Negative coercivity of magnetic elastomers filled with magnetically hard particles
•Magnetic elastomer filled with magnetically hard particles has been investigated for magnetic properties.•The magnetic filler dispersed in the polymer matrix exhibits asignificant asymmetry of the hysteresis loop.•Pronounced asymmetry can lead to a “negative” coercivity on the full hysteresis loop....
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Published in | Journal of magnetism and magnetic materials Vol. 498; p. 166125 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
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Elsevier B.V
15.03.2020
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Abstract | •Magnetic elastomer filled with magnetically hard particles has been investigated for magnetic properties.•The magnetic filler dispersed in the polymer matrix exhibits asignificant asymmetry of the hysteresis loop.•Pronounced asymmetry can lead to a “negative” coercivity on the full hysteresis loop.•The effects are caused by rotation motion performed by magnetic particles inside the polymer matrix.
This research is dedicated to the specifics of the behavior exhibited by elastomer filled with magnetically hard (high-coercivity) particles influenced by magnetic fields. Composite materials of this type are also mentioned as magnetorheological, magnetoactive, and hybrid. There have been done studies on the magnetization processes taking place in ME’s containing magnetically hard spherical NdFeB-alloy particles. As was found out, the coercivity exhibited by a sample can be significantly weaker in comparison to that demonstrated by the filler in pure form. It was also discovered that the coercivity may have negative values in positive magnetic fields. These effects are determined by the magnitude relation of the remnant magnetization of the sample, elasticity of the polymer matrix, strength of the external magnetic field, and the capability of magnetic particles to turn inside the polymer matrix as the magnetic field changes polarity to opposite. |
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AbstractList | This research is dedicated to the specifics of the behavior exhibited by elastomer filled with magnetically hard (high-coercivity) particles influenced by magnetic fields. Composite materials of this type are also mentioned as magnetorheological, magnetoactive, and hybrid. There have been done studies on the magnetization processes taking place in ME's containing magnetically hard spherical NdFeB-alloy particles. As was found out, the coercivity exhibited by a sample can be significantly weaker in comparison to that demonstrated by the filler in pure form. It was also discovered that the coercivity may have negative values in positive magnetic fields. These effects are determined by the magnitude relation of the remnant magnetization of the sample, elasticity of the polymer matrix, strength of the external magnetic field, and the capability of magnetic particles to turn inside the polymer matrix as the magnetic field changes polarity to opposite. •Magnetic elastomer filled with magnetically hard particles has been investigated for magnetic properties.•The magnetic filler dispersed in the polymer matrix exhibits asignificant asymmetry of the hysteresis loop.•Pronounced asymmetry can lead to a “negative” coercivity on the full hysteresis loop.•The effects are caused by rotation motion performed by magnetic particles inside the polymer matrix. This research is dedicated to the specifics of the behavior exhibited by elastomer filled with magnetically hard (high-coercivity) particles influenced by magnetic fields. Composite materials of this type are also mentioned as magnetorheological, magnetoactive, and hybrid. There have been done studies on the magnetization processes taking place in ME’s containing magnetically hard spherical NdFeB-alloy particles. As was found out, the coercivity exhibited by a sample can be significantly weaker in comparison to that demonstrated by the filler in pure form. It was also discovered that the coercivity may have negative values in positive magnetic fields. These effects are determined by the magnitude relation of the remnant magnetization of the sample, elasticity of the polymer matrix, strength of the external magnetic field, and the capability of magnetic particles to turn inside the polymer matrix as the magnetic field changes polarity to opposite. |
ArticleNumber | 166125 |
Author | Stepanov, G.V. Borin, D.Yu Storozhenko, P.A. Bakhtiiarov, A.V. |
Author_xml | – sequence: 1 givenname: G.V. surname: Stepanov fullname: Stepanov, G.V. email: gstepanov@mail.ru organization: State Scientific Research Institute for Chemical Technologies of Organoelement Compounds, 105118 Moscow, Russia – sequence: 2 givenname: D.Yu surname: Borin fullname: Borin, D.Yu organization: TU Dresden, Chair of Magnetofluiddynamics, Measuring and Automation Technology, Dresden D-01062, Germany – sequence: 3 givenname: A.V. surname: Bakhtiiarov fullname: Bakhtiiarov, A.V. organization: State Scientific Research Institute for Chemical Technologies of Organoelement Compounds, 105118 Moscow, Russia – sequence: 4 givenname: P.A. surname: Storozhenko fullname: Storozhenko, P.A. organization: State Scientific Research Institute for Chemical Technologies of Organoelement Compounds, 105118 Moscow, Russia |
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Cites_doi | 10.1088/0964-1726/24/3/035002 10.1016/j.jmmm.2017.09.081 10.1088/1361-665X/aa7396 10.1016/j.jmmm.2012.02.062 10.1039/C6RA23435F 10.1016/j.jmmm.2016.07.051 10.1088/1361-665X/aa75ec 10.1088/1361-665X/aa5d3c 10.1039/C9SM00736A 10.1007/s00419-018-1456-9 10.1088/1742-6596/412/1/012040 10.1134/S0965545X14050149 10.1016/j.jmmm.2017.12.016 |
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References | Stepanov, Borin, Storozhenko (b0055) 2017 Gunther, Becker, Becker, Stepanov, Zimmermann (b0050) 2017 Stepanov, Chertovich, Kramarenko (b0005) 2012; 324 Borin, Stepanov (b0015) 2013; 15 Linke, Borin, Odenbach (b0065) 2016; 6 Volkova, Böhm, Kaufhold, Popp, Becker, Borin, Stepanov, Zimmermann (b0035) 2017 Kramarenko, Chertovich, Stepanov, Semisalova, Makarova, Perov, Khokhlov (b0025) 2015; 24 Borin, Stepanov, Odenbach (b0010) 2013; 412 Stepanov, Borin, Kramarenko, Bogdanov, Semerenko, Storozhenko (b0020) 2014; 56 Becker, Raikher, Stolbov, Böhm, Zimmermann (b0040) 2017; 26 Vaganov, Borin, Odenbach, Raikher (b0070) 2018; 459 Borin, Stepanov, Dohmen (b0080) 2019; 89 Vaganov, Borin, Odenbach, Raikher (b0075) 2019; 15 Becker, Zimmermann, Borin, Stepanov, Storozhenko (b0045) 2018; 449 Wen, Wang, Gong (b0030) 2017; 26 Borin, Stepanov, Dohmen (b0085) 2019; 377 Stepanov, Borin, Bakhtiiarov (b0060) 2017; 26 Stepanov (10.1016/j.jmmm.2019.166125_b0005) 2012; 324 Stepanov (10.1016/j.jmmm.2019.166125_b0055) 2017 Linke (10.1016/j.jmmm.2019.166125_b0065) 2016; 6 Volkova (10.1016/j.jmmm.2019.166125_b0035) 2017 Stepanov (10.1016/j.jmmm.2019.166125_b0060) 2017; 26 Borin (10.1016/j.jmmm.2019.166125_b0015) 2013; 15 Borin (10.1016/j.jmmm.2019.166125_b0080) 2019; 89 Borin (10.1016/j.jmmm.2019.166125_b0010) 2013; 412 Becker (10.1016/j.jmmm.2019.166125_b0045) 2018; 449 Stepanov (10.1016/j.jmmm.2019.166125_b0020) 2014; 56 Kramarenko (10.1016/j.jmmm.2019.166125_b0025) 2015; 24 Becker (10.1016/j.jmmm.2019.166125_b0040) 2017; 26 Vaganov (10.1016/j.jmmm.2019.166125_b0075) 2019; 15 Wen (10.1016/j.jmmm.2019.166125_b0030) 2017; 26 Vaganov (10.1016/j.jmmm.2019.166125_b0070) 2018; 459 Gunther (10.1016/j.jmmm.2019.166125_b0050) 2017 Borin (10.1016/j.jmmm.2019.166125_b0085) 2019; 377 |
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Ser. doi: 10.1088/1742-6596/412/1/012040 contributor: fullname: Borin – volume: 56 start-page: 603 year: 2014 ident: 10.1016/j.jmmm.2019.166125_b0020 article-title: Magnetoactive elastomer based on magnetically hard filler: synthesis and study of viscoelastic and damping properties publication-title: Polym Sci. Ser. A doi: 10.1134/S0965545X14050149 contributor: fullname: Stepanov – volume: 377 year: 2019 ident: 10.1016/j.jmmm.2019.166125_b0085 article-title: On anisotropic mechanical properties of heterogeneous magnetic polymeric composites publication-title: Philosoph. Trans. R. Soc. A contributor: fullname: Borin – start-page: 1 year: 2017 ident: 10.1016/j.jmmm.2019.166125_b0050 contributor: fullname: Gunther – volume: 459 start-page: 92 year: 2018 ident: 10.1016/j.jmmm.2019.166125_b0070 article-title: Effect of local elasticity of the matrix on magnetization loops of hybrid magnetic elastomers publication-title: J. Magn. Magn. Mater. doi: 10.1016/j.jmmm.2017.12.016 contributor: fullname: Vaganov |
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Snippet | •Magnetic elastomer filled with magnetically hard particles has been investigated for magnetic properties.•The magnetic filler dispersed in the polymer matrix... This research is dedicated to the specifics of the behavior exhibited by elastomer filled with magnetically hard (high-coercivity) particles influenced by... |
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SubjectTerms | Coercivity Composite materials Elastomers Hybrid Magnetic elastomer Magnetic fields Magnetism Magnetization Magnetoactive Magnetorheological Particulate composites Polarity Polymers |
Title | Negative coercivity of magnetic elastomers filled with magnetically hard particles |
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