Harnessing Lithium‐Mediated Green Ammonia Synthesis with Water Electrolysis Boosted by Membrane Electrolyzer with Polyoxometalate Proton Shuttles

• Published in: Angewandte Chemie International Edition Vol. 64; no. 27; pp. e202503465 - n/a
• Main Authors: Miao, Jun, Chen, Cailing, Cao, Li, Al Nuaimi, Reham, Li, Zhen, Huang, Kuo‐Wei, Lai, Zhiping
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 01.07.2025
• Edition: International ed. in English
• Subjects: Ammonia; Buffers (chemistry); Electrochemical processes; Electrolysis; Green chemistry; Hydrogen; Hydrogen evolution reactions; Hydrophobicity; Intermediates; Ion‐conducting membranes; Lithium; Membrane technology; Oxidation; Polymethyl methacrylate; Polymethylmethacrylate; Polyoxometalates; Polyoxometallates; Protons; Reactor technology; Reactors; Sustainable ammonia production; Synthesis; Water pollution; Sustainable ammonia production; Polyoxometalates; Electrochemical processes; Membrane technology; Ion‐conducting membranes

Integrating water electrolysis (WE) with lithium‐mediated nitrogen reduction (Li‐NRR) offers a sustainable route for green ammonia production by directly utilizing protons from water oxidation, eliminating reliance on grey or blue hydrogen. Here, polyoxometalates (POMs) function as electron‐coupled...