Enhancement and Prediction of Adhesion Strength of Copper Cold Spray Coatings on Steel Substrates for Nuclear Fuel Repository

Thick copper coatings have been envisioned as corrosion protection barriers for steel containers used in repositories for nuclear waste fuel bundles. Due to its high deposition rate and low oxidation levels, cold spray is considered as an option to produce these coatings as an alternative to traditi...

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Published inJournal of thermal spray technology Vol. 25; no. 8; pp. 1577 - 1587
Main Authors Fernández, R., MacDonald, D., Nastić, A., Jodoin, B., Tieu, A., Vijay, M.
Format Journal Article
LanguageEnglish
Published New York Springer US 01.12.2016
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Abstract Thick copper coatings have been envisioned as corrosion protection barriers for steel containers used in repositories for nuclear waste fuel bundles. Due to its high deposition rate and low oxidation levels, cold spray is considered as an option to produce these coatings as an alternative to traditional machining processes to create corrosion protective sleeves. Previous investigations on the deposition of thick cold spray copper coatings using only nitrogen as process gas on carbon steel substrates have continuously resulted in coating delamination. The current work demonstrates the possibility of using an innovative surface preparation process, forced pulsed waterjet, to induce a complex substrate surface morphology that serves as anchoring points for the copper particles to mechanically adhere to the substrate. The results of this work show that, through the use of this surface preparation method, adhesion strength can be drastically increased, and thick copper coatings can be deposited using nitrogen. Through finite element analysis, it was shown that it is likely that the bonding created is purely mechanical, explaining the lack of adhesion when conventional substrate preparation methods are used and why helium is usually required as process gas.
AbstractList Thick copper coatings have been envisioned as corrosion protection barriers for steel containers used in repositories for nuclear waste fuel bundles. Due to its high deposition rate and low oxidation levels, cold spray is considered as an option to produce these coatings as an alternative to traditional machining processes to create corrosion protective sleeves. Previous investigations on the deposition of thick cold spray copper coatings using only nitrogen as process gas on carbon steel substrates have continuously resulted in coating delamination. The current work demonstrates the possibility of using an innovative surface preparation process, forced pulsed waterjet, to induce a complex substrate surface morphology that serves as anchoring points for the copper particles to mechanically adhere to the substrate. The results of this work show that, through the use of this surface preparation method, adhesion strength can be drastically increased, and thick copper coatings can be deposited using nitrogen. Through finite element analysis, it was shown that it is likely that the bonding created is purely mechanical, explaining the lack of adhesion when conventional substrate preparation methods are used and why helium is usually required as process gas.
Author Tieu, A.
Fernández, R.
Jodoin, B.
Vijay, M.
MacDonald, D.
Nastić, A.
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  surname: Fernández
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  givenname: D.
  surname: MacDonald
  fullname: MacDonald, D.
  organization: Cold Spray Research Laboratory, University of Ottawa
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  surname: Nastić
  fullname: Nastić, A.
  organization: Cold Spray Research Laboratory, University of Ottawa
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  surname: Jodoin
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  organization: Cold Spray Research Laboratory, University of Ottawa
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  surname: Tieu
  fullname: Tieu, A.
  organization: VLN Advanced Technologies Inc
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  givenname: M.
  surname: Vijay
  fullname: Vijay, M.
  organization: VLN Advanced Technologies Inc
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Issue 8
Keywords FEA
cold spray
mechanical anchoring
substrate preparation
nuclear waste management
adhesion
forced pulsed waterjet
Language English
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Snippet Thick copper coatings have been envisioned as corrosion protection barriers for steel containers used in repositories for nuclear waste fuel bundles. Due to...
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StartPage 1577
SubjectTerms Analytical Chemistry
Characterization and Evaluation of Materials
Chemistry and Materials Science
Corrosion and Coatings
Machines
Manufacturing
Materials Science
Peer Reviewed
Processes
Surfaces and Interfaces
Thin Films
Tribology
Title Enhancement and Prediction of Adhesion Strength of Copper Cold Spray Coatings on Steel Substrates for Nuclear Fuel Repository
URI https://link.springer.com/article/10.1007/s11666-016-0467-8
Volume 25
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