijing National Laboratory for Molecular Science, CAS, Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences
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Snippet Two new 2D covalent organic frameworks (COFs) with a regular honeycomb lattice, TAT-COF-1 and TAT-COF-2, were synthesized based on triazatruxene derivatives....
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StartPage 10066
SubjectTerms Aromatic compounds
Carbon dioxide
Covalence
Derivatives
Ethanol
Ethyl alcohol
Fluorescence
Honeycomb
Solvents
Title Triazatruxene based covalent organic framework and its quick-response fluorescence-on nature towards electron rich arenes
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