Accessing bridged bicyclic compounds or meta carbon-functionalized anilines from the dearomatization of anilines
The oxidative dearomatization of anilines was combined with a domino Michael addition, providing a series of nitrogen-containing bridged bicyclic compounds in moderate to excellent yields. The bridged bicyclic compound could be converted into the corresponding meta carbon-functionalized aniline deri...
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| Published in | RSC advances Vol. 3; no. 17; pp. 5775 - 5778 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
01.01.2013
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| Subjects | |
| Online Access | Get full text |
| ISSN | 2046-2069 2046-2069 |
| DOI | 10.1039/c3ra23224g |
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| Abstract | The oxidative dearomatization of anilines was combined with a domino Michael addition, providing a series of nitrogen-containing bridged bicyclic compounds in moderate to excellent yields. The bridged bicyclic compound could be converted into the corresponding meta carbon-functionalized aniline derivative via a quinine-catalyzed tandem retro-oxa-Michael addition–aromatization reaction. |
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| AbstractList | The oxidative dearomatization of anilines was combined with a domino Michael addition, providing a series of nitrogen-containing bridged bicyclic compounds in moderate to excellent yields. The bridged bicyclic compound could be converted into the corresponding meta carbon-functionalized aniline derivative via a quinine-catalyzed tandem retro-oxa-Michael addition–aromatization reaction. |
| Author | Wang, Shuo-En Wang, Linfei Wang, Weibin Fan, Renhua |
| Author_xml | – sequence: 1 givenname: Linfei surname: Wang fullname: Wang, Linfei – sequence: 2 givenname: Shuo-En surname: Wang fullname: Wang, Shuo-En – sequence: 3 givenname: Weibin surname: Wang fullname: Wang, Weibin – sequence: 4 givenname: Renhua surname: Fan fullname: Fan, Renhua |
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| CitedBy_id | crossref_primary_10_1002_ajoc_202100152 crossref_primary_10_2174_1385272824666200211093103 crossref_primary_10_1021_acs_orglett_0c01009 crossref_primary_10_1039_C8OB02970A |
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