Controlling the Chirality of Metallo‐Cages by Manipulating the Stereochemistry of the Metal Centers

• Published in: Angewandte Chemie International Edition Vol. 64; no. 23; pp. e202503833 - n/a
• Main Authors: Li, Yu‐Qing, Fu, Lei, Jiang, Zhiyuan, Han, Ermeng, Li, Tian, Bai, Qixia, Xie, Ting‐Zheng, Zhang, Zhe, Wang, Pingshan, Wu, Tun
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 02.06.2025
• Edition: International ed. in English
• Subjects: Cages; Chiral induction; Chirality; Dynamics of metal ions; Handedness; Host–guest chemistry; Lability; Ligands; Metal ions; Metallography; Metallo‐cuboctahedra; Spontaneous resolution; Stereochemistry; Supramolecular compounds; Metallo‐cuboctahedra; Host–guest chemistry; Chiral induction; Dynamics of metal ions; Spontaneous resolution
• ISSN: 1433-7851; 1521-3773; 1521-3773
• DOI: 10.1002/anie.202503833

Precise control over the chirality of metallo‐cages by manipulating the stereochemistry of metal centers is important in many practical applications, but is extremely challenging. In this study, two isostructural metallo‐cuboctahedra (1‐ZnII12L18 and 2‐CdII12L18) have been assembled using ligand L1...