Emerging trends in olefin polymerization: a perspective

The seemingly matured field of olefin polymerization still poses several challenges and holds enormous potential to meet contemporary material requirements. In this feature article, we examine the progress of olefin polymerization in the last two decades. Among the several emerging trends, we identi...

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Published inJournal of macromolecular science. Part A, Pure and applied chemistry Vol. 60; no. 11; pp. 731 - 750
Main Authors Birajdar, Rajkumar S., Bodkhe, Dnyaneshwar, Gupta, Poonam, Shaikh, Maulali H., Ramekar, Rohan, Chikkali, Samir H.
Format Journal Article
LanguageEnglish
Published New York Marcel Dekker, Inc 02.11.2023
Subjects
Alkenes
Catalysts
Compatibilizers
Copolymerization
Insertion
Metallocenes
Molecular weight
Palladium
Polyethylene
Polymerization
Polyolefins
Trends
Ultra high molecular weight polyethylene
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Abstract The seemingly matured field of olefin polymerization still poses several challenges and holds enormous potential to meet contemporary material requirements. In this feature article, we examine the progress of olefin polymerization in the last two decades. Among the several emerging trends, we identify four most impactful discoveries, namely, (i) disentangled ultra-high molecular weight polyethylene (dUHMWPE), (ii) disubstituted functional olefin copolymerization, (iii) incorporation of bioderived comonomers in polyolefins, and (iv) application of above (ii, iii) functional polyolefins as compatibilizers. The dUHMWPE has attracted significant attention and heterogeneous Ziegler-type catalysts, homogenous metallocene, and post-metallocene catalysts have been reported to produce disentangled ultrahigh molecular weight polyethylene. Insertion copolymerization of difunctional disubstituted olefins has been reported only recently and ortho-phosphinobenzene sulfonate palladium catalyst outperforms the other catalysts. Interestingly, insertion copolymerization of bioderived olefins has witnessed a surge in the number of reports. Sugar and plant oil-derived olefins have been copolymerized with ethylene to obtain relatively hydrophilic polyethylene. The functional polyethylene is finding a new application as compatibilizer or displays better adhesion to surfaces. Thus, the feature article offers a succinct account of emerging trends in polyolefins, identifies the most impactful contributions, and debates the application potential of these new materials.
AbstractList The seemingly matured field of olefin polymerization still poses several challenges and holds enormous potential to meet contemporary material requirements. In this feature article, we examine the progress of olefin polymerization in the last two decades. Among the several emerging trends, we identify four most impactful discoveries, namely, (i) disentangled ultra-high molecular weight polyethylene (dUHMWPE), (ii) disubstituted functional olefin copolymerization, (iii) incorporation of bioderived comonomers in polyolefins, and (iv) application of above (ii, iii) functional polyolefins as compatibilizers. The dUHMWPE has attracted significant attention and heterogeneous Ziegler-type catalysts, homogenous metallocene, and post-metallocene catalysts have been reported to produce disentangled ultrahigh molecular weight polyethylene. Insertion copolymerization of difunctional disubstituted olefins has been reported only recently and ortho-phosphinobenzene sulfonate palladium catalyst outperforms the other catalysts. Interestingly, insertion copolymerization of bioderived olefins has witnessed a surge in the number of reports. Sugar and plant oil-derived olefins have been copolymerized with ethylene to obtain relatively hydrophilic polyethylene. The functional polyethylene is finding a new application as compatibilizer or displays better adhesion to surfaces. Thus, the feature article offers a succinct account of emerging trends in polyolefins, identifies the most impactful contributions, and debates the application potential of these new materials.
Author Birajdar, Rajkumar S.
Chikkali, Samir H.
Bodkhe, Dnyaneshwar
Ramekar, Rohan
Gupta, Poonam
Shaikh, Maulali H.
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Snippet The seemingly matured field of olefin polymerization still poses several challenges and holds enormous potential to meet contemporary material requirements. In...
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SubjectTerms Alkenes
Catalysts
Compatibilizers
Copolymerization
Insertion
Metallocenes
Molecular weight
Palladium
Polyethylene
Polymerization
Polyolefins
Trends
Ultra high molecular weight polyethylene
Title Emerging trends in olefin polymerization: a perspective
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